CAS 98-11-3 MFCD00011689-Benzenesulfonic Acid 苯磺酸 TAO{mole}

Benzenesulfonic Acid 苯磺酸

CAS 98-11-3 MFCD00011689

化学结构图

SMILES: O=S(=O)(O)c1ccccc1

化学属性

Mol. Formula	C6H6O3S
Mol. Weight	158.18
Density	1.32
Flash Point	>110°C
TSCA	Yes
Melting Point	58.0 to 64.0 deg-C
Solubility	可溶
Stability	对湿度敏感
Boiling Point	137°C

别名和识别编码

Chemical Name	Benzenesulfonic Acid
Beilstein Registry Number	11(4)27
PubChem Substance ID	7371
CAS Number	98-11-3
MDL Number	MFCD00011689
Reaxys-RN	742513
Merck Number	1070
EC Number	202-638-7
Synonym	Benzensulfonic acid {LY} Benzensulfonic acid {} {LY} Benzensulfonic acid {} {} {LY} Benzensulfonic acid {} {} {} {LY} Benzensulfonic acid {} {} {} {} {LY} Benzensulfonic acid {} {} {} {} {} {LY} Benzensulfonic acid {} {} {} {} {} {} {LY} Benzensulfonic acid {} {} {} {} {} {} {} {LY} Benzensulfonic acid {} {} {} {} {} {} {} {} {LY} Benzensulfonic acid {} {} {} {} {} {} {} {} {} {LY} Benzensulfonic acid {} {} {} {} {} {} {} {} {} {} {LY} Benzensulfonic acid {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {LY} Benzensulfonic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Benzensulfonic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Benzensulfonic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Benzensulfonic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Benzensulfonic acid
Chemical Name Translation	苯磺酸
Wiswesser Line Notation	WSQR
LabNetwork Molecule ID	LN00220697
InChI	InChI=1S/C6H6O3S/c7-10(8,9)6-4-2-1-3-5-6/h1-5H,(H,7,8,9)
Canonical SMILES	O=S(C1=CC=CC=C1)(O)=O

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产品应用

检验铵盐和钾盐。锌的测定。有机合成。制造苯酚、间苯二酚。催化剂。用作脱水催化剂、树脂固化剂，以及电镀添加剂，同时还可以作为染料中间体。

安全信息

Precautionary statements

P303+P361+P353+P310+P363
P406 Store in corrosive resistant/… container with a resistant inner liner. 存放在耐腐蚀/具有耐性的内衬容器。
P305+P351+P338
P304+P340+P310
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P303+P361+P353
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P501 Dispose of contents/container to..… 处理内容物/容器.....
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P405 Store locked up. 上锁保管。
P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P390 Absorb spillage to prevent material damage. 吸收溢出物，防止重大损害。
P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。

GHS Symbol

Signal word

Hazard statements

H290 May be corrosive to metals 可能腐蚀金属。
H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
H302 Harmful if swallowed 吞食有害
H315 Causes skin irritation 会刺激皮肤
H318 Causes serious eye damage 严重伤害眼睛
H301 Toxic if swallowed 吞食有毒

Hazard Codes C C,Xn

WGK Germany1

RTECSDB4200000

UN Number UN 2583 8/PG 2 UN2586 UN2585 2585

Safety Statements

S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
S20 When using do not eat or drink 使用时，不得进食，饮水；

Risk Statements

R34 Causes burns 会导致灼伤
R22 Harmful if swallowed 吞咽有害
R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter

Packing GroupIII

Hazard Class8

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 890 uL/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AIHAAP American Industrial Hygiene Association Journal.  (AIHA, 475 Wolf
   Ledges Pkwy., Akron, OH 44311)  V.19-    1958-  Volume(issue)/page/year:
   23,95,1962

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Mammal - cat
DOSE/DURATION           : 10 gm/kg
TOXIC EFFECTS :
   Behavioral - tremor
   Behavioral - muscle weakness
   Gastrointestinal - changes in structure or function of salivary glands
REFERENCE :
   JPETAB Journal of Pharmacology and Experimental Therapeutics.  (Williams &
   Wilkins Co., 428 E. Preston St., Baltimore, MD 21202)  V.1-    1909/10-
   Volume(issue)/page/year: 84,358,1945

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Bird - wild bird species
DOSE/DURATION           : 75 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   TXAPA9 Toxicology and Applied Pharmacology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1959-  Volume(issue)/page/year:
   21,315,1972

