Tetrabutylammonium Azide 叠氮化四丁基铵
CAS 993-22-6 MFCD00060069
化学结构图
SMILES: CCCC[N+](CCCC)(CCCC)CCCC.[N-]=[N+]=[N-]
化学属性
| Mol. Formula | C16H36N4 |
|---|---|
| Mol. Weight | 284.48 |
| Melting Point | 84-88 °C (lit.) |
| TSCA | Yes |
| Density | 1.53 |
| Stability | 对热敏感,易吸潮 |
别名和识别编码
| Chemical Name | Tetrabutylammonium Azide |
|---|---|
| MDL Number | MFCD00060069 |
| CAS Number | 993-22-6 |
| Synonym | N,N,N-Tributyl-1-butanaminium azide N,N,N-Tributyl-1-butanaminium azide Tetrabutylammonium nitride Tetrabutylammonium Azide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} |
| PubChem Substance ID | 5743232 |
| Reaxys-RN | 3761583 |
| Chemical Name Translation | 叠氮化四丁基铵 |
| InChIKey | GMRIOAVKKGNMMV-UHFFFAOYSA-N |
| LabNetwork Molecule ID | LN01746513 |
| InChI | InChI=1S/C16H36N.N3/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;1-3-2/h5-16H2,1-4H3;/q+1;-1 |
| Canonical SMILES | [N-]=[N+]=[N-].CCCC[N+](CCCC)(CCCC)CCCC |
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分类
- {SNA} Azidation/Diazo Transfer, Azide Sources, C-X Bond Formation (Non-Halogen), Chemical Biology, Chemical Synthesis, Conjugation Chemistry: Azides, Alkynes and Other Reagents, Synthetic Reagents
- {SNA} Azidation/Diazo Transfer, Azide Sources, C-X Bond Formation (Non-Halogen), Chemical Biology, Chemical Synthesis,
产品应用
- 有机叠氮化试剂
安全信息
GHS Symbol
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P332+P313
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- P302+P350
- P337+P313
- P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
- P403+P233
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
- P301+P310
- P273 Avoid release to the environment. 避免释放到环境中。
- P305+P351+P338
- P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
- P304+P340+P311
- H228 Flammable solid 易燃固体
- H315 Causes skin irritation 会刺激皮肤
- H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
- H319 Causes serious eye irritation 严重刺激眼睛
- H301 Toxic if swallowed 吞食有毒
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S27 Take off immediately all contaminated clothing 立即脱掉全部污染的衣服；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
- S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
- S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
- R32 Contact with acids liberates very toxic gas 与酸接触释放出毒性很高的气体
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- R24/25 Toxic in contact with skin and if swallowed 皮肤接触及吞食都有毒
- R50/53
- R25 Toxic if swallowed 吞咽有毒
