2,3,4,9-Tetrahydro-1H-carbazole 1,2,3,4-四氢咔唑
CAS 942-01-8 MFCD00004959
化学结构图
SMILES: c1ccc2c3c([nH]c2c1)CCCC3
化学属性
| Mol. Formula | C12H13N |
|---|---|
| Mol. Weight | 171.24 |
| Melting Point | 118-120°C |
| TSCA | No |
| Boiling Point | 325-330°C at 760 mmHg |
别名和识别编码
| Chemical Name | 2,3,4,9-Tetrahydro-1H-carbazole |
|---|---|
| MDL Number | MFCD00004959 |
| CAS Number | 942-01-8 |
| EC Number | 213-385-7 |
| Beilstein Registry Number | 133771 |
| PubChem Substance ID | 13664 |
| Alfabeta Name | TETRAHYDROCARBAZOLE H23491---,,, |
| Synonym | 2,3,4,9-Tetrahydro-1H-carbazole {LY} 2,3,4,9-Tetrahydro-1H-carbazole {} {LY} 2,3,4,9-Tetrahydro-1H-carbazole {} {} {LY} 2,3,4,9-Tetrahydro-1H-carbazole {} {} {} {LY} 2,3,4,9-Tetrahydro-1H-carbazole {} {} {} {} {LY} 2,3,4,9-Tetrahydro-1H-carbazole {} {} {} {} {} {LY} 2,3,4,9-Tetrahydro-1H-carbazole {} {} {} {} {} {} {LY} 2,3,4,9-Tetrahydro-1H-carbazole {} {} {} {} {} {} {} {LY} 2,3,4,9-Tetrahydro-1H-carbazole {} {} {} {} {} {} {} {} {LY} 2,3,4,9-Tetrahydro-1H-carbazole {} {} {} {} {} {} {} {} {} {LY} 2,3,4,9-Tetrahydro-1H-carbazole {} {} {} {} {} {} {} {} {} {} {LY} 2,3,4,9-Tetrahydro-1H-carbazole {} {} {} {} {} {} {} {} {} {} {} {LY} 2,3,4,9-Tetrahydro-1H-carbazole {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,3,4,9-Tetrahydro-1H-carbazole {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,3,4,9-Tetrahydro-1H-carbazole {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,3,4,9-Tetrahydro-1H-carbazole {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,3,4,9-Tetrahydro-1H-car |
| InChIKey | HYKFPJAARRNNRX-UHFFFAOYSA-N |
| Chemical Name Translation | 1,2,3,4-四氢咔唑 |
| Reaxys-RN | 133771 |
| LabNetwork Molecule ID | LN00175886 |
| InChI | InChI=1S/C12H13N/c1-3-7-11-9(5-1)10-6-2-4-8-12(10)13-11/h1,3,5,7,13H,2,4,6,8H2 |
| Canonical SMILES | C1(NC2=C3C=CC=C2)=C3CCCC1 |
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信息真实价格透明
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分类
- {SNA} Building Blocks, Carbazoles, Chemical Synthesis, Heterocyclic Building Blocks
相关文献及参考
- Deprotonation with excess superbasic n-BuLi/KO-t-Bu to give the N,ɑ-dianion has been studied in a variety of ether solvents. Formation of substantial amounts of the ɑ-ethyl derivative was observed with Et2O and THF, and also, remarkably, with various alkyl methyl ethers; e.g. in n-BuOMe, the ɑ-ethyl product was obtained in 60% yield. The ethyl group originates from the interaction of the solvent with the strong base, confirmed by the detection of ethylene in the absence of the tetrahydrocarbazole substrate: J. Org. Chem., 60, 8334 (1995). ɑ-Ethylation also occurred with 2-ethylindole, but not with 2-methyl- or 2-isopropyl analogues.
- Photooxygenation with singlet oxygen, followed by reduction of the expected hydroperoxide to the allylic alcohol, is accompanied by ring contraction to a spiro ketone. The same product is formed in high yield on treatment of the spiroketone with mineral acid: J. Org. Chem., 61, 810 (1996):
安全信息
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S37 Wear suitable gloves 戴适当手套；
- S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
GHS Symbol
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P302+P352+P332+P313+P362+P364
- P305+P351+P338
- P305+P351+P338+P337+P313
- P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
- P332+P313
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- H303 May be harmfully swallowed 吞食可能有害
