CAS 900-95-8 MFCD00014977-Fentin acetate 三苯基乙酸锡 TAO{mole}

Fentin acetate 三苯基乙酸锡

CAS 900-95-8 MFCD00014977

化学结构图

SMILES: CC(=O)O[Sn](c1ccccc1)(c1ccccc1)c1ccccc1

化学属性

Mol. Formula	C₂₀H₁₈O₂Sn
Mol. Weight	409.07
TSCA	Yes
Melting Point	>118ºC (dec.)
Solubility	28 MG/L (20 ºC)
Density	1.55
Boiling Point	-
Flash Point	-

别名和识别编码

Chemical Name	Triphenyltin Acetate
Synonym	(acetyloxy)triphenyl-Stannane (acetyloxy)triphenylsta Acetate de triphenyl-etain Acetatotriphenylstannane Acetoxy-triphenyl-stannan Acetoxy-triphenylstannane Acetoxytriphenylstannane; Triphenylacetoxytin; Triphenyltin acetate; TPTA Acetyloxytriphenylz BATASAN(R) BRESTAN Batasan Betafen Brestan Brestan 60 Brestanid ENT 25208 F Fenolovo acetate Fentin acetaat Fentin acetat Fentin acetate Fentine acetate HOE-2824 Liromatin OMS 1020 PHENTINOACETATE Phentin acetate Phentinoacetate SUZU SUZU(R) Stannane, acetoxytriphenyl- TPTA {
Beilstein Registry Number	4146107
PubChem Substance ID	16682804
CAS Number	900-95-8
EC Number	212-984-0
MDL Number	-
Merck Number	14,9745
Chemical Name Translation	三苯基乙酸锡
Wiswesser Line Notation	1VO-SN-R&R&R
InChI	InChI=1S/3C6H5.C2H4O2.Sn/c31-2-4-6-5-3-1;1-2(3)4;/h31-5H;1H3,(H,3,4);/q;;;;+1/p-1
Canonical SMILES	-

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分类

{SNA} 2000/60/EC, Additional Standards, Algicides, Analytical Standards, Baby Food Directives 13/2003 EC & 14/2003 EC, E-G, European Community: ISO, DIN and DL 152, Food and Cosmetic Component Standards, Fungicides, Method and Regulation Specific, Molluscicides, Organotins, Others, Standards for Personal Care and Cosmetic Products, neats, prohibited substances (EU-REGULATION No 1223/2009), 农残和代谢标准品, 农残标准品, 分析/色谱, 按照字母排序
{Chemicalbook} 农药: 杀菌剂: 化学保护剂
{SNA} 2000/60/EC, Algicides, Alphabetical Index of Analytical Standards, Analytical Standards, Analytical/Chromatography,

安全信息

Precautionary statements

P201 Obtain special instructions before use. 使用前获取专门指示。
P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
P203
P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛，皮肤或衣服。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P264+P265
P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
P273 Avoid release to the environment. 避免释放到环境中。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P281 Use personal protective equipment as required. 使用所需的个人防护装备。
P284 Wear respiratory protection.? 佩戴呼吸保护装置。
P301+P310
P301+P316
P302+P352
P304+P340
P304+P340+P310
P305+P351+P338
P305+P354+P338
P307+P311
P308+P311
P308+P313
P308+P316
P309+P311
P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医，如果你觉得不舒服
P316
P317
P318
P319
P320 Specific treatment is urgent (see … on this label). 紧急具体治疗（见本标签上的）。
P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
P322 Specific measures (see …on this label). 具体治疗（见本标签上的）。
P330 Rinse mouth. 漱口
P332+P313
P332+P317
P333+P313
P333+P317
P361 Remove/Take off immediately all contaminated clothing. 立即去除/脱掉所有被污染的衣服。
P361+P364
P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
P362+P364
P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
P403+P233
P405 Store locked up. 上锁保管。
P501 Dispose of contents/container to..… 处理内容物/容器.....

RTECSWH6650000

GHS Symbol

Signal word Danger

Hazard statements

H301 Toxic if swallowed 吞食有毒
H301+H311
H311 Toxic in contact with skin 皮肤接触中毒
H315 Causes skin irritation 会刺激皮肤
H318 Causes serious eye damage 严重伤害眼睛
H330 Fatal if inhaled 吸入致命
H335 May cause respiratory irritation 可能导致呼吸道刺激
H351 Suspected of causing cancer 怀疑致癌
H361 Suspected of damaging fertility or the unborn child 怀疑对生育能力或未出生婴儿造成伤害
H361d Suspected of damaging the unborn child 怀疑对未出生婴儿造成伤害
H371 May cause damage to organs 可能导致器官损伤
H372 Causes damage to organs through prolonged or repeated exposure 长期或频繁接触会损伤器官
H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。

Hazard Codes T+,N T+;N,N,T+ T+;N

WGK Germany3

Personal Protective Equipment dust mask type N95 (US), Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges

Safety Statements

S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；

UN Number 3146 UN3146

Risk Statements

R24/25 Toxic in contact with skin and if swallowed 皮肤接触及吞食都有毒
R37/38 Irritating to respiratory system and skin 对呼吸系统和皮肤有刺激性
R63 Possible risk of harm to the unborn child 可能危害未出生婴儿
R48/23
R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
R26 Very toxic by inhalation 吸入极毒
R50/53

Packing GroupIII

Hazard Class6.1

Storage condition 4°C APPROX 4°C

Warnings 危化品目录(2015) 危险化学品

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 132 gm/kg/78W-I
TOXIC EFFECTS :
   Tumorigenic - neoplastic by RTECS criteria
   Liver - tumors
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: PB223-159

