trans-1,2-Bis(diphenylphosphino)ethylene (E)-1,2-双(二苯基膦基)乙烯
CAS 983-81-3 MFCD00063219
化学结构图
SMILES: C(=C/P(c1ccccc1)c1ccccc1)\P(c1ccccc1)c1ccccc1
化学属性
| Mol. Formula | C26H22P2 |
|---|---|
| Mol. Weight | 396 |
| Melting Point | 123.0 to 127.0 deg-C |
| TSCA | No |
别名和识别编码
| Chemical Name | (E)-1,2-Bis(Diphenylphosphino)Ethene |
|---|---|
| MDL Number | MFCD00063219 |
| CAS Number | 983-81-3 |
| Synonym | (E)-1,2-Bis(diphenylphosphino)ethene TRANS-1,2-BIS(DIPHENYLPHOSPHINO)ETHYLENE 反-1,2-双(二苯基膦基)乙烯 反-1,2-双(二苯基磷基)乙烯 trans-vinylenebis[diphenylphosphine] (E)-Vinylenebis[diphenylphosphine] trans-1,2-Ethenediylbis(diphenylphosphine) NSC 132587 [(E)-1,2-Ethenediyl]bis(diphenylphosphine) [(E)-Vinylene]bis(diphenylphosphine) [(E)-Ethene-1,2-diyl]bis(diphenylphosphine) 反式-1,2-双(二苯基膦)乙烯 |
| PubChem Substance ID | 2733288 |
| EC Number | 213-570-2 |
| Beilstein Registry Number | 757793 |
| Chemical Name Translation | (E)-1,2-双(二苯基膦基)乙烯 |
| Reaxys-RN | 757793 |
| LabNetwork Molecule ID | LN01740638 |
| InChIKey | NCKJIJSEWKIXAT-QURGRASLSA-N |
| InChI | InChI=1S/C26H22P2/c1-5-13-23(14-6-1)27(24-15-7-2-8-16-24)21-22-28(25-17-9-3-10-18-25)26-19-11-4-12-20-26/h1-22H/b22-21+ |
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分类
- {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Phosphine Compounds, Polydentate Phosphine Ligands
相关文献及参考
安全信息
GHS Symbol
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P264+P265
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P302+P350
- P302+P352
- P302+P352+P332+P313+P362+P364
- P304+P340
- P305+P351+P338
- P305+P351+P338+P337+P313
- P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
- P319
- P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
- P332+P313
- P332+P317
- P337+P313
- P337+P317
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
- P362+P364
- P403+P233
- P405 Store locked up. 上锁保管。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S37 Wear suitable gloves 戴适当手套；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
其他信息
- TCI Shanghai:反-1,2-双(二苯基膦基)乙烯 trans-1,2-Bis(diphenylphosphino)ethylene,>;96.0%(T)(983-81-3)
- 敏感性:Air Sensitive
- Acros Organics:反-1,2-双(二苯基磷基)乙烯 trans-1,2-Bis(diphenylphosphino)ethylene, 97%(983-81-3)
- Sigma Aldrich:983-81-3(sigmaaldrich)
- MOL 文件:983-81-3.mol
- 反-1,2-双(二苯基磷基)乙烯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 B2003 反-1,2-双(二苯基膦基)乙烯 trans-1,2-Bis(diphenylphosphino)ethylene 1G 565元 2010/06/21 310040050 反-1,2-双(二苯基磷基)乙烯 trans-1,2-Bis(diphenylphosphino)ethylene 97% 5 GR 2843元 2010/06/21 310040010 反-1,2-双(二苯基磷基)乙烯 trans-1,2-Bis(diphenylphosphino)ethylene 97% 1 GR 704元
- 图谱信息:反-1,2-双(二苯基磷基)乙烯(983-81-3)核磁图( 1 HNMR) 反-1,2-双(二苯基磷基)乙烯(983-81-3)质谱(MS) 反-1,2-双(二苯基磷基)乙烯(983-81-3)核磁图( 13 CNMR)
- Alfa Aesar:反-1,2-双(二苯基膦基)乙烯,98% trans-1,2-Bis(diphenylphosphino)ethylene, 98%(983-81-3)
