CAS 50-29-3 MFCD00000802-Clofenotane p, TAO{mole} - 淘摩尔专家级采购助手

Clofenotane p,

CAS 50-29-3 MFCD00000802

化学结构图

SMILES: Clc1ccc(C(c2ccc(Cl)cc2)C(Cl)(Cl)Cl)cc1

化学属性

Mol. Formula	C14H9Cl5
Mol. Weight	354
Melting Point	108-109°C
Flash Point	72 °C
Solubility	不溶于水，易溶于丙酮、苯、二氯乙烷。
Density	1.0
Stability	对光敏感
Boiling Point	260°C

别名和识别编码

Chemical Name	p’-DDT标准溶液 p, p’-DDT solution
CAS Number	50-29-3
Synonym	######## 1 1,1'-(2,2,2-trichlorethylidene)bis(4-c 1,1,1-TRICHLORO-2,2-BIS(4-CHLOROPHENYL)ETHANE 1,1,1-TRICHLORO-2,2-BIS(P-CHLOROPHENYL)ETHANE 1,1,1-TRICHLORO-2,2-DI(4-CHLOROPHENYL)ETHANE 1,1,1-Trichloro-2,2-di(p-chlorophenyl)ethane 1,1,1-Tricloro-2,2-bis(4-cloro-fenil)-etano 1,1,1-trichloro-2,2-bis(p-chlorophenyl)ethane 1,1,1-trichloro-2,2-bis(p-chlorophenyl)ethane 1,1,1-trichloro-2,2-bis-(4-chloro-phenyl)-ethane 1,1-BIS(4-CHLOROPHENYL)-2,2,2-TRICHLOROETHANE 1,1-Bis(p-chlorophenyl)-2,2,2-trichloroethane 1,1-双(4-氯苯基)2,2,2-三氯乙烷 2 2,2-bis(4-chlorophenyl)-1,1,1-trichloroethane, p,p'-DDT 2,2-bis(p-chlorophenyl)-1,1,1-trichloroethane 2,2-双(4-氯苯基)-1,1,1-三氯乙烷(即P,P'-DDT) 2,2-双(4-氯苯基)-1,1,1-三氯乙烷,1,
PubChem Substance ID	3036
EC Number	200-659-6
Beilstein Registry Number	1882657
MDL Number	MFCD00000802
Chemical Name Translation	p,
Merck Number	13,2861
Wiswesser Line Notation	GXGGYR DG&R DG
InChI	InChI=1S/C14H9Cl5/c15-11-5-1-9(2-6-11)13(14(17,18)19)10-3-7-12(16)8-4-10/h1-8,13H

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产品应用

用于ICP-AES、AAS、AFS、ICP-MS、离子色谱等。滴定分析用标准溶液。主要用于环境监测，仪器卫生监督、商品检验等方面对于农药残毒的分析测试工作。

安全信息

GHS Symbol

WGK Germany3

Hazard statements

H301 Toxic if swallowed 吞食有毒
H311 Toxic in contact with skin 皮肤接触中毒
H351 Suspected of causing cancer 怀疑致癌
H372 Causes damage to organs through prolonged or repeated exposure 长期或频繁接触会损伤器官
H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。

Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges

Hazard Codes T,N T,N,Xi,F

RTECSKJ3325000

Precautionary statements

P201 Obtain special instructions before use. 使用前获取专门指示。
P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
P273 Avoid release to the environment. 避免释放到环境中。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P281 Use personal protective equipment as required. 使用所需的个人防护装备。
P301+P310
P302+P352
P305+P351+P338
P307+P311
P308+P313
P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医，如果你觉得不舒服
P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
P322 Specific measures (see …on this label). 具体治疗（见本标签上的）。
P330 Rinse mouth. 漱口
P337+P313
P361 Remove/Take off immediately all contaminated clothing. 立即去除/脱掉所有被污染的衣服。
P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
P405 Store locked up. 上锁保管。
P501 Dispose of contents/container to..… 处理内容物/容器.....

