2-Chlorobenzyl Bromide 2-氯苯甲基溴
CAS 611-17-6 MFCD00000566
化学结构图
SMILES: Clc1ccccc1CBr
化学属性
| Mol. Formula | C7H6BrCl |
|---|---|
| Mol. Weight | 205 |
| Boiling Point | 103-104 |
| Density | 1.583 |
| Refractive index | 1.5900 to 1.5940 |
| Flash Point | 109°C(lit.) |
| TSCA | No |
| Appearance | 无色油状液体。沸点103-104℃（1.33kPa），相对密度1.583，折光率1.5922。溶于苯、氯仿，在热水中分解。 |
别名和识别编码
| Chemical Name | 2-Chlorobenzyl Bromide |
|---|---|
| CAS Number | 611-17-6 |
| Alfabeta Name | CHLOROBENZYLBROMIDE 2- |
| MDL Number | MFCD00000566 |
| Synonym | -Bromo-2-chlorotoluene 1-(BROMOMETHYL)-2-CHLOROBENZENE 1-(Brommethyl)-2-chlorbenzol 1-(bromomethyl)-2-chloro-benzen 2-CHLORO-ALPHA-BROMOTOLUENE 2-CHLOROBENZYL BROMIDE 2-Chlorobenzyl bromide 97% 2-Chlorobenzylbromide,97% 2-氯苄溴 2-氯苯甲基溴 2-氯苯甲基溴,97% ALPHA-BROMO-2-CHLOROTOLUENE Benzene, 1-(bromomethyl)-2-chloro- O-CHLOROBENZYL BROMIDE Toluene, α-bromo-o-chloro- Toluene, α-bromo-o-chloro- Toluene,α-bromo-o-chloro- alpha-Bromo-2-chlorotoluene; 1-(Bromomethyl)-2-chlorobenzene alpha-bromo-o-chlorotoluene α-Bromo-2-chlorotoluene α-Bromo-o-chlorotoluene 邻氯溴苄 |
| EC Number | 210-257-2 |
| Beilstein Registry Number | 386264 |
| PubChem Substance ID | 11905 |
| Chemical Name Translation | 2-氯苯甲基溴 |
| Reaxys-RN | 386264 |
| LabNetwork Molecule ID | LN00009488 |
| InChI | InChI=1S/C7H6BrCl/c8-5-6-3-1-2-4-7(6)9/h1-4H,5H2 |
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分类
- {SNA} Aryl, Building Blocks, C7, Chemical Synthesis, Halogenated Hydrocarbons, Organic Building Blocks
- {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment
相关文献及参考
- Short: III/31b Title: Nuclear Quadrupole Resonance Spectroscopy Data: Nuclei Zn ... Bi. Diagrams, Indexes Author: Chihara, H.; Nakamura, N. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/31b Year: 1993 Keyword: NQR ISBN: 3-540-55147-6 ISBN: 978-3-540-55147-8 Internet Resource: DOI:10.1007/b46097 RefComment: 147 figs., VIII, 347 pages. Hardcover Abstract: Volume III/31 continues the compilation of nuclear quadrupole resonance spectroscopy data of solid substances which started in with volume III/20 in 1987 covering the literature from the beginning of nuclear quadrupole resonance spectroscopy in 1951 to 1982 and containing the data for 8000 substances in the solid state, distributed among three subvolumes III/20 a, b, and c. Volume III/31 covers the literature published in the period from the end of 1982 through the end of 1989. Included are the data for substances studied for the first time, as well as data for substances already present in the previous volume III/20 if the data published there could be completed or improved by new studies. In total there are 2500 substances in volume III/31, showing the scope and significance of nuclear quadrupole resonance spectroscopy up to recent times.
- Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15
安全信息
GHS Symbol
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S27 Take off immediately all contaminated clothing 立即脱掉全部污染的衣服；
- S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- R34 Causes burns 会导致灼伤
- R36/37 Irritating to eyes and respiratory system 对眼睛和呼吸系统有刺激性
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P303+P361+P353
- P304+P340
- P304+P340+
- P305+P351+P338
- P305+P351+P338+P310
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- H290 May be corrosive to metals 可能腐蚀金属。
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
- H335 May cause respiratory irritation 可能导致呼吸道刺激
其他信息
- MOL 文件:611-17-6.mol
- 检测方法:GC
- TCI Shanghai:2-氯苄溴 2-Chlorobenzyl Bromide,>;98.0%(GC)(611-17-6)
- 存储注意事项:氮气保护;光敏感
- Hazard Note:Corrosive/Lachrymatory
- 上游原料:2-氯甲苯
- 方法一:邻氯甲苯在光照下与溴反应，溴化产物减压蒸馏，收集100-120℃（1.33kPa）馏分，即得成品，产率98%。
- 用途一:有机合成中间体。
- MSDS 信息:alpha-Bromo-2-chlorotoluene(611-17-6).msds
- 2-氯苄溴价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 C1443 2-氯苄溴 2-Chlorobenzyl Bromide 25G 1010元 2014/06/02 C1443 2-氯苄溴 2-Chlorobenzyl Bromide 5G 368元 2010/06/21 278931000 2-氯苄溴 2-Chlorobenzyl bromide 97% 100 GR 3808元
- Alfa Aesar:2-氯苯甲基溴,97% 2-Chlorobenzyl bromide, 97%(611-17-6)
- Sigma Aldrich:611-17-6(sigmaaldrich)
- Acros Organics:2-氯苄溴 2-Chlorobenzyl bromide, 97%(611-17-6)
- 图谱信息:2-氯苄溴(611-17-6)质谱(MS) 2-氯苄溴(611-17-6)核磁图( 1 HNMR) 2-氯苄溴(611-17-6)红外图谱(IR1) 2-氯苄溴(611-17-6)核磁图( 13 CNMR)
- 下游产品:3-(2-氯苯基)丙酸 --> N-(2-氯苄基)-N-甲胺 --> (2-氯苯基)甲基磺酰氯
- 敏感性:Lachrymatory
