CAS 1163-19-5 MFCD00000059-Decabromodiphenyl oxide 十溴二苯醚 TAO{mole}

Decabromodiphenyl oxide 十溴二苯醚

CAS 1163-19-5 MFCD00000059

化学结构图

SMILES: Brc1c(Br)c(Br)c(Oc2c(Br)c(Br)c(Br)c(Br)c2Br)c(Br)c1Br

化学属性

Mol. Formula	C12Br10O
Mol. Weight	959.17
Density	3.0
Melting Point	>300°C
TSCA	Yes
Boiling Point	425°C
Solubility	<0.1 G/100 ML AT 20 ºC
Flash Point	-12°C
Appearance	白色或淡黄色粉末。熔点304-309℃。溴含量83.3%。几乎不溶于所有溶剂。热稳定性良好。

别名和识别编码

Chemical Name	Decabromodiphenyl oxide
CAS Number	1163-19-5
EC Number	214-604-9
Beilstein Registry Number	2188438
MDL Number	MFCD00000059
Reaxys-RN	2188438
PubChem Substance ID	14410
Synonym	1,1'-Oxybis(2,3,4,5,6-pentabromobenzene) 1,1’-oxybis(2,3,4,5,6-pentabromo-benzen 6,6'-Oxybis(1,2,3,4,5-pentabromobenzene) {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
Chemical Name Translation	十溴二苯醚
LabNetwork Molecule ID	LN00201236
InChI	InChI=1S/C12Br10O/c13-1-3(15)7(19)11(8(20)4(1)16)23-12-9(21)5(17)2(14)6(18)10(12)22
Canonical SMILES	BrC1=C(Br)C(Br)=C(Br)C(Br)=C1OC2=C(Br)C(Br)=C(Br)C(Br)=C2Br

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品牌质保精细包装现货库存一流品牌服务

产品应用

添加型阻燃剂

安全信息

Signal word Danger Warning

GHS Symbol

WGK Germany1

Safety Statements

S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；

Risk Statements

R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
R21/22 Harmful in contact with skin and if swallowed 皮肤接触和不慎吞咽有害
R22 Harmful if swallowed 吞咽有害
R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
R53 May cause long-term adverse effects in the aquatic environment 对水生环境有长期的有害作用

Precautionary statements

P201 Obtain special instructions before use. 使用前获取专门指示。
P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P281 Use personal protective equipment as required. 使用所需的个人防护装备。
P305+P351+P338
P305+P351+P338+P337+P313
P308+P313
P332+P313
P405 Store locked up. 上锁保管。
P501 Dispose of contents/container to..… 处理内容物/容器.....

RTECSKN3525000

Hazard statements

H315 Causes skin irritation 会刺激皮肤
H304 May be fatal if swallowed and enters airways 吞食和进入呼吸道可能致命
H336 May cause drowsiness or dizziness 肯能导致嗜睡或头晕
H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
H361d Suspected of damaging the unborn child 怀疑对未出生婴儿造成伤害
H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
H332 Harmful if inhaled 吸入有害
H302 Harmful if swallowed 吞食有害
H312 Harmful in contact with skin 皮肤接触有害
H316 Causes mild skin irritation 会轻微的刺激皮肤

Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter dust mask type N95 (US), Eyeshields, Gloves

Packing GroupII

UN Number 3152 UN3152

Hazard Codes Xn,Xi,N,F F,Xn,N Xn

Hazard Class9

Storage condition 2-8°C

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1092 gm/kg/2Y-C
TOXIC EFFECTS :
   Tumorigenic - neoplastic by RTECS criteria
   Liver - tumors
REFERENCE :
   NTPTR* National Toxicology Program Technical Report Series.  (Research
   Triangle Park, NC 27709) No.206-  Volume(issue)/page/year: NTP-TR-309,1986

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 500 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: OTS0522261

TYPE OF TEST            : LD - Lethal dose
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : >3 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 48(8),18,1983

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 100 mg/kg
SEX/DURATION            : female 6-15 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Fertility - post-implantation mortality (e.g. dead and/or
   resorbed implants per total number of implants)
REFERENCE :
   COTODO Journal of Fire and Flammability/Combustion Toxicology Supplement.
   (Westport, CT)  V.1-2, 1974-75.  For publisher information, see JCTODH.
   Volume(issue)/page/year: 1,52,1974