其他信息

储运特性:通风低温干燥; 与库房食品原料分开存放
Acros Organics:苯磺酸 Benzenesulfonic acid, tech., 90%(98-11-3)
{
外观性质:无色针状或片状晶体。
用途四:检验铵盐和钾盐。锌的测定。有机合成。制造苯酚、间苯二酚。催化剂。用作脱水催化剂、树脂固化剂，以及电镀添加剂，同时还可以作为染料中间体。
用途一:用作实验试剂、催化剂，也用于有机合成及苯酚制造
灭火剂:干粉,泡沫,沙土,二氧化碳, 雾状水
类别:有毒物品
上游原料:氯化钠 --> 亚硫酸钠 --> Α-球蛋白 --> D-(S)-3-乙酰巯基-2-甲基丙酰基-L-脯氨酸 --> 苯磺酸钠
海关编码:29041000
图谱信息:苯磺酸(98-11-3)质谱(MS) 苯磺酸(98-11-3)红外图谱(IR2) 苯磺酸(98-11-3)红外图谱(IR1)
敏感性:Hygroscopic
急性毒性:口服-大鼠 LD50: 980 毫克/公斤; 口服-野鸟 LD50: 75 毫克/公斤
易吸湿。易溶于水和乙醇，微溶于苯，不溶于乙醚和二硫化碳。属氧化剂。低毒，半数致死量(大鼠，经口)890mg/kg。对皮肤、眼和黏膜有刺激性。
用途二:主要用于经碱熔制苯酚，也用于制间苯二酚等，在酯化和脱水反应中常用作催化剂
用途三:苯磺酸用于油田注水，可以解除地层的堵塞、提高地层渗透率。作为酸化注水井的酸，苯磺酸的特点是与碳酸盐反应慢，而且浓度愈大，反应速度愈慢，能酸化深远的地层，与盐酸相比，苯磺酸（及混合芳基磺酸）有效期长、腐蚀性小、使用安全。苯磺酸还用做酯化和脱水反应的催化剂和铸造工业的固化剂。
下游产品:硬脂酸 --> 碳酸氢铵 --> 香兰素 --> 磷酸精胺酸 --> 3,8-二氨基-5-甲基-6-苯基溴化菲啶盐 --> 4,4'-二氨基二苯甲烷 --> 酸性蓝 83 --> (Z)-4-癸烯醛 --> 乙氧基喹啉 --> 酸性黑26 --> 荧光增白剂 220 --> 毛用活性蓝 PW-3R --> 二羟基二苯砜酚磺酸尿素甲醛缩合物
方法一:以苯为原料，经硫酸磺化而得。将93%硫酸2400L加入磺化锅内，将苯以2500-3000L/h的流量打入蒸发器，经过蒸发及过热成温度为150℃以上的过热苯蒸气，通过鼓泡器在硫酸层中进行反应，温度在170℃左右，最后游离酸控制在4-5%。大约经过10h左右完成反应，未反应的苯蒸气和生成的水蒸气经冷凝分离，酸性苯再经液碱中和、食盐脱水后循环使用。含苯的苯磺酸再经真空脱苯器脱除余苯。磺化收率96.5%。苯磺酸用亚硫酸钠或氢氧化钠中和，即得苯磺酸钠。中和收率99%。原料消耗定额：苯600kg/t、发烟硫酸750kg/t。
Alfa Aesar:苯磺酸,tech.ca75%w/waq.soln. Benzenesulfonic acid, tech. ca 75% w/w aq. soln.(98-11-3)
MOL 文件:98-11-3.mol
易吸湿。易溶于水和乙醇，微溶于苯，不溶于乙醚和二硫化碳。属氧化剂。低毒，半数致死量(大鼠，经口)890mg/kg。对皮肤、眼和黏膜有刺激性
苯磺酸价格(试剂级):更新日期产品编号产品名称包装价格 2011/08/23 30017628 苯磺酸 500ml 158元 2011/04/16 B3408 无水苯磺酸 Benzenesulfonic Acid Anhydrous 5G 407元 2010/06/21 159020250 苯磺酸 Benzenesulfonic acid 90%, tech. 25 GR 113元
防护措施:对皮肤、眼、呼吸道有刺激作用。其钠盐无毒。操作中应穿戴防护用具。大鼠经口LD50为890mg/kg，猫经皮肤LD50 为10mg/kg。
刺激数据:皮肤-兔子
毒性分级:高毒