CAS 1638-63-7 MFCD00000714-2-Chloro-2-Oxo-1-Phenylethyl Acetate 乙酰扁桃酰氯 TAO{mole}

2-Chloro-2-Oxo-1-Phenylethyl Acetate 乙酰扁桃酰氯

CAS 1638-63-7 MFCD00000714

化学结构图

SMILES: CC(=O)OC(C(=O)Cl)c1ccccc1

化学属性

Mol. Formula	CH3CO2CH(C6H5)COCl
Mol. Weight	212.63
Density	0.943 g/mL at 25 °C(lit.)
Refractive index	n20/D 1.514(lit.)
Boiling Point	125-130 °C/10 mmHg(lit.)
Flash Point	112 ºC
Appearance	纯度95%以上商品的性质：沸点125-130℃（1.33kPa），相对密度0.943，折光率1.5140，闪点>;110℃。

别名和识别编码

Chemical Name	2-Chloro-2-Oxo-1-Phenylethyl Acetate
MDL Number	MFCD00000714
CAS Number	1638-63-7
Synonym	TIMTEC-BB SBB003420 (R)-O-Acetylmandelic acid chloride 0-乙酰基苦杏仁酸氯化物乙酰基扁桃酰氯 O-Acetylmandelicacidchoride Benzeneacetyl chloride, alpha-(acetyloxy)- 1-(氯甲酰)苄基乙酸酯 Acetoxyphenylacetyl chloride O-Acetylmandelyl chloride O-ACETYLMANDELIC CHLORIDE, 95+% DL-MANDELOYL CHLORIDE ACETATE 2-Acetoxy-2-phenylacetic acid chloride ACETYLMANDELICACIDCHORIDE O-ACETYLMANDELOYL CHLORIDE ACETYLMANDELIC CHLORIDE 乙酰扁桃酰氯 O-ACETYLMANDELIC ACID CHLORIDE 1-(Chloroformyl)benzyl acetate Acetic acid 1-phenyl-2-oxo-2-chloroethyl ester O-乙酰氯化扁桃酸 2-ACETOXY-2-PHENYLACETYL CHLORIDE O-ACETYLMANDELIC CHLORIDE 2-Acetoxy-2-phenylacetyl chloride O-Acetylmandeloyl chloride, tech.,95% 1-(Chloroformyl)benzyl acetate; O-Acetylmandelic acid chloride O-Aceylmandelic Chloride LABOTEST-BB LTBB000504
EC Number	216-674-6
Chemical Name Translation	乙酰扁桃酰氯
InChIKey	BERNQQVIUAZUHY-UHFFFAOYSA-N
PubChem Substance ID	97698
InChI	InChI=1S/C10H9ClO3/c1-7(12)14-9(10(11)13)8-5-3-2-4-6-8/h2-6,9H,1H3

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安全信息

GHS Symbol

WGK Germany3

Hazard statements

H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
H318 Causes serious eye damage 严重伤害眼睛
H335 May cause respiratory irritation 可能导致呼吸道刺激

Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter

Precautionary statements

P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P301+P330+P331
P303+P361+P353
P304+P340
P305+P351+P338
P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
P403+P233
P405 Store locked up. 上锁保管。
P501 Dispose of contents/container to..… 处理内容物/容器.....

Signal word Danger

Hazard Codes C

Safety Statements

S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
S27 Take off immediately all contaminated clothing 立即脱掉全部污染的衣服；
S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；

Risk Statements

R36/37 Irritating to eyes and respiratory system 对眼睛和呼吸系统有刺激性
R34 Causes burns 会导致灼伤

Packing GroupIII

Hazard Class8

Storage condition 0-6°C

UN Number UN 3265 8/PG 2

其他信息

用途一:医药中间体，用于半合成或全合成制取后马托品氢溴酸盐。
下游产品:
方法一:由扁桃酸乙酰化反应得到乙酰基扁桃酸，再经氯化而得。在干燥回流装置中，放入相当于1份扁桃酸乙酰化所得乙酰基扁桃酸(约1.29份)。再加2.38份二氯亚砜，于60-65℃反应2.5h，反应放出产生的氯化氢及二氧化硫气体。然后升温至60-70℃，减压回收过量的二氯亚砜。再加无水苯1.8倍量，减压共沸蒸馏，蒸出多余的二氯亚砜和乙酰氯，至蒸馏温度逐渐升至80℃，且已无苯馏出时，再加无水苯1.2倍量，再减压蒸馏一次，至蒸馏温度逐渐升至90℃为止。得淡黄色油状物，即乙酰扁桃酰氯。得量约为扁桃酸的1.44倍。
MSDS 信息:O-Acetylmandelic acid chloride(1638-63-7).msds
Acros Organics:O-乙酰氯化扁桃酸 O-Acetylmandelic acid chloride, 95%(1638-63-7)
MOL 文件:1638-63-7.mol
乙酰扁桃酰氯价格(试剂级):更新日期产品编号产品名称包装价格 2010/06/21 102600050 乙酰扁桃酰氯 O-Acetylmandelic acid chloride 95% 5 GR 297元
上游原料:氧氯化硫 --> 乙酰氯 --> 二氧化硫 --> 无水苯 --> (S)-(+)-O-乙酰基-L-扁桃酸