Triphenylborane 三苯基硼烷

CAS 960-71-4 MFCD00003007

化学结构图

960-71-4
SMILES: c1ccc(B(c2ccccc2)c2ccccc2)cc1

化学属性

Mol. FormulaB(C6H5)3
Mol. Weight242
Boiling Point203 °C/15 mmHg(lit.)
Density0.898 g/mL at 25 °C
Melting Point145 °C(lit.)
TSCAYes
Flash Point1 °F
Appearance powder

别名和识别编码

Chemical NameTriphenylborane
CAS Number960-71-4
PubChem Substance ID70400
MDL NumberMFCD00003007
Synonym triphenyl-boran 三苯基硼烷 triphenylborane solution 三苯基硼烷 溶液 TRIPHENYLBORON, POWDER, WATER <2% triphenyl-borane Borane, triphenyl- 三苯基硼 Triphenyboron Bortriphenyl Borine, triphenyl- Triphenylborine Triphenylboron, min. 95% TRIPHENYLBORINE 三苯硼[烷] BORON TRIPHENYL Methylquecksilber(II)-chlorid 13% Cl TRIPHENYLBORON borine,triphenyl Triphenylboron Triphenylborane Triphenylbor C18H15B Triphenylboron,min.95% TRIPHENYLBORANE
EC Number213-504-2
Beilstein Registry Number1961313
Chemical Name Translation三苯基硼烷
InChIKeyMXSVLWZRHLXFKH-UHFFFAOYSA-N
LabNetwork Molecule IDLN01363619
InChIInChI=1S/C18H15B/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18/h1-15H
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分类

  • {SNA} Boron, CVD and ALD Precursors by Metal, Materials Science, Micro/NanoElectronics, Vapor Deposition Precursors
  • {SNA} Boron, Micro/NanoElectronics, Solution Deposition Precursors, 材料科学
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment
  • {SNA} Alphabetical Index of Analytical Standards, Analytical Standards, Boron, Micro/NanoElectronics, Solution Deposition Precursors, T, TP - TZ, 分析/色谱, 材料科学
  • {SNA} Alphabetical Index of Analytical Standards, Analytical Standards, Analytical/Chromatography, Boron, Materials Science, Micro/NanoElectronics, Solution D
  • {SNA} Boron, CVD and ALD Pre

相关文献及参考

  • Beil. 16 ,IV,1623
  • Corp MSDS 1 (2), 3516:A / FT-IR 1 (2), 1134:C / FT-IR 2 (3), 4458:D / IR-Spectra (2), 1327:D / IR-Spectra (3), 1552:F / NMR-Reference 2 (2), 1013:B / RegBook 1 (2), 3027:I / Structure Index 1 , 479:E:1
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15
  • Short: III/35A Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts and Coupling Constants for Boron-11 and Phosphorus-31 Author: Gupta, R.R.; Jain, M.; Pardasani, P.; Pardasani, R.T.; Pelter, A. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35A Year: 1997 ISBN: 3-540-60366-2 ISBN: 978-3-540-60366-5 Internet Resource: DOI:10.1007/b53033 RefComment: VIII, 242 pages. With CD-ROM. Hardcover Abstract: This volume provides a comprehensive and evaluated compilation of nuclear magnetic resonance data. Chemical shifts and coupling constants of boron-11 and phosphorus-31 (subvol. A), fluorine-19 and nitrogen-15 (subvol. B), hydrogen-1 (subvol. C), and carbon-13 (subvol. D) compounds are tabulated together with the gross- and structure formulas and the most readily available solvents. Due to the large amount of the data merely chemical shifts are presented in the printed versions, and all the data, chemical shifts and coupling constants are provided on CO-ROM's.

安全信息

GHS Symbol
WGK Germany3
Hazard Codes Xn;F F F,Xn
Hazard statements
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H228 Flammable solid 易燃固体
  • H302 Harmful if swallowed 吞食有害
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H351 Suspected of causing cancer 怀疑致癌
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P281 Use personal protective equipment as required. 使用所需的个人防护装备。
  • P301+P312+P330
  • P305+P351+P338
  • P370+P378
  • P403+P235
Signal word Danger Warning
RTECSED2367500
Safety Statements
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
  • S22 Do not breathe dust 不要吸入粉尘；
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S39 Wear eye/face protection 戴眼睛/面孔保护装置；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S33 Take precautionary measures against static discharges 对静电采取预防措施；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
UN Number UN1325 UN 1993 3/PG 2 1993
Risk Statements
  • R11 Highly flammable 非常易燃
  • R19 May form explosive peroxides 可能生成易爆的过氧化物质
  • R36/37 Irritating to eyes and respiratory system 对眼睛和呼吸系统有刺激性
  • R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
  • R22 Harmful if swallowed 吞咽有害
Storage condition Air Sensitive
Personal Protective Equipment Eyeshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Packing GroupIII
Hazard Class4.1

其他信息

  • 灭火剂:干粉、二氧化碳
  • Alfa Aesar:三苯基硼 Triphenylborane, 96%(960-71-4)
  • Sigma Aldrich:960-71-4(sigmaaldrich)
  • 毒性分级:高毒
  • 三苯基硼烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/05/25 32589 三苯基硼 Triphenylborane, 96% 5g 1375元 2010/05/25 32589 三苯基硼 Triphenylborane, 96% 25g 5936元 2010/05/25 32589 三苯基硼 Triphenylborane, 96% 1g 322元
  • 敏感性:Air Sensitive
  • 下游产品:二苯基酸
  • 储运特性:库房通风低温干燥; 防潮;与食品、氧化剂分开储运
  • F:10-23
  • MOL 文件:960-71-4.mol
  • 可燃性危险特性:遇热、明火燃烧; 火场放出硼化物辛辣刺激烟雾
  • TSCA:No
  • 刺激数据:眼睛- 兔 110 毫克/ 24小时 重度
  • 急性毒性:口服- 大鼠 LD50: 196 毫克/ 公斤
  • 类别:有毒物品

系列性分类

  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Boron 硼
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Boronic Acids and Derivatives 硼酸和硼酸衍生物
  4. Others - Boronic Acids and Derivatives
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Alphabetic - Analytical Standards
  4. T - Alphabetic
  5. TP - TZ - T
  1. Materials Science 材料科学
  2. Micro/NanoElectronics - Materials Science
  3. Solution Deposition Precursors - Micro/NanoElectronics
  4. Boron - Solution Deposition Precursors
  1. Materials Science 材料科学
  2. Micro/NanoElectronics - Materials Science
  3. Vapor Deposition Precursors - Micro/NanoElectronics
  4. CVD and ALD Precursors by Metal - Vapor Deposition Precursors
  5. Boron - CVD and ALD Precursors by Metal
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Boronic Acids and Derivatives 硼酸和硼酸衍生物
  4. Boranes

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