Cobalt(II) acetylacetonate 乙酰丙酮钴(II)
CAS 14024-48-7 MFCD00000014
化学结构图
SMILES:
化学属性
| Mol. Formula | C10H14CoO4·2H2O |
|---|---|
| Mol. Weight | 257.15(as Anhydrous) |
| Melting Point | 165-170 °C(lit.) |
| TSCA | Yes |
| Stability | 易吸潮 |
别名和识别编码
| Chemical Name | Cobalt(II) acetylacetonate |
|---|---|
| CAS Number | 14024-48-7 |
| Beilstein Registry Number | 1,783 |
| PubChem Substance ID | 87565505 |
| MDL Number | MFCD00000014 |
| Synonym | 2,4-戊二酮 钴(II) 衍生物 Co(acac)2 乙酰丙酮合钴 乙酰丙酮钴 乙酰丙酮钴 乙酰丙酮钴(II) 乙酰丙酮钴（II） Co(acac)2 乙酰丙酮合钴 2,4-戊二酮 钴(II) 衍生物 Bis(acetylacetonato)cobalt(II) hydrate |
| EC Number | 237-855-6 |
| Chemical Name Translation | 乙酰丙酮钴(II) |
| Reaxys-RN | 4157956 |
| InChIKey | BKFAZDGHFACXKY-UHFFFAOYSA-N |
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资金保障
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分类
- {SNA} Cobalt, Materials Science, Micro/NanoElectronics, Solution Deposition Precursors
- {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Cobalt
- Cobalt, Materials Science, Micro/NanoElectronics, Solution Deposition Precursors
- {SNA} Cobalt, Micro/NanoElectronics, Solution Deposition Precursors, 材料科学
产品应用
- 有机反应催化剂。添加剂。油漆的催干剂。
相关文献及参考
- Catalyst which mediates the coupling of vinylic halides with organomagnesium reagents, or with organozinc reagents with retention of alkene stereochemistry: Tetrahedron Lett., 39, 6159, 6163 (1998), respectively.
- Beilstein:1,783
- Used catalytically with NaBH4, promotes the Pauson-Khand type reaction of an akyne, an alkene and CO: Tetrahedron Lett., 37, 3145 (1996):
安全信息
- H317 May cause an allergic skin reaction 可能导致皮肤过敏
- H302 Harmful if swallowed 吞食有害
- H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled 吸入可能导致过敏或哮喘症状或呼吸困难
- H350 May cause cancer 可能致癌
- H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
- H318 Causes serious eye damage 严重伤害眼睛
- H360 May damage fertility or the unborn child 可能对生育能力或未出生婴儿造成伤害
- H302+H312+H332
- H361 Suspected of damaging fertility or the unborn child 怀疑对生育能力或未出生婴儿造成伤害
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P308+P313
- P332+P313
- P301+P312+P330
- P302+P350
- P337+P313
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P305+P351+P338
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P201 Obtain special instructions before use. 使用前获取专门指示。
- P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
- P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
- P304+P340+P312
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338+P337+P313
- P405 Store locked up. 上锁保管。
- P302+P352+P312+P362+P364
GHS Symbol
- S24 Avoid contact with skin 避免皮肤接触；
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- S37 Wear suitable gloves 戴适当手套；
- S22 Do not breathe dust 不要吸入粉尘；
- S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
- S7 Keep container tightly closed 保存在严格密闭容器中；
- R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
- R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
其他信息
- 难溶于冷的四氯化碳和苯、微溶于水、氯仿，溶于甲醇、乙醇。
