Heptafluorobutyric anhydride 七氟丁酸酐
CAS 336-59-4 MFCD00000432
化学结构图
SMILES: O=C(OC(=O)C(F)(F)C(F)(F)C(F)(F)F)C(F)(F)C(F)(F)C(F)(F)F
化学属性
| Mol. Formula | C8F14O3 |
|---|---|
| Mol. Weight | 410.06 |
| Boiling Point | 108-110 °C at 760 mmHg |
| TSCA | T |
| Density | 1.674 |
| Refractive index | n20/D 1.287(lit.) |
| Melting Point | -43 °C |
| Solubility | 起反应 |
| Flash Point | None |
| Stability | 对湿度敏感 |
别名和识别编码
| Chemical Name | Heptafluorobutyric anhydride |
|---|---|
| CAS Number | 336-59-4 |
| Alfabeta Name | HEPTAFLUOROBUTYRICANHYDRIDE |
| MDL Number | MFCD00000432 |
| Synonym | Perfluorobutyric anhydride {LY} Perfluorobutyric anhydride {} {LY} Perfluorobutyric anhydride {} {} {LY} Perfluorobutyric anhydride {} {} {} {LY} Perfluorobutyric anhydride {} {} {} {} {LY} Perfluorobutyric anhydride {} {} {} {} {} {LY} Perfluorobutyric anhydride {} {} {} {} {} {} {LY} Perfluorobutyric anhydride {} {} {} {} {} {} {} {LY} Perfluorobutyric anhydride {} {} {} {} {} {} {} {} {LY} Perfluorobutyric anhydride {} {} {} {} {} {} {} {} {} {LY} Perfluorobutyric anhydride {} {} {} {} {} {} {} {} {} {} {LY} Perfluorobutyric anhydride {} {} {} {} {} {} {} {} {} {} {} {LY} Perfluorobutyric anhydride {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Perfluorobutyric anhydride {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Perfluorobutyric anhydride {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Perfluorobutyric anhydride {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Perfluorobutyric anh |
| EC Number | 206-410-8 |
| Beilstein Registry Number | 856036 |
| PubChem Substance ID | 67643 |
| Reaxys-RN | 856036 |
| Chemical Name Translation | 七氟丁酸酐 |
| InChIKey | UFFSXJKVKBQEHC-UHFFFAOYSA-N |
| LabNetwork Molecule ID | LN00115757 |
| InChI | InChI=1S/C8F14O3/c9-3(10,5(13,14)7(17,18)19)1(23)25-2(24)4(11,12)6(15,16)8(20,21)22 |
| Canonical SMILES | O=C(OC(C(F)(F)C(F)(F)C(F)(F)F)=O)C(F)(F)C(F)(F)C(F)(F)F |
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分类
- {SNA} Building Blocks, Carbonyl Compounds, Carboxylic Acid Anhydrides, Chemical Synthesis, Organic Building Blocks
- {uni_hamburg} no charge; carbo-anhydride; 1fragment
- {SNA} β-Glucuronidase, β-Glucuronidase Drug Analysis Bundle, Ac
- {SA} β-Glucuronidase, β-Glucuronidase Drug Analysis Bundle, Alkyl Fluorinated Building Blocks, Analytical and Industrial Enzymes, Biochemicals and Reagents,
产品应用
- GC-MS 分析合成肽立体异构体含量的衍生化试剂。
- GC 衍生化试剂，用于制备氨基酸和其他生物活性化合物的挥?发性衍生物
相关文献及参考
- Reagent for the preparation of volatile heptafluorobutyryl derivatives of amines, alcohols, etc., for GC purposes: J. Chromat., 60, 134 (1971); 69, 157 (1972); 97, 19, 175 (1974); D. R. Knapp, Handbook of Analytical Derivatisation Reactions, Wiley, N.Y. (1979); Handbook of Derivatives for Chromatography, 2nd ed., K. Blau and J. M. Halket, Eds., Wiley, Chichester (1993).
- Short: II/27B
- Short: EINECS
- Reagent for the preparation of volatile heptafluorobutyryl derivatives of amines, alcohols, etc., for GC purposes: J. Chromat., 60, 134 (1971); 69, 157 (1972); 97, 19, 175 (1974); D. R. Knapp, Handbook of Analytical Derivatisation Reactions, Wiley, N.Y. (1979); H
- Beilstein:2(4)817
安全信息
GHS Symbol
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
- R34 Causes burns 会导致灼伤
- P234 Keep only in original container. 只保留在原来的容器中。
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P301+P330+P331
- P301+P330+P331+P310
- P303+P361+P353+P310+P363
- P304+P340+P310
- P305+P351+P338
- P305+P351+P338+P310
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- P390 Absorb spillage to prevent material damage. 吸收溢出物，防止重大损害。
- P405 Store locked up. 上锁保管。
- P406 Store in corrosive resistant/… container with a resistant inner liner. 存放在耐腐蚀/具有耐性的内衬容器。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- H290 May be corrosive to metals 可能腐蚀金属。
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
其他信息
- Sigma Aldrich:336-59-4(sigmaaldrich)
- Hazard Note:Corrosive/Hygroscopic
- 上游原料:五氧化二磷 --> 七氟丁酸
- 检测方法:GC,NMR,MS
- TSCA:T
- MSDS 信息:Perfluorobutyric anhydride(336-59-4).msds
- 存储注意事项:湿度敏感
- TCI Shanghai:七氟丁酸酐 Heptafluorobutyric Anhydride,>;95.0%(T)(336-59-4)
- 七氟丁酸酐价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 H0337 七氟丁酸酐 Heptafluorobutyric Anhydride 10G 656元 2010/06/21 169260250 七氟丁酸酐 Heptafluorobutyric anhydride 98+% 25 GR 1754元 2010/06/21 169260050 七氟丁酸酐 Heptafluorobutyric anhydride 98+% 5 GR 501元
- 图谱信息:七氟丁酸酐(336-59-4)红外图谱(IR1) 七氟丁酸酐(336-59-4)质谱(MS)
- Alfa Aesar:七氟丁酸酐,98% Heptafluorobutyric anhydride, 98%(336-59-4)
- 敏感性:Hygroscopic
- Acros Organics:七氟丁酸酐 Heptafluorobutyric anhydride, 98+%(336-59-4)
- F:10-21
- MOL 文件:336-59-4.mol
- 用途一:气相色谱中的衍生化试剂、酰化试剂。
- 和水反应形成丁酸。
- 海关编码:29159080
