Tris(trimethylsilyl)silyl vinyl ether 三(三甲基硅基)氧乙烯基硅烷
CAS 861445-91-2 MFCD11656064
化学结构图
SMILES: C[Si](C)(C)[Si](OC=C)([Si](C)(C)C)[Si](C)(C)C
化学属性
| Mol. Formula | C11H30OSi4 |
|---|---|
| Mol. Weight | 290.70 |
| Melting Point | 51-61 °C |
别名和识别编码
| Chemical Name | Tris(trimethylsilyl)silyl vinyl ether |
|---|---|
| Synonym | 三(三甲基硅基)硅氧基乙烯 乙烯氧基三(三甲基硅基)硅烷 三(三甲基硅基)硅氧基乙烯 三(三甲基硅基)氧乙烯基硅烷 乙烯氧基三(三甲基硅基)硅烷 |
| MDL Number | MFCD11656064 |
| CAS Number | 861445-91-2 |
| Chemical Name Translation | 三(三甲基硅基)氧乙烯基硅烷 |
| PubChem Substance ID | 329761989 |
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分类
- {SNA} Building Blocks, Chemical Synthesis, Enol Ethers, Organic Building Blocks, Organometallic Reagents, Organosilicon, Others, Oxygen Compounds
- {SNA} Building Blocks, Chemical Synthesis, Enol Ethers, Organic Building Blocks, Organometallic Reagents, Organosilicon, Other Organosilicon, Oxygen Compounds
相关文献及参考
- 1. Boxer, M. B.; Yamamoto, H., Remarkable Tris(trimethylsilyl)silyl Group for Diastereoselective [2+2] Cyclizations Org. Lett. 7 , 3127, (2005) 摘要
- 2. Boxer, M. B.; Yamamoto, H., Tris(trimethylsilyl)silyl-Governed Aldehyde Cross-Aldol Cascade Reaction J. Am. Chem. Soc. 128 , 48, (2006) 摘要
- 3. Northrup, A. B.; MacMillan, D. W. C., The First Direct and Enantioselective Cross-Aldol Reaction of Aldehydes J. Am. Chem. Soc. 124 , 6798, (2002) 摘要
- 4. Boxer, M. B.; Yamamoto, H., "Super Silyl" Group for Diastereoselective Sequential Reactions: Access to Complex Chiral Architecture in One Pot J. Am. Chem. Soc. 129 , 2762, (2007)
- 5. Boxer, M. B.; Yamamoto, H., Super Silyl Group for a Sequential Diastereoselective Aldol-Polyhalomethyllithium Addition Reaction Org. Lett. 10 , 453, (2008) 摘要
- 6. Boxer, M. B.; et al., Ketone Super Silyl Enol Ethers in Sequential Reactions: Diastereoselective Generation of Tertiary Carbinols in One Pot J. Am. Chem. Soc. 130 , 1580, (2008)
- 7. Albert, B. J.; et al., Rapid Total Syntheses Utilizing "Supersilyl" Chemistry Angew. Chem. Int. Ed. Engl. 50 , 2610-2612, (2011) 摘要
- 8. Laub, H. A.; et al., Effect of the "Supersilyl" Group on the Reactivities of Allylsilanes and Silyl Enol Ethers Org. Lett. 12 , 5206-5209, (2010) 摘要
安全信息
GHS Symbol
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
- H228 Flammable solid 易燃固体
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
- R11 Highly flammable 非常易燃
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
