Triphenyltin Hydride 三苯基氢化锡
CAS 892-20-6 MFCD00003004
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分类
- {SNA} Chemical Synthesis, Organometallic Reagents, Organotin, Organotins, Reduction, Synthetic Reagents, Tin Hydrides
- {uni_hamburg} no charge; metal-organic; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment
相关文献及参考
- For general reactions of organotin hydrides, see Tri-n-butyltin hydride, A13298.
- 2-(Bromomethyl)penicillin V methyl ester undergoes ring-expansion via the methylene radical, to give the corresponding cepham: Tetrahedron, 44, 5953 (1988):
- Short: III/35C4
- Hydrostannylation of terminal alkynes is conveniently carried out in the presence of triethylboron. Reaction is faster than with tributyl tin hydride and gives higher yields. Stereoselectivity varies from 69-100% (E): Tetrahedron, 45, 923 (1989):
- Short: EINECS
- Reagent for free-radical desulfurization of the thionocarbonates of 1,2-diols to the corresponding methylenedioxy compounds: J. Org. Chem., 62, 1690 (1997).
- Reagent for free-radical desulfurization of the thionocarbonates of 1,2-diols to the correspond
安全信息
GHS Symbol
- H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
- H331 Toxic if inhaled 吸入中毒
- H311 Toxic in contact with skin 皮肤接触中毒
- H301 Toxic if swallowed 吞食有毒
- H301+H311+H331
- P273 Avoid release to the environment. 避免释放到环境中。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P301+P310
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
- P301+P310+P330
- P304+P340+P312
- P302+P352+P312
- R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入,皮肤接触及吞食都有毒
- R50/53
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
- S27 Take off immediately all contaminated clothing 立即脱掉全部污染的衣服;
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
- S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后,立即用大量…(由生产厂家指定)冲洗;
- S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
- S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
- S27/28
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 81 mg/kg TOXIC EFFECTS : Behavioral - muscle weakness REFERENCE : 34ZIAG "Toxicology of Drugs and Chemicals," Deichmann, W.B., New York, Academic Press, Inc., 1969 Volume(issue)/page/year: -,591,1969
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intraperitoneal SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 7900 ug/kg TOXIC EFFECTS : Behavioral - muscle weakness REFERENCE : 34ZIAG "Toxicology of Drugs and Chemicals," Deichmann, W.B., New York, Academic Press, Inc., 1969 Volume(issue)/page/year: -,591,1969
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 491 mg/kg TOXIC EFFECTS : Behavioral - muscle weakness REFERENCE : 34ZIAG "Toxicology of Drugs and Chemicals," Deichmann, W.B., New York, Academic Press, Inc., 1969 Volume(issue)/page/year: -,591,1969
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intraperitoneal SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 8500 ug/kg TOXIC EFFECTS : Behavioral - muscle weakness REFERENCE : 34ZIAG "Toxicology of Drugs and Chemicals," Deichmann, W.B., New York, Academic Press, Inc., 1969 Volume(issue)/page/year: -,591,1969
其他信息
- MOL 文件:892-20-6.mol
- Acros Organics:三苯基氢化锡 Triphenyltin hydride, 95%(892-20-6)
- Alfa Aesar:三苯基氢化锡,97% Triphenyltin hydride, 97%(892-20-6)
- 三苯基锡化氢价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/06/21 223780250 三苯基锡化氢 Triphenyltin hydride 95% 25 GR 2423元 2010/05/25 L00163 三苯基氢化锡, 97% Triphenyltin hydride, 97% 5g 605元 2010/05/25 L00163 三苯基氢化锡, 97% Triphenyltin hydride, 97% 25g 1890元
- TSCA:No
- Sigma Aldrich:892-20-6(sigmaaldrich)
- 敏感性:Moisture Sensitive