Butyltin trichloride 丁基三氯化锡
CAS 1118-46-3 MFCD00000515
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分类
- {uni_hamburg} no charge; metal-organic; 1fragment
- {SNA} Chemical Synthesis, Organometallic Reagents, Organotin, Organotin Halides
相关文献及参考
- Short: III/35D5
- Short: III/20a
- Merck: 14,10455 Beilstein: 4,IV,4346
- Merck: 14,10455
安全信息
- R34 Causes burns 会导致灼伤
- R20/21 Harmful by inhalation and in contact with skin 吸入及与皮肤接触有害
- R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
- R37 Irritating to respiratory system 刺激呼吸道
- R50/53
- R20 Harmful by inhalation 吸入有害
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- R21 Harmful in contact with skin 与皮肤接触有害
- R48/23/25
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
- S27 Take off immediately all contaminated clothing 立即脱掉全部污染的衣服;
- S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后,立即用大量…(由生产厂家指定)冲洗;
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
- S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
- S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
GHS Symbol
- H227 Combustible liquid 可燃液体
- H302+H312+H332
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
- H332 Harmful if inhaled 吸入有害
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P234 Keep only in original container. 只保留在原来的容器中。
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P273 Avoid release to the environment. 避免释放到环境中。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P301+P330+P331+P310
- P303+P361+P353+P310+P363
- P304+P340+P310
- P305+P351+P338
- P305+P351+P338+P310
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
- P390 Absorb spillage to prevent material damage. 吸收溢出物,防止重大损害。
- P403+P235
- P405 Store locked up. 上锁保管。
- P406 Store in corrosive resistant/… container with a resistant inner liner. 存放在耐腐蚀/具有耐性的内衬容器。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 2140 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : 85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,1245,1986
TYPE OF TEST : Mutation test systems - not otherwise specified TEST SYSTEM : Bacteria - Escherichia coli DOSE/DURATION : 5 mg/tube REFERENCE : MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 280,195,1992
TYPE OF TEST : Mutation in microorganisms TEST SYSTEM : Bacteria - Salmonella typhimurium DOSE/DURATION : 100 ug/tube REFERENCE : MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 300,265,1993
TYPE OF TEST : TDLo - Lowest published toxic dose ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE : 3 gm/kg SEX/DURATION : female 7-8 day(s) after conception TOXIC EFFECTS : Reproductive - Maternal Effects - other effects Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death, e.g., stunted fetus) REFERENCE : JJATDK JAT, Journal of Applied Toxicology. (John Wiley & Sons Ltd., Baffins Lane, Chichester, W. Sussex PO19 1UD, UK) V.1- 1981- Volume(issue)/page/year: 15,297,1995
其他信息
- 可燃性危险特性:热分解排出有毒氯化物烟雾
- 储运特性:库房通风低温干燥
- 毒性分级:中毒
- Acros Organics:三氯丁基锡 Butyltin trichloride, 97%(1118-46-3)
- 敏感性:Moisture Sensitive
- Alfa Aesar:n-Butyltin trichloride, 96%(1118-46-3)
- MSDS 信息:Butyltin trichloride(1118-46-3).msds
- 下游产品:2-溴甲基-四氢吡喃
- 丁基三氯化锡价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/06/21 191205000 丁基三氯化锡 Butyltin trichloride 97% 500 GR 2756元 2010/06/21 191201000 丁基三氯化锡 Butyltin trichloride 97% 100 GR 800元 2010/05/25 71125 n-Butyltin trichloride, 96% 25g 253元
- 上游原料:四丁基锡
- 外观:无色或微黄色液体。
- Sigma Aldrich:1118-46-3(sigmaaldrich)
- 职业标准:TWA 0.1 毫克(锡)/立方米; STEL 0.2 毫克/立方米 (皮肤)
- 灭火剂:水, 干粉, 二氧化碳, 泡沫
- 急性毒性:口服-大鼠 LD50: 2140 毫克/公斤
- 类别:有毒物质
- TSCA:Yes
- 用途二:丁基三氯化锡(1118-46-3)是一种PVC稳定剂的重要中间体,主要用于玻璃容器表面的热端涂层。啤酒瓶热端喷涂液。
- MOL 文件:1118-46-3.mol
- 用途一:用作生产玻璃制品的增强剂
- 刺激数据:皮肤-兔 0.75 毫克/24小时 重度; 眼睛-兔 0.05 毫克/24小时 重度