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 30 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85DPAN "Wirksubstanzen der Pflanzenschutz und Schadlingsbekampfungsmittel,"
   Perkow, W., Berlin, Verlag Paul

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - guinea pig
DOSE/DURATION           : 21 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85GYAV "Pflanzenschutz-und Schaedlingsbekaempfungsmittel: Abriss einer
   Toxikologie und Therapie von Vergiftungen," 2nd ed., Klimmer, O.R.,
   Hattingen, Fed. Rep. Ger., Hundt-Verlag, 1971  Volume(issue)/page/year:
   -,127,1971

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 81 mg/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
REFERENCE :
   BJIMAG British Journal of Industrial Medicine.  (British Medical Journal,
   Box 560B, Kennebunkport, ME 04046)  V.1-    1944-  Volume(issue)/page/year:
   23,222,1966

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 18 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems
   Laboratory, NIOSH Exchange Chemicals.  (Aberdeen Proving Ground, M

TYPE OF TEST            : Mutation test systems - not otherwise specified
TEST SYSTEM             : Rodent - hamster Ovary
DOSE/DURATION           : 60 ug/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 300,5,1993

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 380 mg/kg
SEX/DURATION            : male 19 day(s) pre-mating
TOXIC EFFECTS :
   Reproductive - Paternal Effects - testes, epididymis, sperm duct
REFERENCE :
   JEENAI Journal of Economic Entomology.  (Entomological Soc. of America, 4603
   Calvert Rd., College Park, MD 20740)  V.1-    1908- Volume(issue)/page/year:
   61,32,1968

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 50 mg/kg
SEX/DURATION            : female 6-15 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Specific Developmental Abnormalities - musculoskeletal system
REFERENCE :
   BECTA6 Bulletin of Environmental Contamination and Toxicology.
   (Springer-Verlag New York, Inc., Service Center, 44 Hartz Way, Secaucus, NJ
   07094)  V.1-    1966-  Volume(issue)/page/year: 24,936,1980

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 54 mg/kg
SEX/DURATION            : female 7-15 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Effects on Newborn - weaning or lactation index (e.g., #
   alive at weaning per # alive at day 4)
   Reproductive - Effects on Newborn - behavioral
REFERENCE :
   NTOTDY Neurobehavioral Toxicology and Teratology.  (Fayetteville, NY) V.3-8,
   1981-86.  For publisher information, see NETEEC. Volume(issue)/page/year:
   4,247,1982

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 99 mg/kg
SEX/DURATION            : female 7-17 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Fertility - post-i

其他信息

Sigma Aldrich:900-95-8(sigmaaldrich)
图谱信息:三苯基锡醋酸盐(900-95-8)质谱(MS) 三苯基锡醋酸盐(900-95-8)红外图谱(IR1) 三苯基锡醋酸盐(900-95-8)红外图谱(IR2)
MSDS 信息:乙酰氧基三苯基锡(900-95-8).msds
MOL 文件:900-95-8.mol
Alfa Aesar:Triphenyltin acetate(900-95-8)
上游原料:氢氧化钠 --> 溴苯 --> 四氯化锡 --> 三苯基氯化锡 --> 三苯基氢氧化锡
用途三:防治甜菜褐斑病、马铃薯晚疫病、大豆炭疽病、黑点病、褐纹病、紫斑病。对水稻稻瘟病、稻曲病、条斑病也有较好防效。对洋葱黑斑病、芹菜叶枯病、菜豆炭疽病、咖啡的生尾孢病也都有很好的防效。特别对福寿螺、藻类、水蜗牛有着特殊防效。
急性毒性:口服-大鼠 LD50: 125 毫克/公斤; 口服-小鼠 LD50: 81 毫克/公斤
中毒症状:属剧烈神经毒物。头痛，头晕，多汗重者：恶心呕吐，大汗淋漓，排尿困难，抽搐，精神错乱，昏迷，呼吸困难等。
TSCA:Yes
灭火剂:砂土、干粉、泡沫
储运特性:库房通风低温干燥; 与食品原料分开储运
毒性:大鼠急性经口LD 50 为125mg/kg，大鼠急性经皮LD 50 为500mg/kg。对黏膜有刺激性。对野鸡LC 50 约580mg/L (8d)，蜜蜂安全。
类别:农药
急救治疗:[1]误服者立即催吐，洗胃、导泻。 [2]无特殊解毒剂，预防治疗，防止脑水肿发生。 [3]严禁大量输液。注意：在我国无登记产品
用途二:保护性杀菌剂，无内吸作用。主要用于防治马铃薯晚疫病，甜菜褐斑病，大豆炭疽病、褐纹病、紫斑病，水稻稻瘟病、条斑病，胡麻叶枯病，洋葱黑斑病，芹菜叶枯病，菜豆炭疽病等。用量3～6g/100m 2 。除杀菌外，也可用于防治水田中的藻类和水蜗牛。用于甜菜、大豆，还有增糖、增产的作用。用药4周后始可食用或喂饲牲畜。
三苯基锡醋酸盐价格(试剂级):更新日期产品编号产品名称包装价格 2010/05/25 71178 Triphenyltin acetate 50g 722元 2010/05/25 71178 Triphenyltin acetate 10g 202元
毒性分级:高毒
方法一:苯基溴化镁与四氯化锡反应制得三苯基氯化锡，随之与氢氧化钠反应制得三苯基羟基锡，最后与乙酰氯反应制得薯瘟锡。
外观性质:白色无气味的晶体。
可燃性危险特性:受热分解有毒含锡气体
用途一:用于防治水稻稻瘟病、稻曲病，甜菜的褐斑病等
职业标准:TWA 0.1 毫克 (锡)/立方米; STEL 0.2 毫克 (锡)/立方米