1,2,3-Trichlorobenzene 1,2,3-三氯苯

CAS 87-61-6 MFCD00000537

化学结构图

87-61-6
SMILES: Clc1cccc(Cl)c1Cl

化学属性

Mol. FormulaC6H3Cl3
Mol. Weight181
Density1.69
Flash Point126°(258°F)
TSCAYes
Melting Point52.0 to 56.0 deg-C
Boiling Point219°C(lit.)
Autoignition Point1059 °F
Vapor Density6.25 (vs air)
Vapor Pressure0.07 mmHg ( 25 °C)
Refractive index1.5776
SolubilityINSOLUBLE

别名和识别编码

Chemical Name1,2,3-Trichlorobenzene
MDL NumberMFCD00000537
CAS Number87-61-6
EC Number201-757-1
Merck Number9630
Beilstein Registry Number5,203
PubChem Substance ID87576341
Synonym 1 VIC-TRICHLOROBENZENE trichlorobenzene(non-specificname) 连三氯代苯,连位三氯苯 vic-Trichlorobenzene 1,2,3-Trichlorbenzol 1,2,6-Trichlorobenzene 2 1,2,3-三氯苯 1,2,3-trichlorobenzene solution benzene,1,2,3-trichloro- 1,2,3-Trichlorobenzene (1mg/ml in Methanol) [for Water Analysis] 1,2,3-Trichlorobenzene,99% 1,2,3-TRICHLOROBENZENE PESTANAL 1,2,3-TRICHLORBENZENE 1,2,3-TRICHLOROBENZENE, 1000MG, NEAT 3-三氯苯 1,2,3-trcb Trichlorobenzene,1,2,3- 1,2,3-三氯苯;连三氯代苯;连位三氯苯 连三氯代苯 1,2,3-TRICHLOROBENZENE, 1X1ML, MEOH, 500 0UG/ML 连位三氯苯 ai3-15516 1,2,3-Trichlorobnzene 1,2,3-TRICHLOROBENZENE 1,2,3-trichloro-benzen 连三氯苯 1,2,3-Trichlorobenzene 1,2,3-TCB 1，2，3-三氯苯 Trichlorbenzole
Chemical Name Translation1,2,3-三氯苯
Reaxys-RN956882
LabNetwork Molecule IDLN00201994
InChIInChI=1S/C6H3Cl3/c7-4-2-1-3-5(8)6(4)9/h1-3H
信息真实价格透明    资金保障    专业采购外包团队在线服务   
信息真实价格透明    资金保障    专业采购外包团队在线服务   
品牌质保精细包装    现货库存    一流品牌服务   

分类

  • {SNA} Alphabetical Index of Analytical Standards, Chemical Class, Alpha Sort, Analytical Standards, Analytical/Chromatography, Aromatics, Chloro, Chromatography, Environmental Standards, Halogenated, T, T-Z, TP - TZ, Volatiles/ Semivolatiles
  • {SNA} Aryl, Building Blocks, C6, Chemical Synthesis, Halogenated Hydrocarbons, Organic Building Blocks
  • {SNA} All alphabetically sorted, Alphabetical Index of Analytical Standards, Analytical Standards, Analytical/Chromatography, Chromatography, Environmental Standa

产品应用

  • 溶剂。润滑剂。有机合成中间体。杀白蚁剂药。

相关文献及参考

  • Merck: 14,9630 Beilstein: 5,IV,664
  • Merck: 14,9630

安全信息

RTECSDC2095000
Safety Statements
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
  • S57 Use appropriate containment to avoid environmental contamination 使用适当容器避免环境污染；
Packing GroupIII
UN Number UN3077 UN 3077 9/PG 3 3077
Risk Statements
  • R39/23/24/25 Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed 毒性：吸入，皮肤接触和吞食都会产生十分严重的不可逆危险
  • R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有毒
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R38 Irritating to skin 刺激皮肤
  • R52/53
  • R22 Harmful if swallowed 吞咽有害
  • R51/53
GHS Symbol
WGK Germany3
Hazard statements
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H315 Causes skin irritation 会刺激皮肤
  • H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H302 Harmful if swallowed 吞食有害
  • H319 Causes serious eye irritation 严重刺激眼睛
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Precautionary statements
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P332+P313
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医，如果你觉得不舒服
  • P301+P312+P330
  • P337+P313
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P403+P233
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P303+P361+P353
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P304+P340
  • P308+P313
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
  • P304+P340+P312
Signal word
Hazard Codes
Hazard Class9
Storage condition 密封保存 储存温度2-8℃ 0-6°C
Warnings 危化品目录(2015) 危险化学品 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1830 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   DCTODJ Drug and Chemical Toxicology.  (Marcel Dekker, 270 Madison Ave., New
   York, NY 10016) V.1-    1977/78-  Volume(issue)/page/year: 11,11,1988

