CAS 872-49-1 MFCD00014505-5-Chloro-1-Methylimidazole 5-氯-1-甲基咪唑 TAO{mole}

5-Chloro-1-Methylimidazole 5-氯-1-甲基咪唑

CAS 872-49-1 MFCD00014505

化学结构图

SMILES: C[n]1c[n]cc1Cl

化学属性

Mol. Formula	C4H5ClN2
Mol. Weight	116.55
Boiling Point	250-252 °C at 760mmHg
Refractive index	1.5110 to 1.5150
Density	1.25 g/mL at 25 °C(lit.)
Flash Point	96°C(lit.)
TSCA	No
Solubility	不溶
Melting Point	N/A

别名和识别编码

Chemical Name	5-Chloro-1-Methylimidazole
CAS Number	872-49-1
Alfabeta Name	CHLOROMETHYLIMIDAZOLE H511-----
MDL Number	MFCD00014505
Synonym	5-Chloro-1-methylimidazole {LY} 5-Chloro-1-methylimidazole {} {LY} 5-Chloro-1-methylimidazole {} {} {LY} 5-Chloro-1-methylimidazole {} {} {} {LY} 5-Chloro-1-methylimidazole {} {} {} {} {LY} 5-Chloro-1-methylimidazole {} {} {} {} {} {LY} 5-Chloro-1-methylimidazole {} {} {} {} {} {} {LY} 5-Chloro-1-methylimidazole {} {} {} {} {} {} {} {LY} 5-Chloro-1-methylimidazole {} {} {} {} {} {} {} {} {LY} 5-Chloro-1-methylimidazole {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {LY} 5-Chloro-1-methylimidazole {} {} {} {} {} {} {} {} {} {} {LY} 5-Chloro-1-methylimidazole {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 5-Chloro-1-methylimidazole {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 5-Chloro-1-methylimidazole {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 5-Chloro-1-methylimidazole {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 5-Chloro-1-methylimidazole {} {} {} {} {}
PubChem Substance ID	87561051
EC Number	212-827-6
Beilstein Registry Number	23(5)4,458
Chemical Name Translation	5-氯-1-甲基咪唑
Reaxys-RN	110509
InChIKey	NYDGOZPYEABERA-UHFFFAOYSA-N
LabNetwork Molecule ID	LN00004220
Canonical SMILES	CN1C=NC=C1Cl

信息真实价格透明资金保障专业采购外包团队在线服务

品牌质保精细包装现货库存一流品牌服务

产品应用

A useful synthetic intermediate.

安全信息

Warnings IRRITANT

GHS Symbol

WGK Germany3

Hazard statements

H315 Causes skin irritation 会刺激皮肤
H319 Causes serious eye irritation 严重刺激眼睛
H335 May cause respiratory irritation 可能导致呼吸道刺激

Personal Protective Equipment Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter

Precautionary statements

P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P302+P352+P332+P313+P362+P364
P332+P313
P305+P351+P338+P337+P313
P302+P350
P337+P313
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P305+P351+P338

Signal word Warning

Risk Statements

R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

Safety Statements

S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S37 Wear suitable gloves 戴适当手套；

Hazard Codes Xi

Storage condition 2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {

其他信息

5-氯-1-甲基咪唑价格(试剂级):更新日期产品编号产品名称包装价格 2014/06/02 C2317 5-氯-1-甲基咪唑 5-Chloro-1-methylimidazole 25G 2830元 2014/06/02 C2317 5-氯-1-甲基咪唑 5-Chloro-1-methylimidazole 5G 941元 2010/05/25 L11899 5-氯-1-甲基咪唑, 98% 5-Chloro-1-methylimidazole, 98% 5g 4830元
上游原料:三氯氧磷 --> 五氯化磷 --> 二甲胺 --> N,N'-二甲基草酰胺
方法一:由乙二酰二甲胺和五氯化磷反应得到。将过量的乙二酰二甲胺和五氯化磷分次投入反应锅中，在70-80℃下保温2h，放置过夜，减压蒸出氧氯化磷，温度不超过100℃，冷却，加入冰水，搅拌，用30-40%碱液调节pH为9-10，静置。分出油状物，母液冷却，析出无机盐后过滤，用氯仿洗涤，并用氯仿抽提母液。合并油层及氯仿层，回收氯仿，减压蒸馏，收集沸点110-115℃（4.0kPa）馏分，得1-甲基-5-氯咪唑。收率为52%。
下游产品:5-氯-1-甲基-4-硝基咪唑 --> 硫唑嘌呤
Alfa Aesar:5-氯-1-甲基咪唑,98% 5-Chloro-1-methylimidazole, 98%(872-49-1)
MSDS 信息:5-Chloro-1-methylimidazole(872-49-1).msds
Sigma Aldrich:872-49-1(sigmaaldrich)
MOL 文件:872-49-1.mol
用途一:医药中间体。