2-Bromo-4'-phenylacetophenone 2-溴-4-苯基乙酰苯

CAS 135-73-9 MFCD00000202

化学结构图

135-73-9
SMILES: O=C(CBr)c1ccc(-c2ccccc2)cc1

化学属性

Mol. FormulaC14
Mol. Weight275
Melting Point125.0 to 129.0 deg-C
TSCAYes
Density1.422

别名和识别编码

Chemical Name2-Bromo-4'-phenylacetophenone
Synonym ALPHA-BROMO-P-PHENYLACETOPHENONE Ethanone, 1-[1,1'-biphenyl]-4-yl-2-bromo- P-PHENYLPHENACYL BROMIDE ALPHA-BROMO-4-PHENYLACETOPHENONE 4-(Bromoacetyl)biphenyl 2-溴-4-苯基乙酰苯 4-BROMOACETYLBIPHENYL 1-(1,1’-联苯基)-4-基-2-溴乙酮 4-苯基苯甲酰甲基溴 A-BROMO-P-PHENYLACETOPHENONE 4-(溴乙酰)联苯 Α-溴-4-苯基乙酰苯 AKOS BBS-00004047 2-BROMO-4'-PHENYLACETOPHENONE 4'-PHENYLPHENACYL BROMIDE 1-Biphenyl-4-yl-2-bromo-ethanone 1-[1,1'-BIPHENYL]-4-YL-2-BROMO-1-ETHANONE TIMTEC-BB SBB001097 4-PHENYLPHENACYL BROMIDE 2-溴-4ˊ-苯基乙酰苯 ω-溴-4-苯基乙酰苯 Bromomethyl p-biphenylyl ketone 4-苯基溴代苯乙酮 ω-溴-4-苯基乙酰苯 4-苯基苯甲酰甲基溴 P-BROMOACETYLBIPHENYL 1-(1,1'-BIPHENYL-4-YL)-2-BROMOETHANONE Acetophenone, 2-bromo-4'-phenyl- OMEGA-BROMO-4-PHENYLACETOPHENONE 2-溴-4′-苯基乙酰苯 PHENYLPHENACYL BROMIDE 2-溴-4'-苯基苯乙酮, 97% 1-[1,1’-biphenyl]-4-yl-2-bromo-ethanon 1-BROMO-4'-PHENYLACETOPHENONE 联苯基-2-溴乙酮 2-溴-4ˊ-苯基苯乙酮
CAS Number135-73-9
PubChem Substance ID87563641
EC Number205-217-6
Beilstein Registry Number7(3)2137
MDL NumberMFCD00000202
Reaxys-RN513838
Chemical Name Translation2-溴-4-苯基乙酰苯
InChIKeyKGHGZRVXCKCJGX-UHFFFAOYSA-N
LabNetwork Molecule IDLN00224907
InChIInChI=1S/C14H11BrO/c15-10-14(16)13-8-6-12(7-9-13)11-4-2-1-3-5-11/h1-9H,10H2
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分类

  • {SNA} B, Bioactive Small Molecules, Building Blocks, C13 to C14, Carbonyl Compounds, Chemical Synthesis, Ketones, Organic Building Blocks, 细胞生物学
  • B, Bioactive Small Molecules, Building Blocks, C13 to C14, Carbonyl Compounds, Cell Biology, Chemical Synthesis, Ketones, Organic Building Blocks
  • {SN
  • {SNA} B, Bioactive Small Molecules, Building Blocks, C13 to C14, Carbonyl Compounds, Cell Biology, Chemical Synthesis, Ketones, Organic Build

相关文献及参考

  • Beil. 7 ,IV,1408
  • Aldrich MSDS 1 , 277:C / Corp MSDS 1 (1), 566:D / FT-IR 1 (2), 22:B / FT-IR 2 (2), 2391:D / FT-NMR 1 (2), 827:A / IR-Spectra (3), 861:E / IR-Spectra (2), 754:B / NMR-Reference 2 (2), 23:D / RegBook 1 (2), 1633:N / Sigma FT-IR 1 (2), 343:D / Structure Index 1 , 256:D:3
  • Short: IV/7a Title: Liquid Crystals: One-Ring Systems and Two-Ring Systems without Bridging Groups Author: Vill, V. Editor: Thiem, J. Source: Landolt-Börnstein, New Series Volume: IV/7a Year: 1992 Keyword: organic compounds; enthaly of fusion; melting point; phase transition; liquid crystals; glass transition ISBN: 3-540-55503-X ISBN: 978-3-540-55503-2 Internet Resource: DOI:10.1007/b46098 RefComment: 10 figs., VIII, 268 pages.

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H290 May be corrosive to metals 可能腐蚀金属。
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Hazard Codes
Precautionary statements
  • P303+P361+P353+P310+P363
  • P390 Absorb spillage to prevent material damage. 吸收溢出物，防止重大损害。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P405 Store locked up. 上锁保管。
  • P304+P340
  • P303+P361+P353
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P304+P340+P310
  • P301+P330+P331+P310
  • P234 Keep only in original container. 只保留在原来的容器中。
  • P406 Store in corrosive resistant/… container with a resistant inner liner. 存放在耐腐蚀/具有耐性的内衬容器。
  • P305+P351+P338+P310
Signal word
UN Number UN 3261 8/PG 2 3261
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
Risk Statements
Storage condition Light Sensitive 0-6°C
Packing GroupIII
Hazard Class8

其他信息

  • MOL 文件:135-73-9.mol
  • Alfa Aesar:2-溴-4'-苯基苯乙酮,97% 2-Bromo-4'-phenylacetophenone, 97%(135-73-9)
  • F:8-19
  • 2-溴-4-苯基乙酰苯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 B0633 2-溴-4'-苯基乙酰苯 2-Bromo-4'-phenylacetophenone 25G 909元 2014/06/02 B0633 2-溴-4'-苯基乙酰苯 2-Bromo-4'-phenylacetophenone 5G 318元 2010/06/21 MWP00289EE 2-溴-4-苯基乙酰苯 1-[1,1'-biphenyl]-4-yl-2-bromoethan-1-one 50 GR 1500元
  • Acros Organics:2-溴-4'-苯基苯乙酮 2-Bromo-4'-phenylacetophenone, 98%(135-73-9)
  • Sigma Aldrich:135-73-9(sigmaaldrich)
  • 图谱信息:2-溴-4-苯基乙酰苯(135-73-9)质谱(MS) 2-溴-4-苯基乙酰苯(135-73-9)核磁图( 1 HNMR) 2-溴-4-苯基乙酰苯(135-73-9)红外图谱(IR2) 2-溴-4-苯基乙酰苯(135-73-9)核磁图( 13 CNMR) 2-溴-4-苯基乙酰苯(135-73-9)红外图谱(IR1)
  • TCI Shanghai:4’-苯基-2-溴苯乙酮 2-Bromo-4'-phenylacetophenone,>;98.0%(T)(135-73-9)
  • 敏感性:Lachrymatory

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Ketones - Carbonyl Compounds
  6. C13 to C14 - Ketones
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Aromatic Ketones
  1. Analytical & Chromatography 分析化学与色谱
  2. Labeling Reagents for HPLC
  1. Analytical & Chromatography 分析化学与色谱
  2. HPLC
  3. Analytical Reagents
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Ketones 酮
  6. C11 to C12

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