Acryloyl chloride 丙烯酰氯
CAS 814-68-6 MFCD00000731
信息真实价格透明
资金保障
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信息真实价格透明
资金保障
专业采购外包团队在线服务
品牌质保精细包装
现货库存
一流品牌服务
分类
- Acrylate, Acrylic Monomers, Materials Science, Monomers, Polymer Science
- {uni_hamburg} no charge; carbonyl chloride; 1fragment
- {SNA} Acrylate, Acrylic Monomers, Materials Science, Monomers, Polymer Science
产品应用
- 有机合成中间体。高分子化合物单体。
相关文献及参考
- Short: II/24C
- Short: II/24B
- Beilstein:2(4)1471
安全信息
GHS Symbol
- H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
- H290 May be corrosive to metals 可能腐蚀金属。
- H302 Harmful if swallowed 吞食有害
- H312 Harmful in contact with skin 皮肤接触有害
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
- H318 Causes serious eye damage 严重伤害眼睛
- H330 Fatal if inhaled 吸入致命
- H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P233 Keep container tightly closed. ?保持容器密闭。
- P234 Keep only in original container. 只保留在原来的容器中。
- P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
- P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
- P241+P242+P243
- P242 Use only non-sparking tools. 只能使用无火花工具。
- P243 Take precautionary measures against static discharge. 采取预防措施,防止静电放电。
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P264+P265
- P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P273 Avoid release to the environment. 避免释放到环境中。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P284 Wear respiratory protection.? 佩戴呼吸保护装置。
- P301+P312
- P301+P317
- P301+P330+P331
- P301+P330+P331+P310
- P302+P352
- P302+P361+P354
- P303+P361+P353
- P304+P340
- P304+P340+P310
- P305+P351+P338
- P305+P351+P338+P310
- P305+P354+P338
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
- P316
- P317
- P320 Specific treatment is urgent (see … on this label). 紧急具体治疗(见本标签上的)。
- P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
- P322 Specific measures (see …on this label). 具体治疗(见本标签上的)。
- P330 Rinse mouth. 漱口
- P362+P364
- P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
- P370+P378
- P390 Absorb spillage to prevent material damage. 吸收溢出物,防止重大损害。
- P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
- P403+P233
- P403+P235
- P404 Store in a closed container. 贮存于密闭容器中。
- P405 Store locked up. 上锁保管。
- P406 Store in corrosive resistant/… container with a resistant inner liner. 存放在耐腐蚀/具有耐性的内衬容器。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- R11 Highly flammable 非常易燃
- R14 Reacts violently with water 遇水会猛烈反应
- R26 Very toxic by inhalation 吸入极毒
- R34 Causes burns 会导致灼伤
- S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
- S20 When using do not eat or drink 使用时,不得进食,饮水;
- S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾;
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
- S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后,立即用大量…(由生产厂家指定)冲洗;
- S30 Never add water to this product 切勿将水加入该产品中;
- S33 Take precautionary measures against static discharges 对静电采取预防措施;
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
- S4 Keep away from living quarters 远离生活区;
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
- S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
- S7/9 Keep container tightly closed and in a well-ventilated place 保持容器严格密闭,置于通风良好的场所;
- S8 Keep container dry 保持容器干燥;
- S9 Keep container in a well-ventilated place 保持容器在通风良好的场所;
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intravenous SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 180 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#03367
TYPE OF TEST : LCLo - Lowest published lethal concentration ROUTE OF EXPOSURE : Inhalation SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 25 ppm/4H TOXIC EFFECTS : Sense Organs and Special Senses (Eye) - iritis Behavioral - ataxia Lungs, Thorax, or Respiration - emphysema REFERENCE : BJIMAG British Journal of Industrial Medicine. (British Medical Journal, Box 560B, Kennebunkport, ME 04046) V.1- 1944- Volume(issue)/page/year: 27,1,1970
TYPE OF TEST : LC50 - Lethal concentration, 50 percent kill ROUTE OF EXPOSURE : Inhalation SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 92 mg/m3/2H TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : 85GMAT "Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982 Volume(issue)/page/year: -,17,1982
其他信息
- 海关编码:29161980
- 外观性质:浅黄色液体。
- Alfa Aesar:丙烯酰氯,96%,400ppm的苯并噻嗪作稳定剂 Acryloyl chloride, 96%, stab. with 400ppm phenothiazine(814-68-6)
- Sigma Aldrich:814-68-6(sigmaaldrich)
- 类别:有毒物品
- 用途三:有机合成中间体。高分子化合物单体。
- 丙烯酰氯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 L1036302 丙烯酰氯, 96% 50g 319元 2011/04/16 A0147 丙烯酰氯(含稳定剂吩噻嗪) Acryloyl Chloride (stabilized with Phenothiazine) 500G 2880元 2011/04/16 A0147 丙烯酰氯(含稳定剂吩噻嗪) Acryloyl Chloride (stabilized with Phenothiazine) 25G 374元
- 敏感性:Moisture & Light Sensitive
- TCI Shanghai:丙烯酰氯(含稳定剂甲氧基氢醌) Acryloyl Chloride (stabilized with MEHQ),>;95.0%(T)(814-68-6)
- 用途二:该品用于有机合成。国外市售98%商品,沸点72-76℃,相对密度1.114,闪点16℃。
- 上游原料:氯化亚铜
- 储运特性:库房通风低温干燥
- 用途一:主要用于合成丙烯酸酯、丙烯酰胺类化合物,也用于制备防灰雾剂I的中间体
- 蒸气密度:>;1 (vs air)
- 图谱信息:丙烯酰氯(814-68-6)核磁图( 13 CNMR) 丙烯酰氯(814-68-6)核磁图( 1 HNMR) 丙烯酰氯(814-68-6)质谱(MS) 丙烯酰氯(814-68-6)红外图谱(IR1)
- MOL 文件:814-68-6.mol
- 易溶于氯仿,遇水和醇分解。有毒。有催泪性和腐蚀性。商品常加吩噻嗪和对苯二酚作稳定剂。
- 蒸气压:1.93 psi ( 20 °C)
- 毒性分级:高毒
- 下游产品:N-异丙基丙烯酰胺 --> 苯磺酸阿曲库铵 --> N-丙烯酰氧基琥珀酰亚胺 --> 1,4-二丙烯酰基哌嗪 --> 1,4-丁二醇二丙烯酸酯
- 可燃性危险特性:可燃; 加热分解释放有毒氯化物烟雾
- 方法一:由丙烯酸和三氯化磷作用,丙烯酸与三氯化磷的摩尔配比为1:0.333,将两者混合后,加热至沸腾。将反应混合物慢慢冷却到60-70℃。再反应15min,然后在室温下放置2h。反应物分二层,分出上层产物,加入氯化亚铜进行减压蒸馏,收集30-40℃(18.7kPa)的馏分,重蒸一次,收集30-32℃(18.7kPa)的馏分,得到丙烯酰氯。产率66%。
- MSDS 信息:丙烯酰氯(814-68-6).msds
- 灭火剂:干粉、泡沫、砂土、二氧化碳, 雾状水
- F:8-10
- 急性毒性:吸入-大鼠 LCL0:25 PPM/4小时; 吸入-小鼠 LC50: 92 毫克/立方米/2小时