tert-Butylmagnesium chloride 叔丁基氯化镁

CAS 677-22-5 MFCD00000465

化学结构图

677-22-5
SMILES: CC(C)(C)[Mg]Cl

化学属性

Mol. FormulaC4H9ClMg
Mol. Weight116.87
Density0.931
TSCANo
Flash Point34 °F
Stability对空气和湿度敏感，密封充氩保存
Boiling Point77-79

别名和识别编码

Chemical Nametert-Butylmagnesium chloride
CAS Number677-22-5
EC Number250-023-7
Beilstein Registry Number3535403
MDL NumberMFCD00000465
PubChem Substance ID87564088
Synonym Tert-butyl magnesium chloride,1.0M solution in THF,Safeseal {LY} Tert-butyl magnesium chloride,1.0M solution in THF,Safeseal solution~1MinTHF t-Butylmagnesium Chloride 1.0 M In Tetrahydrofuran tert-Butylmagnesium Chloride (23% in Tetrahydrofuran, ca. 2mol/L) {} {LY} Tert-butyl magnesium chloride,1.0M solution in THF,Safeseal {} {} {LY} Tert-butyl magnesium chloride,1.0M solution in THF,Safeseal {} {} {} {LY} Tert-butyl magnesium chloride,1.0M solution in THF,Safeseal {} {} {} {} {LY} Tert-butyl magnesium chloride,1.0M solution in THF,Safeseal {} {} {} {} {} {} {} {} {} {} {LY} Tert-butyl magnesium chloride,1.0M solution in THF,Safeseal {} {} {} {} {} {} {LY} Tert-butyl magnesium chloride,1.0M solution in THF,Safeseal {} {} {} {} {} {} {} {LY} Tert-butyl magnesium chloride,1.0M solution in THF,Safeseal {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tert-butyl magnesium chloride,1.0M solution in THF,Safeseal {} {} {} {} {} {}
Reaxys-RN3911207
Chemical Name Translation叔丁基氯化镁
InChIKeyCQRPUKWAZPZXTO-UHFFFAOYSA-M
LabNetwork Molecule IDLN00163692
InChIInChI=1S/C4H9.ClH.Mg/c1-4(2)3;;/h1-3H3;1H;/q-1;;+2/p-1
Canonical SMILESCC([Mg]Cl)(C)C
信息真实价格透明    资金保障    专业采购外包团队在线服务   
信息真实价格透明    资金保障    专业采购外包团队在线服务   
品牌质保精细包装    现货库存    一流品牌服务   

分类

  • {SNA} Acids & Bases, Alkyl, Bases, Chemical Synthesis, Grignard Reagents, Organic Bases,
  • {SNA} 12 Principles Aligned Products, 25mL Sure/Seal Reagents, Acids & Bases, Alkyl,
  • {SNA} Acids & Bases, Alkyl, Bases, Chemical Synthesis, Grignard Reagents,

产品应用

  • Reagent used in an Fe(acac)3-catalyzed cross-coupling with chloroenynols

相关文献及参考

  • Beilstein: 4,665

安全信息

Signal word Danger
GHS Symbol
WGK Germany1
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
Risk Statements
  • R11 Highly flammable 非常易燃
  • R14 Reacts violently with water 遇水会猛烈反应
  • R14/15 Reacts violently with water, liberating extremely flammable gases 遇水剧烈反应，释放出高度可燃气体
  • R17 Spontaneously flammable in air 在空气中能够自燃
  • R19 May form explosive peroxides 可能生成易爆的过氧化物质
  • R22 Harmful if swallowed 吞咽有害
  • R34 Causes burns 会导致灼伤
  • R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥
Precautionary statements
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P222 Do not allow contact with air. 不要与空气接触。
  • P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire. 远离任何与水接触的可能，因为会剧烈反应可能产生闪火。
  • P231+P232
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241+P242+P243
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331+P310
  • P303+P361+P353
  • P303+P361+P353+P310+P363
  • P304+P340+P310
  • P305+P351+P338
  • P305+P351+P338+P310
  • P308+P313
  • P335+P334
  • P370+P378
  • P402+P404
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P422 Store contents under… 存储目录在…之下。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H224 Extremely flammable liquid and vapour 极端易燃液体和蒸气
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H250 Catches fire spontaneously if exposed to air 暴露于空气自发着火
  • H260 In contact with water releases flammable gases which may ignite spontaneously 与水接触时释放可燃气体，可自燃。
  • H261 In contact with water releases flammable gas 与水接触时释放可燃气体。
  • H302 Harmful if swallowed 吞食有害
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H336 May cause drowsiness or dizziness 肯能导致嗜睡或头晕
  • H351 Suspected of causing cancer 怀疑致癌
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes 4.3 F+,C,F F,C
Packing GroupI
UN Number 3399
Storage condition -20°C {LY} -20°C Air & Moisture Sensitive {} {LY} -20°C {} {} {LY} -20°C {} {} {} {LY} -20°C {} {} {} {} {LY} -20°C {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°
Hazard Class4.3/3
Restrict 危险品

其他信息

  • 叔丁基氯化镁价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 B1148 氯化叔丁基镁(23%的四氢呋喃溶液,约2mol/L) tert-Butylmagnesium Chloride (23% in Tetrahydrofuran, ca. 2mol/L) 250G 817元 2014/06/02 B1147 氯化叔丁基镁(26%的乙醚溶液,约2mol/L) tert-Butylmagnesium Chloride (26% in Ethyl Ether, ca. 2mol/L) 250G 350元 2010/06/21 394308000 叔丁基氯化镁 tert-Butylmagnesium chloride , 1.7M solution in diethyl ether, AcroSeal® 800 ML 2675元
  • Sigma Aldrich:677-22-5(sigmaaldrich)
  • 检测方法:TITR
  • TCI Shanghai:氯化叔丁基镁(26%的乙醚溶液,约2mol/L) tert-Butylmagnesium Chloride (26% in Ethyl Ether, ca. 2mol/L)(677-22-5)
  • MOL 文件:677-22-5.mol
  • 存储注意事项:氮气保护
  • 上游原料:四氢呋喃 --> 镁 --> 氯代叔丁烷
  • Acros Organics:叔丁基氯化镁 tert-Butylmagnesium chloride, 2.0M solution in diethyl ether(677-22-5)
  • F:1-3-10

系列性分类

  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Grignard Reagents 格氏试剂
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Organic Acids - Synthetic Reagents
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Grignard Reagents 格氏试剂
  4. Alkyl - Grignard Reagents
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Grignard Reagents 格氏试剂
  4. Alkyl - Grignard Reagents
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Grignard Reagents & Alkyl Metals
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Metal Compounds 金属化合物
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Grignard Reagents 格氏试剂
  4. Alkenyl
  1. Functional Group 官能团索引
  2. organomagnesium compound

相关产品推荐