Chlorocarbonylsulfenyl chloride 氯羰基亚磺酰氯

CAS 2757-23-5 MFCD00000703

化学结构图

2757-23-5
SMILES: O=C(Cl)SCl

化学属性

Mol. FormulaCCl2OS
Mol. Weight130.98
Refractive index1.5170 to 1.5260
Boiling Point98°C
Density1.552 g/mL at 25 °C(lit.)
TSCANo
Flash Point62°C(lit.)

别名和识别编码

Chemical NameChlorocarbonylsulfenyl Chloride
Synonym (Chlorocarbonyl)sulfenyl chloride (Chloroformyl)sulfur chloride (Chlorothio)formyl chloride, Chloroformylsulfenyl chloride (Chlorothio)formyl chloride 1-(Chlorothio)formic acid chloride 1-(Chlorothio)formyl chloride CHLOROCARBONYLSULFENYL CHLORIDE CHLOROCARBONYLSULPHENYL CHLORIDE CHLOROFORMYLSULFENYL CHLORIDE CHLOROTHIOFORMYL CHLORIDE CTFC Carbonochloridothioic acid, anhydrosulfide with thiohypochlorous acid Carbonyl chloride thiohypochlorite Chlorcarbonylsulfenylchlorid Chlorformylsulfenylchlorid Chloro(chlorosulfanyl)oxomethane Chlorocarbonylsulfenyl Chloride {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
CAS Number2757-23-5
PubChem Substance ID75990
EC Number220-415-2
Beilstein Registry Number506318
MDL NumberMFCD00000703
Reaxys-RN506318
Chemical Name Translation氯羰基亚磺酰氯
InChIKeyMNOALXGAYUJNKX-UHFFFAOYSA-N
LabNetwork Molecule IDLN00240610
InChIInChI=1S/CCl2OS/c2-1(4)5-3
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分类

  • {uni_hamburg} no charge; carbonyl chloride; 1fragment
  • {SA} Building Blocks, Chemical Synthesis, Organic Building Blocks, Sulfenyl Halides, Sulfur Compounds
  • {SNA} Building Blocks, Chemical Synthesis, Organic Building Blocks, Sulfenyl Halides, Sulfur Compounds

相关文献及参考

  • Short: EINECS
  • Short: II/25B
  • Reagent used in the protection of amino groups as their N-dithiasuccinimide (Dts) derivatives: J. Org. Chem., 42, 2819 (1977). The group is stable to acid but is cleaved by treatment with a thiol, e.g. 2-mercaptoethanol and base: J. Am. Chem. Soc., 99, 7363 (1977); 102, 3084 (1980). For use in the protection of amino sugars, including selective reduction in the presence of an azido group with sodium borohydride, see: J. Chem. Soc., Perkin 1, 405 (1995). See also Appendix 6.

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H227 Combustible liquid 可燃液体
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes C
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331
  • P301+P330+P331+P310
  • P302+P361+P354
  • P303+P361+P353
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P310
  • P305+P354+P338
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P316
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P370+P378
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
UN Number UN3265 UN 3265 8/PG 2 3265
Risk Statements
  • R37 Irritating to respiratory system 刺激呼吸道
  • R34 Causes burns 会导致灼伤
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S20 When using do not eat or drink 使用时,不得进食,饮水;
Storage condition +4°C Moisture Sensitive
Packing GroupIII
Hazard Class8

其他信息

  • Acros Organics:氯羰基亚磺酰氯 Chlorocarbonylsulfenyl chloride, 95%(2757-23-5)
  • TCI Shanghai:氯羰基亚磺酰氯 Chlorocarbonylsulfenyl Chloride,>;95.0%(T)(2757-23-5)
  • Alfa Aesar:氯羰基次磺酰氯,97% Chlorocarbonylsulfenyl chloride, 97%(2757-23-5)
  • F:9-13-21
  • 氯羰基亚磺酰氯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 C1043 氯羰基亚磺酰氯 Chlorocarbonylsulfenyl Chloride 5G 679元 2014/06/02 C1043 氯羰基亚磺酰氯 Chlorocarbonylsulfenyl Chloride 25G 2250元 2010/06/21 224340050 氯羰基亚磺酰氯 Chlorocarbonylsulfenyl chloride 95% 5 GR 870元
  • Sigma Aldrich:2757-23-5(sigmaaldrich)
  • MOL 文件:2757-23-5.mol
  • 敏感性:Moisture Sensitive
  • 图谱信息:氯羰基亚磺酰氯(2757-23-5)核磁图( 13 CNMR) 氯羰基亚磺酰氯(2757-23-5)红外图谱(IR1) 氯羰基亚磺酰氯(2757-23-5)质谱(MS)

系列性分类


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