Signal word Danger

Safety Statements

S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S22 Do not breathe dust 不要吸入粉尘；
S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
S33 Take precautionary measures against static discharges 对静电采取预防措施；
S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
S36 Wear suitable protective clothing 穿戴适当的防护服；
S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
S7 Keep container tightly closed 保存在严格密闭容器中；

Risk Statements

R11 Highly flammable 非常易燃
R25 Toxic if swallowed 吞咽有毒
R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有毒
R48/25
R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
R50/53
R52/53
R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
R39/23/24/25 Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed 毒性：吸入，皮肤接触和吞食都会产生十分严重的不可逆危险

Storage condition APPROX 4°C 低温(<10˚C)及避光保存。储存温度 2-8℃ 储存温度2-8℃

UN Number UN 2811 6.1/PG 3

Warnings 危化品目录(2015) 危险化学品

TYPE OF TEST            : TD - Toxic dose (other than lowest)
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 19 gm/kg/2Y-C
TOXIC EFFECTS :
   Tumorigenic - neoplastic by RTECS criteria
   Liver - tumors
   Blood - lymphoma, including Hodgkin

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1225 mg/kg/7W-C
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Liver - tumors
REFERENCE :
   TUMOAB Tumori.  (Casa Editrice Ambrosiana, Via G. Frua 6, 20146 Milan,
   Italy)  V.1-    1911-  Volume(issue)/page/year: 6

{hazar

TYPE OF TEST            : TD - Toxic dose (other than lowest)
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 17976 mg/kg/2Y-C
TOXIC EFFECTS :
   Tumorigenic - neoplastic by RTECS criteria
   Liver - tumors
REFERENCE :
   TUMOAB Tumori.  (Casa Editrice Ambrosiana, Via G. Frua 6, 20146 Milan,
   Italy)  V.1-    1911-  Volume(issue)/page/year: 68,11,1982

TYPE OF TEST            : TD - Toxic dose (other than lowest)
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 3408 mg/kg
                          multigenerations
TOXIC EFFECTS :
   Tumorigenic - neoplastic by RTECS criteria
   Reproductive - Tumorigenic effects - transplacental tumorigenesis
   Lungs, Thorax, or Respiration - tumors
REFERENCE :
   IJCNAW International Journal of Cancer.  (International Union Against
   Cancer, 3 rue du Conseil- General, 1205 Geneva, Switzerland)  V.1-    1966-
   Volume(issue)/page/year: 11,688,1973

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Primate - monkey
DOSE/DURATION           : 200 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AVPCAQ Advances in Pharmacology and Chemotherapy.  (Academic Press, Inc., 1
   E. First St., Duluth, MN 55802)  V.7-20, 1969-84.  Volume(issue)/page/year:
   12,31,1975

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 9100 ug/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   PESTD5 Proceedings of the European Society of Toxicology.  (Amsterdam,
   Netherlands)  V.16-18, 1975-77.  Discontinued.  Volume(issue)/page/year:
   17,351,1976

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Human - infant
DOSE/DURATION           : 150 mg/kg
TOXIC EFFECTS :
   Lungs, Thorax, or Respiration - acute pulmonary edema
REFERENCE :
   BMJOAE British Medical Journal.  (British Medical Assoc., BMA House,
   Tavistock Sq., London WC1H 9JR, UK)  V.1-    1857- Volume(issue)/page/year:
   2,845,1945

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1500 mg/kg
TOXIC EFFECTS :
   Behavioral - tremor
   Behavioral - muscle weakness
   Behavioral - ataxia
REFERENCE :
   BMJOAE British Medical Journal.  (British Medical Assoc., BMA House,
   Tavistock Sq., London WC1H 9JR, UK

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Human
DOSE/DURATION           : 500 mg/kg
T

TYPE OF TEST

TYPE OF TEST            : DNA adduct
TEST SYSTEM             : Bacteria - Escherichia coli
DOSE/DURATION           : 15 umol/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issu

TYPE OF TEST            : Cytogenetic analysis
TEST SYSTEM             : Human Leukocyte
DOSE/DURATION           : 40 mg/L
REFERENCE :
   HOEKAN Hokkaidoritsu Eisei Kenkyushoho.  Report of the Hokkaido Institute of
   Public Health.  (Nishi- 12-chome, Kita-19-jo, Kita-ku, Sapporo 060, Japan) 
   No.1-    1951-  Volume(issue)/page/year: 29,33,1979

TYPE OF TEST            : Mutation test systems - not otherwise specified
TEST SYSTEM             : Human Fibroblast
DOSE/DURATION           : 100 mg/kg
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 17(3),32,1973

