CAS 994-30-9 MFCD00000507-Triethylchlorosilane 三乙基氯硅烷 TAO{mole}

Triethylchlorosilane 三乙基氯硅烷

CAS 994-30-9 MFCD00000507

化学结构图

SMILES: CC[Si](Cl)(CC)CC

化学属性

Mol. Formula	C6H15ClSi
Mol. Weight	150.72
Density	0.886
Refractive index	1.4300 to 1.4320
Boiling Point	142-144 °C at 760 mmHg
Flash Point	30°C(lit.)
TSCA	Yes
Melting Point	-50 °C
Stability	对湿度敏感
Appearance	有刺激性的无色易燃液体。
Danger-Level	乙类

别名和识别编码

Chemical Name	Triethylchlorosilane
CAS Number	994-30-9
Synonym	Chlorotriethylsilane {LY} Chlorotriethylsilane {} {LY} Chlorotriethylsilane {} {} {LY} Chlorotriethylsilane {} {} {} {LY} Chlorotriethylsilane {} {} {} {} {LY} Chlorotriethylsilane {} {} {} {} {} {LY} Chlorotriethylsilane {} {} {} {} {} {} {LY} Chlorotriethylsilane {} {} {} {} {} {} {} {LY} Chlorotriethylsilane {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {LY} Chlorotriethylsilane {} {} {} {} {} {} {} {} {} {LY} Chlorotriethylsilane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Chlorotriethylsilane {} {} {} {} {} {} {} {} {} {} {} {LY} Chlorotriethylsilane {} {} {} {} {} {} {} {} {} {} {} {} {LY} Chlorotriethylsilane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Chlorotriethylsilane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Chlorotriethylsilane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Chlorotriethylsilane {} {} {} {} {} {} {} {} {} {} {} {}
MDL Number	MFCD00000507
EC Number	213-615-6
Beilstein Registry Number	1732860
PubChem Substance ID	13819
Reaxys-RN	1732860
Chemical Name Translation	三乙基氯硅烷
LabNetwork Molecule ID	LN00007961
InChI	InChI=1S/C6H15ClSi/c1-4-8(7,5-2)6-3/h4-6H2,1-3H3
Canonical SMILES	CC[Si](Cl)(CC)CC

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产品应用

和Grignard试剂一起用于钯催化的丙二烯的碳硅烷化。Grignard攻击丙二烯中间碳，从而是末端碳硅烷化。

安全信息

Signal word Danger

GHS Symbol

WGK Germany1

Safety Statements

S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
S25 Avoid contact with eyes 避免眼睛接触；
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S33 Take precautionary measures against static discharges 对静电采取预防措施；
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用（指明具体的消防器材种类，如果用水增加危险，注明“禁止用水”
S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；

Risk Statements

R10 Flammable 易燃
R11 Highly flammable 非常易燃
R14 Reacts violently with water 遇水会猛烈反应
R19 May form explosive peroxides 可能生成易爆的过氧化物质
R22 Harmful if swallowed 吞咽有害
R35 Causes severe burns 会导致严重灼伤
R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
R37 Irritating to respiratory system 刺激呼吸道
R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用

Precautionary statements

P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
P233 Keep container tightly closed. ?保持容器密闭。
P234 Keep only in original container. 只保留在原来的容器中。
P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
P241+P242+P243
P242 Use only non-sparking tools. 只能使用无火花工具。
P243 Take precautionary measures against static discharge. 采取预防措施，防止静电放电。
P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P301+P310
P301+P330+P331
P301+P330+P331+P310
P303+P361+P353
P303+P361+P353+P310+P363
P304+P340
P304+P340+P310
P305+P351+P338
P305+P351+P338+P310
P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
P330 Rinse mouth. 漱口
P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
P370+P378
P390 Absorb spillage to prevent material damage. 吸收溢出物，防止重大损害。
P403+P235
P405 Store locked up. 上锁保管。
P406 Store in corrosive resistant/… container with a resistant inner liner. 存放在耐腐蚀/具有耐性的内衬容器。
P501 Dispose of contents/container to..… 处理内容物/容器.....

Hazard statements

H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
H226 Flammable liquid and vapour 易燃液体和蒸气
H301 Toxic if swallowed 吞食有毒
H302 Harmful if swallowed 吞食有害
H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
H318 Causes serious eye damage 严重伤害眼睛
H335 May cause respiratory irritation 可能导致呼吸道刺激
H351 Suspected of causing cancer 怀疑致癌

Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter

Packing GroupII

UN Number 2924 2986 UN 2986 8/PG 2

Storage condition 2-8°C {LY} 2-8°C Flammables area Moisture Sensitive {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {

Hazard Codes 3 F,C

Hazard Class8/3

其他信息

TCI Shanghai:三乙基氯硅烷 Chlorotriethylsilane,>;97.0%(GC)(994-30-9)
海关编码:29310095
三乙基氯硅烷价格(试剂级):更新日期产品编号产品名称包装价格 2011/08/23 xw010200 三乙基氯硅烷 100ml 550元 2011/04/16 T0589 三乙基氯硅烷 Chlorotriethylsilane 25G 1200元 2011/04/16 T0589 三乙基氯硅烷 Chlorotriethylsilane 5G 369元
F:10-21
图谱信息:三乙基氯硅烷(994-30-9)质谱(MS) 三乙基氯硅烷(994-30-9)核磁图( 1 HNMR) 三乙基氯硅烷(994-30-9)红外图谱(IR1)
用途一:用来合成有机硅的原料、中间体及用作乙基硅油、乙基硅橡胶的封端剂
用途二:和Grignard试剂一起用于钯催化的丙二烯的碳硅烷化。Grignard攻击丙二烯中间碳，从而是末端碳硅烷化。
Acros Organics:三乙基氯硅烷 Chlorotriethylsilane, 99%(994-30-9)
TSCA:Yes
MOL 文件:994-30-9.mol
Sigma Aldrich:994-30-9(sigmaaldrich)
Alfa Aesar:三乙基氯硅烷,98+% Chlorotriethylsilane, 98+%(994-30-9)
MSDS 信息:Chlorotriethylsilane(994-30-9).msds
敏感性:Moisture Sensitive
水中分解.