Allyl Methacrylate 甲基丙烯酸烯丙酯

CAS 96-05-9 MFCD00008592

化学结构图

96-05-9
SMILES: C=CCOC(=O)C(=C)C

化学属性

Mol. FormulaC7H10O2
Mol. Weight126
Refractive index1.4340 to 1.4370
Boiling Point59-61
Density0.938
Flash Point35°C(lit.)
TSCAYes
Melting Point-65°C
Vapor Pressure4.6 mmHg ( 20 °C)
Solubility4 G/L (20 ºC)

别名和识别编码

Chemical NameAllyl Methacrylate
CAS Number96-05-9
PubChem Substance ID87572188
EC Number202-473-0
Beilstein Registry Number1747406
MDL NumberMFCD00008592
Reaxys-RN1747406
Synonym METHACRYLIC ACID ALLYL ESTER 2-甲基-2-丙烯酸-2-丙烯基酯 Sipomer AM 甲基丙烯酸烯丙基酯 烯丙基甲基丙烯酸酯 Allyl methacrylate, stabilized, 98% 2-methyl-2-propenoicaci2-propenylester ageflexama Methacrylic acid allyl ester 甲基丙烯酸烯丙酯; 2-甲基丙烯酸烯丙酯 ALLYL METHACRYLATE methacrylic acid allyl ester 2-Methyl-2-propenyl 2-propenoate Methacrylsäureallylester 2-methyl-2-propenoic acid, vinylmethyl ester 2-甲基丙烯酸烯丙酯 Allyl methacrylate ALLYL METHACRYLATE, STAB. METHACRYLIC ACID ALLYL ESTER (STABILIZED WITH MEHQ) 97+% SR-201 Methacrylic acid, allyl ester 2-Propenyl 2-methylpropenoate Allyl 2-methylacrylate 2-Propenoic acid, 2-methyl-, 2-propenyl ester Allylmethacrylate,97% Allyl ester of Methacrylic acid 2-Methyl-2-propenyl-2-propensäureester 2-Propenoicacid,2-methyl-,2-propenylester Methacrylsäure-allylester 甲基丙烯酸烯丙酯 Ageflex ama methylacrylic acid-allyl ester Ageflex AMA Allylester kyseliny methakrylove 甲基丙烯酸烯丙酯, 97%, 100PPM的4-甲氧基苯酚作稳定剂 苯烯酰氯 Allylmethacrylat allylesterkyselinymethakrylove 丙烯甲基丙烯酸 ALLYL A-METHYLACRYLATE
Chemical Name Translation甲基丙烯酸烯丙酯
Wiswesser Line Notation1UY1&VO2U1
LabNetwork Molecule IDLN00227050
InChIInChI=1S/C7H10O2/c1-4-5-9-7(8)6(2)3/h4H,1-2,5H2,3H3
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分类

  • {uni_hamburg} no charge; ester; 1fragment
  • Acrylic Monomers, Building Blocks, C6 to C7, Carbonyl Compounds, Chemical Synthesis,
  • {SNA} Acrylic Monomers, Building Blocks, C6 to C7, Carbonyl Compounds, Chemical Synthesis, Esters, Materials Science, Methacrylate, Monomers, Organic Building Blocks, Polymer Science
  • {SNA} Acrylic Monomers, Building Blocks, C6 to C7, Carbonyl Compounds, Chemical Synthesis, Esters, Methacrylate, Monomers, Organic Building Blocks, Polymer Science, 材料科学

相关文献及参考

  • Short: IV/8H
  • Short: EINECS
  • Beilstein:2(3)1290

安全信息

GHS Symbol
WGK Germany2
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
  • H331 Toxic if inhaled 吸入中毒
  • H312 Harmful in contact with skin 皮肤接触有害
  • H302 Harmful if swallowed 吞食有害
  • H330 Fatal if inhaled 吸入致命
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
  • H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
  • H311 Toxic in contact with skin 皮肤接触中毒
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes 6.1 F,T+,N T,N
RTECSUD3483000
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P241+P242+P243
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P310+P330
  • P302+P352+P312+P361+P364
  • P303+P361+P353
  • P304+P340+P310
  • P304+P340+P311
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
  • P337+P313
  • P370+P378
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
Risk Statements
  • R10 Flammable 易燃
  • R21/22 Harmful in contact with skin and if swallowed 皮肤接触和不慎吞咽有害
  • R23 Toxic by inhalation 吸入有毒
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R50 Very toxic to aquatic organisms 对水生生物极毒
UN Number 2929
Packing GroupII
Storage condition 密封保存 2-8°C
Hazard Class6.1/3
TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1800 mg/m3
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 34(8),59,1990

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 5500 mg/m3
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 34(8),59,1990

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 57 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 34(8),59,1990

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 500 uL/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AIHAAP American Indu

Warnings 危险化学品

其他信息

  • 甲基丙烯酸烯丙酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 M0075 甲基丙烯酸烯丙酯(含稳定剂MEHQ) Allyl Methacrylate (stabilized with MEHQ) 500ML 373元 2014/06/02 M0075 甲基丙烯酸烯丙酯(含稳定剂MEHQ) Allyl Methacrylate (stabilized with MEHQ) 25ML 137元 2010/06/21 215875000 甲基丙烯酸烯丙酯 Allyl methacrylate 98%, stabilized 500 ML 773元
  • 海关编码:29161490
  • 图谱信息:甲基丙烯酸烯丙酯(96-05-9)Raman光谱 甲基丙烯酸烯丙酯(96-05-9)质谱(MS) 甲基丙烯酸烯丙酯(96-05-9)红外图谱(IR1) 甲基丙烯酸烯丙酯(96-05-9)核磁图( 13 CNMR)
  • 刺激数据:皮肤-兔子 20毫克/24小时 中度; 眼睛-兔子 500 毫克/24小时 轻度
  • 毒性分级:中毒
  • 可燃性危险特性:可燃;燃烧产生刺激烟雾
  • Sigma Aldrich:96-05-9(sigmaaldrich)
  • 用途一:广泛用作有机玻璃制备中共聚单体、接枝单体及牙齿修补交联剂等
  • 蒸气压:4.6 mm Hg ( 20 °C)
  • TCI Shanghai:甲基丙烯酸烯丙酯 Allyl Methacrylate (stabilized with MEHQ),>;97.0%(GC)(96-05-9)
  • 储运特性:库房通风低温干燥; 与食品原料分开存放
  • MSDS 信息:Allyl methacrylate(96-05-9).msds
  • 灭火剂:干粉、泡沫、砂土、二氧化碳, 雾状水
  • MOL 文件:96-05-9.mol
  • Acros Organics:甲基丙烯酸烯丙酯 Allyl methacrylate, stabilized, 98%(96-05-9)
  • Alfa Aesar:甲基丙烯酸烯丙酯,97%,100ppm的4-甲氧基苯酚作稳定剂 Allyl methacrylate, 97%, stab. with 100 ppm 4-methoxyphenol(96-05-9)
  • 急性毒性:口服-大鼠LD50: 430毫克/公斤; 吸入-大鼠LCL0: 500 PPM
  • 类别:有毒物品

系列性分类


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