{haz

TYPE OF TEST            : DNA inhibition
ROUTE OF EXPOSURE       : Intraperitoneal
TEST SYSTEM             : Rodent - mouse
DOSE/DURATION           : 20 gm/kg
REFERENCE :
   ARGEAR Archiv fuer Geschwulstforschung.  (VEB Verlag Volk und Gesundheit
   Neue Gruenstr. 18, Berlin DDR-1020, Ger. Dem. Rep.)  V.1-    1949-
   Volume(issue)/page/year: 51,605,1981

TYPE OF TEST            : Sex chromosome loss and nondisjunction
ROUTE OF EXPOSURE       : Oral
TEST SYSTEM             : Insect - Drosophila melanogaster
DOSE/DURATION           : 1 ug
REFERENCE :
   AJBSAM Australian Journal of Biological Sciences.  (Commonwealth Scientific
   and Industrial Research Organization, 314 Albert St., E. Melbourne, Vic.
   3002, Australia)  V.6-    1953-  Volume(issue)/page/year: 27,427,1974

TYPE OF TEST            : DNA adduct
TEST SYSTEM

{hazard_c

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - mouse
DOSE                    : 418 mg/kg
SEX/DURATION            : female 6-14 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Effects on Embryo or Fetus - extra-embryonic structures
   (e.g., placenta, umbilical cord)
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: PB223-160

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE                    : 504 mg/kg
SEX/DURATION            : lactating female 21 day(s) post-birth
TOXIC EFFECTS :
   Reproductive - Effects on Newborn - behavioral
REFERENCE :
   ENPBBC Environmental Physiology and Biochemistry.  (Copenhagen, Denmark)
   V.2-5, 1972-75. Discontinued.  Volume(issue)/page/year: 4,189,1974

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - ra

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE                    : 81 mg/kg
SEX/DURATION            : male 4 week(s) pre-mating
                          female 4 week(s) pre-mating  - 2 week(s) post-birth
TOXIC EFFECTS :
   Reproductive - Fertility - other measures of fertility
REFERENCE :
   TXAPA9 Toxicology and Applied Pharmacology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1959-  Volume(issue)/page/year:
   10,54,1967

TYPE OF TEST            : TDLo - Lowest published to

其他信息

用途:具有胃毒和触杀作用，属高残留农药品种，用于防治多种昆虫和卫生害虫
易溶于吡啶及二氧六环。在100ml溶剂中溶解度
图谱信息:2,2-双(对氯苯基)-1,1,1-三氯乙烷 (50-29-3)核磁图( 1 HNMR) 2,2-双(对氯苯基)-1,1,1-三氯乙烷 (50-29-3)Raman光谱 2,2-双(对氯苯基)-1,1,1-三氯乙烷 (50-29-3)红外图谱(IR1) 2,2-双(对氯苯基)-1,1,1-三氯乙烷 (50-29-3)核磁图( 13 CNMR) 2,2-双(对氯苯基)-1,1,1-三氯乙烷 (50-29-3)质谱(MS) 2,2-双(对氯苯基)-1,1,1-三氯乙烷 (50-29-3)红外图谱(IR2)
杀虫剂单一组分标准液
易溶于吡啶及二氧六环。在100ml溶剂中溶解度分别为：丙酮58g，四氯化碳45g，氯苯74g，乙醇2g，乙醚28g。不溶于水、稀酸和碱液。
RTECS号:KJ3325000
稳定性:Stable. Combustible. Incompatible with strong oxidizing agents, iron and aluminium and their salts, alkalies.
MOL 文件:50-29-3.mol
生产方法:由三氯乙醛与一氯化苯在发烟硫酸存在下缩合而得。在缩合锅中投入三氯乙醛、氯苯，搅拌下滴加发烟硫酸。缩合后的物料静置分层，放净废酸，酸性滴滴涕氯苯溶液用热水洗涤，再用氢氧化钠溶液洗涤。然后蒸馏回收氯苯，残留物即熔融的滴滴涕放至滚筒结晶器冷却结晶即得成品。缩合反应在10-23℃进行，缩合中同时加入缩合反应产生的废酸（内含副反应生成的对氯苯磺酸）或抑制副反应，减少对氯苯磺酸的生成量，滴加硫酸的时间约2.5h。一级品的滴滴涕原粉对位含量≥74.0%。
PackingGroup:III
HazardClass:6.1(b)
外观性质:白色或淡黄色粉末。