CAS 103-88-8 MFCD00000092-4'-Bromoacetanilide 4-溴乙酰苯胺 TAO{mole}

4'-Bromoacetanilide 4-溴乙酰苯胺

CAS 103-88-8 MFCD00000092

化学结构图

SMILES: CC(=O)Nc1ccc(Br)cc1

化学属性

Mol. Formula	C8H8BrNO
Mol. Weight	214.05922
Melting Point	165-169 °C
TSCA	Yes
Solubility	难溶
Appearance	4'-溴乙酰苯胺(103-88-8)为浅黄色结晶或粉末状结晶。熔点168℃，相对密度1.717。溶于苯、氯仿、乙酸乙酯，略溶于醇，微溶于热水，不溶于冷水。
Boiling Point	353.4 °C at 760 mmHg

别名和识别编码

Chemical Name	4'-Bromoacetanilide
MDL Number	MFCD00000092
CAS Number	103-88-8
Beilstein Registry Number	12(3)1437
Reaxys-RN	2208091
PubChem Substance ID	87563555
Merck Number	1399
Synonym	N-(4-bromophenyl)acetamide {LY} N-(4-bromophenyl)acetamide {} {LY} N-(4-bromophenyl)acetamide {} {} {LY} N-(4-bromophenyl)acetamide {} {} {} {LY} N-(4-bromophenyl)acetamide {} {} {} {} {LY} N-(4-bromophenyl)acetamide {} {} {} {} {} {LY} N-(4-bromophenyl)acetamide {} {} {} {} {} {} {LY} N-(4-bromophenyl)acetamide {} {} {} {} {} {} {} {LY} N-(4-bromophenyl)acetamide {} {} {} {} {} {} {} {} {LY} N-(4-bromophenyl)acetamide {} {} {} {} {} {} {} {} {} {LY} N-(4-bromophenyl)acetamide {} {} {} {} {} {} {} {} {} {} {LY} N-(4-bromophenyl)acetamide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} N-(4-bromophenyl)acetamide {} {} {} {} {} {} {} {} {} {} {} {} {LY} N-(4-bromophenyl)acetamide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} N-(4-bromophenyl)acetamide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} N-(4-bromophenyl)acetamide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
EC Number	203-154-9
Alfabeta Name	BROMOACETANILIDE 4-'
Chemical Name Translation	4-溴乙酰苯胺
Wiswesser Line Notation	ER DMV1
LabNetwork Molecule ID	LN00182753
InChI	InChI=1S/C8H8BrNO/c1-6(11)10-8-4-2-7(9)3-5-8/h2-5H,1H3,(H,10,11)
Canonical SMILES	O=C(C)NC(C=C1)=CC=C1Br

信息真实价格透明资金保障专业采购外包团队在线服务

品牌质保精细包装现货库存一流品牌服务

安全信息

RTECSAD9625000

Signal word Warning {} {} {} {} {} {TCI}

Hazard statements

H315 Causes skin irritation 会刺激皮肤
H319 Causes serious eye irritation 严重刺激眼睛
H335 May cause respiratory irritation 可能导致呼吸道刺激

Precautionary statements

P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P332+P313
P305+P351+P338+P337+P313
P302+P350
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P305+P351+P338
P337+P313
P302+P352+P332+P313+P362+P364

Safety Statements

S36 Wear suitable protective clothing 穿戴适当的防护服；
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S37 Wear suitable gloves 戴适当手套；

WGK Germany3

GHS Symbol

Hazard Codes Xi

Risk Statements

R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves

Warnings IRRITANT

Packing GroupIII

Hazard Class6.1(b)

UN Number 2811

TYPE OF TEST            : LD - Lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : >500 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NCNSA6 National Academy of Sciences, National Research Council,
   Chemical-Biological Coordination Center, Review.  (Washington, DC)
   Volume(issue)/page/year: 5,10,1953

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 250 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: AD277-689

Storage condition 2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {}

其他信息

上游原料:乙酐 --> 碳酸氢钠 --> 4-溴苯胺 --> 亚硫酸氢钠溶液
图谱信息:4'-溴乙酰苯胺(103-88-8)Raman光谱 4'-溴乙酰苯胺(103-88-8)核磁图( 1 HNMR) 4'-溴乙酰苯胺(103-88-8)质谱(MS) 4'-溴乙酰苯胺(103-88-8)红外图谱(IR1) 4'-溴乙酰苯胺(103-88-8)红外图谱(IR2)
Sigma Aldrich:103-88-8(sigmaaldrich)
MOL 文件:103-88-8.mol
Acros Organics:4'-溴乙酰苯胺 ** 4'-Bromoacetanilide, 98%(103-88-8)
Hazard Note:Irritant
用途一:有机合成中间体。
TCI Shanghai:4'-溴乙酰苯胺 4'-Bromoacetanilide,>;98.0%(GC)(103-88-8)
Alfa Aesar:4'-溴乙酰苯胺,98% 4'-Bromoacetanilide, 98%(103-88-8)
4'-溴乙酰苯胺价格(试剂级):更新日期产品编号产品名称包装价格 2014/06/02 B0534 4'-溴乙酰苯胺 4'-Bromoacetanilide 500G 3250元 2014/06/02 B0534 4'-溴乙酰苯胺 4'-Bromoacetanilide 25G 422元 2010/06/21 171570250 4'-溴乙酰苯胺 4'-Bromoacetanilide 98% 25 GR 679元
方法一:由乙酰苯胺经溴化而得。将乙酰苯胺溶于乙醇中，冷至10℃左右，慢慢加溴，温度控制在20-25℃，约1.5-2h加完，再搅拌0.5h，放置一天，然后倒至亚硫酸氢钠溶液中，过滤，水洗，再用乙醇重结晶即得成品。