CAS 97-02-9 MFCD00007151-2,4-Dinitroaniline, 98% 2,4-二硝基苯胺 TAO{mole}

2,4-Dinitroaniline, 98% 2,4-二硝基苯胺

CAS 97-02-9 MFCD00007151

化学结构图

SMILES: Nc1ccc([N+](=O)[O-])cc1[N+](=O)[O-]

化学属性

Mol. Formula	C6H5N3O4
Mol. Weight	183
Melting Point	176-178
Density	1.61
Flash Point	224°(435°F)
TSCA	Yes
Solubility	0.06 G/L (20 ºC)
Stability	对光敏感

别名和识别编码

Chemical Name	2,4-Dinitroaniline, 98%
MDL Number	MFCD00007151
CAS Number	97-02-9
Synonym	2,4-Dinitroaniline {LY} 2,4-Dinitroaniline 2,4-Dinitrobenzamine 2,4-Dinitrobenzenamine 2,4-dinitro-Benzenamine 2,4-dinitro-anilin 2,4-dinitro-aniline 2,4-dinitro-benzenamin 2,4-dinitrophenylamine 2,4-二硝基苯胺 2,4-二硝基苯胺, 99% (DRY WT.), CONT. UP TO 15% WATER 2,4-二硝苯胺 2,4-硝基苯胺 2.4-二硝基苯胺 2,4-DINITROANILINE 4-二硝基苯,间二硝基苯胺 Benzenamine, 2,4-dinitro- DNA NCI-C60753 dinitro-2,4aniline {} {LY} 2,4-Dinitroaniline {} {} {LY} 2,4-Dinitroaniline {} {} {} {LY} 2,4-Dinitroaniline {} {} {} {} {LY} 2,4-Dinitroaniline {} {} {} {} {} {Chemicalbook {} {} {} {} {} {uni_hamburg} 2,4-Dinitroanilin {} {} {} {} {} {} {Chemicalbook} 2,4-Dinitroaminobenzene {} {} {} {} {} {} {} {uni_hamburg} 2,4-Dinitro {} {} {} {} {} {} {} {} {Chemicalbook} 2,4-DINITROANILI
PubChem Substance ID	87569112
EC Number	202-553-5
Beilstein Registry Number	982999
Merck Number	3270
Reaxys-RN	982999
Chemical Name Translation	2,4-二硝基苯胺
Wiswesser Line Notation	WNR BZ ENW
LabNetwork Molecule ID	LN00195996
Canonical SMILES	NC1=CC=C([N+]([O-])=O)C=C1[N+]([O-])=O

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品牌质保精细包装现货库存一流品牌服务

产品应用

用作偶氮染料中间体，腐蚀抑制剂，分析试剂。检验酚和某些不饱和烃，有机合成。

安全信息

GHS Symbol

WGK Germany2

Hazard statements

H301 Toxic if swallowed 吞食有毒
H330 Fatal if inhaled 吸入致命
H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
H310 Fatal in contact with skin 皮肤接触致命
H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
H300 Fatal if swallowed 吞食致命

Precautionary statements

P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
P301+P316
P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
P405 Store locked up. 上锁保管。
P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛，皮肤或衣服。
P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
P501 Dispose of contents/container to..… 处理内容物/容器.....
P284 Wear respiratory protection.? 佩戴呼吸保护装置。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P302+P352
P304+P340
P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
P361+P364
P319
P273 Avoid release to the environment. 避免释放到环境中。
P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P330 Rinse mouth. 漱口
P403+P233
P320 Specific treatment is urgent (see … on this label). 紧急具体治疗（见本标签上的）。

Signal word Danger

RTECSBX9100000

Personal Protective Equipment dust mask type N95 (US), Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges

Safety Statements

S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；

Packing GroupII

UN Number 1596

Risk Statements

R33 Danger of cumulative effects 有累积作用的危险
R51/53
R26/27/28 Very toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有剧毒

Hazard Codes 6.1

Hazard Class6.1

Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {Chemicalbook} Flammables area 密封避光保存。

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 285 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   TSCAT* Office of Toxic Substances Report.  (U.S. Environmental Protection
   Agency, Office of Toxic Substances, 401 M St., SW, Washington, DC 20460)
   Volume(issue)/page/year: OTS 206512

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - guinea pig
DOSE/DURATION           : 1050 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 47(10),15,1982

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 250 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NCNSA6 National Academy of Sciences, National Research Council,
   Chemical-Biological Coordination Center, Review.  (Washington, DC)
   Volume(issue)/page/year: 5,32,1953

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 370 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 25(8),50,1981

TYPE OF

TYPE OF TEST            : Unscheduled DNA synthesis
TEST SYSTEM             : Rodent - rat Liver
DOSE/DURATION           : 50 umol/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 221,263,1989

