(3S,7AR)-3-ISOPROPYL-7A-METHYL BICYCLIC LACTAM (3S-顺)-(+)-四氢-3-异丙基-7a-甲基吡咯并[2,1-b]噁唑-5(6H)-酮
CAS 98203-44-2 MFCD00467212
化学结构图
SMILES: CC(C)[C@H]1CO[C@]2(C)CCC(=O)N21
化学属性
| Mol. Formula | C10H17NO2 |
|---|---|
| Mol. Weight | 183.25 |
| Refractive index | n20/D 1.473(lit.) |
| Boiling Point | 70 °C/0.4 mmHg(lit.) |
| Density | 1.027 g/mL at 25 °C(lit.) |
别名和识别编码
| Chemical Name | (3S-cis)-(+)-Tetrahydro-3-isopropyl-7a-methylpyrrolo[2,1-b]oxazol-5(6H)-one |
|---|---|
| CAS Number | 98203-44-2 |
| PubChem Substance ID | 24860069 |
| MDL Number | MFCD00467212 |
| Chemical Name Translation | (3S-顺)-(+)-四氢-3-异丙基-7a-甲基吡咯并[2,1-b]噁唑-5(6H)-酮 |
| Synonym | (3S-顺)-(+)-四氢-3-异丙基-7a-甲基吡咯并[2,1-b]噁唑-5(6H)-酮 |
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分类
- {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Heterocyclic Building Blocks, Others
- Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Heterocyclic Building Blocks, Others
- {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Heterocyclic Building Blocks, Other Heterocyclic Building Blocks
相关文献及参考
- 1. Romo, D. Meyers, A.I. Tetrahedron 47 , 9503, (1991)
- 2. Fray, A.H. Meyers, A.I. J. Org. Chem. 61 , 3362, (1996)
- 3. Meyers, A.I. et al. J. Org. Chem. 60 , 4359, (1995)
- 4. Munchhoff, M.J. Meyers, A.I. J. Org. Chem. 60 , 7084, (1995)
- 5. Munchhoff, M.J. Meyers, A.I. J. Org. Chem. 60 , 7086, (1995)
- 6. Sandham, D.A. Meyers, A.I. J. Chem. Soc., Chem. Commun. , 2511, (1995)
- 7. Andres, C.S. Meyers, A.I. Tetrahedron Lett. 36 , 3491, (1995)
- 8. Andres, C.J. et al. Tetrahedron Lett. 60 , 3189, (1995)
- 9. Brengel, G.P. Meyers, A.I. J. Org. Chem. 61 , 3230, (1996)
- 10. Meyers, A.I. et al. J. Org. Chem. 61 , 2586, (1996) 摘要
- FT-IR 2 (1), 1349:B / FT-NMR 1 (1), 1298:C / RegBook 1 (1), 929:M / Structure Index 1 , 144:A:8
安全信息
GHS Symbol
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H226 Flammable liquid and vapour 易燃液体和蒸气
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