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1390 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   MUTAEX Mutagenesis. (Oxford Univ. Press, Pinkhill House, Southfield Road,
   Eynsham, Oxford OX8 1JJ, UK) V.1- 1986-  Volume(issue)/page/year: 2,111,1987

TYPE OF TEST            : Micronucleus test
ROUTE OF EXPOSURE       : Intraperitoneal
TEST SYSTEM             : Rodent - mouse
DOSE/DURATION           : 250 mg/kg/24H
REFERENCE :
   MUTAEX Mutagenesis. (Oxford Univ. Press, Pinkhill House, Southfield Road,
   Eynsham, Oxford OX8 1JJ, UK) V.1- 1986-  Volume(issue)/page/year: 2,111,1987

其他信息

  • 毒性分级:中毒
  • 储运特性:库房通风低温干燥; 与食品添加剂分开存放
  • Acros Organics:1 2 3-三氯苯 1,2,3-Trichlorobenzene, 99%(87-61-6)
  • MSDS 信息:1,2,3-三氯苯(87-61-6).msds
  • 急性毒性:口服-大鼠 LD50: 1830 毫克/公斤; 腹腔-小鼠 LD50: 1390 毫克/公斤
  • 蒸气压:0.07 mm Hg ( 25 °C)
  • 能随水蒸气挥发。易溶于苯，醚和二硫化碳，微溶于醇，不溶于水。
  • TCI Shanghai:1,2,3-三氯苯(1mg/ml的甲醇溶液)[用于水分析] 1,2,3-Trichlorobenzene (1mg/ml in Methanol) [for Water Analysis](87-61-6)
  • 用途一:主要用于有机合成
  • 挥发性有机化合物(VOCs)单组分标准液
  • 海关编码:29036990
  • Alfa Aesar:1，2，3-三氯苯,99% 1,2,3-Trichlorobenzene, 99%(87-61-6)
  • 1,2,3-三氯苯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T0377 1,2,3-三氯苯 1,2,3-Trichlorobenzene 25G 117元 2014/06/02 S0673 1,2,3-三氯苯(1mg/ml的甲醇溶液)[用于水分析] 1,2,3-Trichlorobenzene (1mg/ml in Methanol) [for Water Analysis] 1ML 240元 2014/06/02 T0377 1,2,3-三氯苯 1,2,3-Trichlorobenzene 500G 558元
  • 用途二:溶剂。润滑剂。有机合成中间体。杀白蚁剂药。
  • 类别:农药
  • 下游产品:三氯苯 --> 1,3,5-三氯苯 --> 2,3-二氯苯酚 --> 2,3,4-三氯苯磺酸
  • 外观性质:白色结晶。
  • 方法一:1.热解法干燥的六六六无毒体在热解釜中加热热即得三氯苯，同时副产大量氯化氢。2.碱解法六六六无毒体与石灰乳共热即得三氯苯，同时副产大量氯化钙液。上述二法所得三氯苯均为1,2,4-三氯苯；1,3,5-三氯苯；1,2,3-三氯苯三种异构体的混合物，以1,2,4-三氯苯为主要组分。石灰乳法生产的三氯苯中，1,2,4-三氯苯含量在75%以上，1,2,3-三氯苯约占20%。
  • Sigma Aldrich:87-61-6(sigmaaldrich)
  • MOL 文件:87-61-6.mol
  • 上游原料:三氯苯 --> 1,3,5-三氯苯
  • 灭火剂:雾状水、泡沫、二氧化碳、砂土
  • 蒸气密度:6.25 (vs air)
  • 图谱信息:1,2,3-三氯苯(87-61-6)红外图谱(IR3) 1,2,3-三氯苯(87-61-6)红外图谱(IR1) 1,2,3-三氯苯(87-61-6)核磁图( 1 HNMR) 1,2,3-三氯苯(87-61-6)红外图谱(IR2) 1,2,3-三氯苯(87-61-6)质谱(MS) 1,2,3-三氯苯(87-61-6)核磁图( 13 CNMR) 1,2,3-三氯苯(87-61-6)Raman光谱
  • 可燃性危险特性:明火可燃; 燃烧释放有毒氯化物烟雾; 水解生成盐酸

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃
  5. Aryl 芳基卤代烃
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃
  5. Aryl 芳基卤代烃
  6. C6 - Aryl
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃
  5. Aryl 芳基卤代烃
  6. C6 - Aryl
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Alphabetic - Analytical Standards
  4. T - Alphabetic
  5. TP - TZ - T
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Halogenated 卤化物 (氟氯溴碘)
  5. Chloro - Halogenated
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃
  5. Aryl 芳香卤代烃
  6. C13 to C37+

相关产品推荐