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 10 ug/plate
REFERENCE :
   ENMUDM Environmental Mutagenesis.  (New York, NY)  V.1-9, 1979-87.  For
   publisher information, see EMMUEG.  Volume(issue)/page/year: 5(Suppl
   1),3,1983

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 2 ug/plate
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 67,1,1979

TYPE OF TEST            : TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 17 mg/m3/4H
SEX/DURATION            : female 1-7 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Effects on Embryo or Fetus - fetal death
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 26(6),47,1982

TYPE OF TEST            : TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 1100 ug/m3/4H
SEX/DURATION            : female 1-7 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death,
   e.g., stunted fetus)
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 26(6),47,1982

TYPE OF TEST            : TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 17 mg/m3/4H
SEX/DURATION            : female 1-7 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Fertility - pre-implantation mortality (e.g. reduction in
   number of implants per female; total number of implants per corpora lutea)
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 26(6),47,1982

Warnings 危险化学品

其他信息

方法一:由2,4-二硝基氯苯加压氨解而得。在氨解反应锅内加入15kg拉开粉（1,2-二丁基萘-6-磺酸钠）、300kg2,4-二硝基氯苯、1350L氨水（含氨150kg），加热，在1h左右升温到80℃，停止加热。控制反应温度为108-110℃，压力为0.35-0.4MPa。保温反应4h后泄压。放出的氨气用水吸收回用。反应液冷却至35℃以下过滤，滤饼用冷水洗涤到接近中性，得成品。收率90-95%。
上游原料:氨 --> 4-氯苯甲醛 --> 2,4-二硝基氯苯 --> 磺酸钠 --> 工业氨水 --> 丁基萘磺酸钠
刺激数据:眼睛-兔子 500 毫克/24小时轻度
图谱信息:2,4-二硝基苯胺(97-02-9)核磁图( 1 HNMR) 2,4-二硝基苯胺(97-02-9)质谱(MS) 2,4-二硝基苯胺(97-02-9)红外图谱(IR1) 2,4-二硝基苯胺(97-02-9)核磁图( 13 CNMR) 2,4-二硝基苯胺(97-02-9)红外图谱(IR2)
储运特性:库房通风低温干燥; 与氧化剂、食品添加剂、酸类分开存放
类别:有毒物品
Alfa Aesar:2,4-二硝基苯胺,99%(drywt.),cont.upto15%water 2,4-Dinitroaniline, 99% (dry wt.), cont. up to 15% water(97-02-9)
急性毒性:口服-大鼠 LD50: 285 毫克/公斤; 口服-小鼠 LD50: 370 毫克/公斤
用途一:用于制造偶氮染料及分散染料，也可用作印刷油墨的调色剂和制取防腐剂等
TCI Shanghai:2,4-二硝基苯胺 2,4-Dinitroaniline,>;99.0%(GC)(97-02-9)
灭火剂:雾状水、泡沫、二氧化碳、干粉、砂土。
用途三:用作偶氮染料中间体，腐蚀抑制剂，分析试剂。检验酚和某些不饱和烃，有机合成。
MOL 文件:97-02-9.mol
海关编码:29214210
可燃性危险特性:明火可燃; 高热分解有毒氮氧化物烟雾;与氧化剂反应
下游产品:分散兰 79 --> 2-溴-4,6-二硝基苯胺 --> 4-硝基邻苯二胺 --> 颜料橙 5 --> 硫化黄9 --> N-(2,4-二硝基苯基)乙酰胺
与稀无机酸不能形成盐类。溶于乙醚等许多有机溶剂，微溶于乙醇、沸水，溶解度:0.06 g/l 水(20 C)，0.7% 乙醇 (21 C).溶于热盐酸，几乎不溶于冷水。中等毒，半数致死量(大鼠，经口)418mg/kg。有刺激性。商品常含15%水润湿。
毒性分级:高毒
MSDS 信息:2,4-二硝基苯胺(97-02-9).msds
Acros Organics:2，4-硝基苯胺 2,4-Dinitroaniline, 99%(97-02-9)
Sigma Aldrich:97-02-9(sigmaaldrich)
2,4-二硝基苯胺价格(试剂级):更新日期产品编号产品名称包装价格 2011/08/23 80054524 2，4-二硝基苯胺;1-氨基-2,4-二硝基苯 25g 18元 2011/08/23 80054560 2，4-二硝基苯胺;1-氨基-2,4-二硝基苯 25g 20元 2011/04/16 D0814 2,4-二硝基苯胺 2,4-Dinitroaniline 25G 124元
职业标准:STEL 0.3 毫克/立方米
外观性质:黄色针状结晶。
用途二:该品是分散染料、中性染料、硫化染料、有机颜料的中间体。用于生产硫化深蓝3R、分散红B、分散紫2R等染料。也用于其他有机合成，生产农药二硝散等，以及用作印刷油墨的调色剂和制取防腐剂。