CAS 5469-26-1 MFCD00000206-1-Bromopinacolone 1-溴频哪酮 TAO{mole}

1-Bromopinacolone 1-溴频哪酮

CAS 5469-26-1 MFCD00000206

化学结构图

SMILES: CC(C)(C)C(=O)CBr

化学属性

Mol. Formula	C6H11BrO
Mol. Weight	179.05
Refractive index	1.4640 to 1.4680
Boiling Point	188-194 °C at 760 mmHg
Density	1.331 g/mL at 25 °C(lit.)
Melting Point	-10 °C
Flash Point	66°C(lit.)
TSCA	No
Appearance	白色或淡黄色透明液体。

别名和识别编码

Chemical Name	1-Bromopinacolone
MDL Number	MFCD00000206
CAS Number	5469-26-1
Synonym	1-Bromo-3,3-dimethyl-2-butanone {LY} 1-Bromo-3,3-dimethyl-2-butanone {} {LY} 1-Bromo-3,3-dimethyl-2-butanone {} {} {LY} 1-Bromo-3,3-dimethyl-2-butanone {} {} {} {LY} 1-Bromo-3,3-dimethyl-2-butanone {} {} {} {} {LY} 1-Bromo-3,3-dimethyl-2-butanone {} {} {} {} {} {LY} 1-Bromo-3,3-dimethyl-2-butanone {} {} {} {} {} {} {LY} 1-Bromo-3,3-dimethyl-2-butanone {} {} {} {} {} {} {} {LY} 1-Bromo-3,3-dimethyl-2-butanone {} {} {} {} {} {} {} {} {LY} 1-Bromo-3,3-dimethyl-2-butanone {} {} {} {} {} {} {} {} {} {LY} 1-Bromo-3,3-dimethyl-2-butanone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Bromo-3,3-dimethyl-2-butanone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Bromo-3,3-dimethyl-2-butanone {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Bromo-3,3-dimethyl-2-butanone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Bromo-3,3-dimethyl-2-butanone {} {} {} {} {}
PubChem Substance ID	21642
EC Number	226-794-0
Beilstein Registry Number	506485
Reaxys-RN	506485
Chemical Name Translation	1-溴频哪酮
InChIKey	SAIRZMWXVJEBMO-UHFFFAOYSA-N
LabNetwork Molecule ID	LN00182896
InChI	InChI=1S/C6H11BrO/c1-6(2,3)5(8)4-7/h4H2,1-3H3
Canonical SMILES	CC(C)(C)C(=O)CBr

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品牌质保精细包装现货库存一流品牌服务

安全信息

GHS Symbol

WGK Germany3

Hazard statements

H315 Causes skin irritation 会刺激皮肤
H319 Causes serious eye irritation 严重刺激眼睛
H335 May cause respiratory irritation 可能导致呼吸道刺激
H227 Combustible liquid 可燃液体

Personal Protective Equipment Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter

RTECSEL7010000

Precautionary statements

P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P501 Dispose of contents/container to..… 处理内容物/容器.....
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P305+P351+P338
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
P332+P313
P305+P351+P338+P337+P313
P302+P350
P337+P313
P302+P352+P332+P313+P362+P364

Signal word Warning

Packing GroupII

UN Number UN2810 1224

Risk Statements

R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

Safety Statements

S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；

Hazard Codes Xi,F Xi

Hazard Class3.2

Storage condition 2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - guinea pig
DOSE/DURATION           : 500 mg/kg
TOXIC EFFECTS :
   Peripheral Nerve and Sensation - flaccid paralysis without anesthesia
   (usually neuromuscular blockage)
   Lungs, Thorax, or Respiration - dyspnea
REFERENCE :
   BDKS** "Studien uber die Pharmakologie des Pinakolins und einiger seiner
   Derivate mit besonderer Berucksichtigung der Kreislaufwirkung,
   Dissertation," Bang, L., Pharmakologischen Abteilung des Karolinischen
   Instituts, Stockholm, Sweden, 1934  Volume(issue)/page/year: -,-,1934

其他信息

F:8-10-21
Acros Organics:1-溴频哪酮 1-Bromopinacolone, 93%(5469-26-1)
Sigma Aldrich:5469-26-1(sigmaaldrich)
Hazard Note:Irritant/Flammable
MOL 文件:5469-26-1.mol
1-溴频哪酮价格(试剂级):更新日期产品编号产品名称包装价格 2014/06/02 B1490 1-溴-3,3-二甲基-2-丁酮 1-Bromo-3,3-dimethyl-2-butanone 25G 1440元 2014/06/02 B1490 1-溴-3,3-二甲基-2-丁酮 1-Bromo-3,3-dimethyl-2-butanone 5G 539元 2010/06/21 CD08380EB 1-溴频哪酮 1-bromo-3,3-dimethylbutan-2-one 25 GR 1035元
MSDS 信息:Bromomethyl tert-butyl ketone(5469-26-1).msds
Alfa Aesar:1-溴频哪酮,97% 1-Bromopinacolone, 97+%(5469-26-1)
TCI Shanghai:1-溴-3,3-二甲基-2-丁酮 1-Bromo-3,3-dimethyl-2-butanone,>;95.0%(GC)(5469-26-1)
上游原料:甲醇 --> 乙醚 --> 二氯甲烷 --> 频哪酮 --> 四丁基三溴化铵