其他信息

十溴二苯醚价格(试剂级):更新日期产品编号产品名称包装价格 2011/08/23 30213480 十溴联苯醚 1kg 108元 2011/04/16 D1388 十溴二苯醚 Decabromodiphenyl Ether 500G 613元 2011/04/16 D1388 十溴二苯醚 Decabromodiphenyl Ether 25G 167元
Alfa Aesar:双(五溴苯基)醚,99% Bis(pentabromophenyl) ether, 99%(1163-19-5)
常规方法:用铁桶或编织袋内衬塑料袋包装。每桶（袋）净重25kg。贮存于干燥、通风良好的库房中。贮运时注意防火、防晒。按一般化学品规定贮运。
{Chemical
方法一:本制备方法包括：溴化、除溴、吸滤、洗涤、干燥等工艺。将溶剂二氯乙烷和碎铝片，加入反应釜中，搅拌下缓缓滴加1 400 kg溴，直至碎铝全部消失。将温度调至15 ℃，直至溴滴加完毕。另外将180 kg二苯醚用二氯乙烷溶解，将其打入计量槽中。在搅拌下滴入溴溶液中。滴毕后继续升温至50 ℃时保温反应6 h。加水100 kg，并加适量的亚硫酸钠除去过量的溴。搅拌均匀后静置沉淀，吸滤，用水洗涤至中性。压滤，干燥得成品。反应式：
用途二:十溴二苯醚产品主要用作添加型阻燃剂，含溴量大，热稳定性好、阻燃效能高，用途广泛，适用作聚乙烯、聚丙烯、ABS树脂、环氧树脂、PBT树脂、硅橡胶、三元乙橡胶及聚脂纤维、棉纤维等的阻燃剂。
Hazard Note:Irritant
用途五:添加型阻燃剂
水溶性<0.1 g/100 mL at 20℃。几乎不溶于所有溶剂。热稳定性良好。
Sigma Aldrich:1163-19-5(sigmaaldrich)
图谱信息:十溴二苯醚(1163-19-5)质谱(MS) 十溴二苯醚(1163-19-5)红外图谱(IR1) 十溴二苯醚(1163-19-5)红外图谱(IR2)
上游原料:溴 --> 二苯醚 --> 铝 --> 二氯乙烷 --> 氯乙烷 --> 二溴甲烷 --> 1,4
下游产品:1,4-苯二甲酸二甲酯与1,4-丁二醇的聚合物
MOL 文件:1163-19-5.mol
防护措施:大鼠经口LD50＞15g/kg。可以用于塑料制品，由于原料有毒，生产设备应密闭，操作现场应有良好通风。操作人员穿戴防护用具。
用途三:本品用于聚乙烯、聚丙烯、聚对苯二甲酸丁二醇酯中作阻燃剂。其物理性和经济性都比较好。其缺点是耐候性差。
用途一:高效添加型阻燃剂，对HIPS、ABS、LDPE、橡胶、PBT等都具有优良的阻燃效果，亦可用于尼龙纤维及涤棉纺织物
TCI Shanghai:十溴二苯醚 Decabromodiphenyl Ether,>;98.0%(GC)(1163-19-5)
海关编码:29093031
方法二:二苯醚在卤代催化剂（铁粉等）存在下，与溴反应而得。生产方法可有两种：1.溶剂法将二苯醚溶于溶剂中，加入催化剂，然后加溴进行反应。反应毕，过滤、洗涤、干燥，即得十溴联苯醚。常用的溶剂有二溴乙烷、二氯乙烷、二溴甲烷、四氯化碳、四氯乙烷等。2.过量溴化法即用过量溴作溶剂的溴化方法。将催化剂溶解在溴中，向溴中滴加二苯醚。反应结束后，将过量溴蒸出，中和、过滤，干燥即得成品。工业品为白色粉末，溴含量81-83%。原料消耗定额：二苯醚180kg/t、溴（99.5%）1400kg/t。
用途四:添加型阻燃剂，用途广泛。可用于聚乙烯、聚丙烯、ABS树脂、聚对苯二甲酸丁二醇酯、聚对苯二甲酸乙二醇酯以及硅橡胶、三元乙丙橡胶制品中。该品与三氧化二锑并用阻燃效果更佳，是无污染阻燃剂。该品作为阻燃剂在物性和经济性两方面都比较好。但其缺点是耐候性差，并会使树脂发黄。用于高冲击聚苯乙烯中的添加量为12%-15%。
MSDS 信息:1,1'-Oxybis(2,3,4,5,6-pentabromobenzene)(1163-19-5).msds