1-Nitronaphthalene 1-硝基萘
CAS 86-57-7 MFCD00003913
信息真实价格透明
资金保障
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信息真实价格透明
资金保障
专业采购外包团队在线服务
品牌质保精细包装
现货库存
一流品牌服务
分类
- {uni_hamburg} no charge; carbocycle; aromatic; large ring; fused rings; 6ring; 10ring; 1fragment
- {SNA} Building Blocks, Chemical Synthesis, Nitro Compounds, Nitrogen Compounds, Organic Building Blocks
- All PAH Standards, Alphabetic, Analytical Standards, Analytical/Chromatography, Application CRMs, CRMs, Certified Reference Materials (CRMs), Chromatography, Environmental CRM, Environmental Standards, N, NA - NI, Nitro-PAH, PAHs, Volatiles/ Semivolatiles, neat
产品应用
- Usually used to study excited state dynamics of 1-nitropthalene in nonpolar, aprotic and protic solvents.
相关文献及参考
- Short: II/27B
- Merck: 14,6614 Beilstein: 5,IV,1673
- Merck: 14,6614
- Short: II/3
安全信息
GHS Symbol
- H228 Flammable solid 易燃固体
- H301 Toxic if swallowed 吞食有毒
- H302 Harmful if swallowed 吞食有害
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- H351 Suspected of causing cancer 怀疑致癌
- H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
- P201 Obtain special instructions before use. 使用前获取专门指示。
- P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前,切勿操作。
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
- P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P273 Avoid release to the environment. 避免释放到环境中。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P281 Use personal protective equipment as required. 使用所需的个人防护装备。
- P301+P310
- P301+P310+P330
- P301+P312+P330
- P302+P352
- P302+P352+P312+P361+P364
- P304+P340
- P304+P340+P311
- P305+P351+P338
- P308+P313
- P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
- P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
- P330 Rinse mouth. 漱口
- P332+P313
- P337+P313
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
- P370 In case of fire: 在发生火灾的情况下:
- P370+P378
- P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
- P403+P233
- P405 Store locked up. 上锁保管。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
- S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后,立即用大量…(由生产厂家指定)冲洗;
- S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
- S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
- S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
- S57 Use appropriate containment to avoid environmental contamination 使用适当容器避免环境污染;
- S20 When using do not eat or drink 使用时,不得进食,饮水;
- S36 Wear suitable protective clothing 穿戴适当的防护服;
- R11 Highly flammable 非常易燃
- R25 Toxic if swallowed 吞咽有毒
- R51/53
- R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intraperitoneal SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 86 mg/kg TOXIC EFFECTS : Lungs, Thorax, or Respiration - dyspnea Liver - hepatitis (hepatocellular necrosis), diffuse REFERENCE : JJATDK JAT, Journal of Applied Toxicology. (John Wiley & Sons Ltd., Baffins Lane, Chichester, W. Sussex PO19 1UD, UK) V.1- 1981- Volume(issue)/page/year: 4,253,1984
TYPE OF TEST : DNA inhibition TEST SYSTEM : Human HeLa cell DOSE/DURATION : 260 umol/L REFERENCE : CRNGDP Carcinogenesis (London). (Oxford Univ. Press, Pinkhill House, Southfield Road, Eynsham, Oxford OX8 1JJ, UK) V.1- 1980- Volume(issue)/page/year: 13,2389,1992
TYPE OF TEST : Mutation test systems - not otherwise specified TEST SYSTEM : Bacteria - Salmonella typhimurium DOSE/DURATION : 19 mg/L REFERENCE : MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 192,239,1987
TYPE OF TEST : Specific locus test ROUTE OF EXPOSURE : Oral TEST SYSTEM : Insect - Drosophila melanogaster DOSE/DURATION : 2 mmol/L REFERENCE : MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 341,161,1995
TYPE OF TEST : Mutation in microorganisms TEST SYSTEM : Bacteria - Salmonella typhimurium DOSE/DURATION : 100 ug/plate REFERENCE : ENMUDM Environmental Mutagenesis. (New York, NY) V.1-9, 1979-87. For publisher information, see EMMUEG. Volume(issue)/page/year: 7(Suppl 5),1,1985
TYPE OF TEST : Mutation in mammalian somatic cells TEST SYSTEM : Rodent - hamster Lung DOSE/DURATION : 20 mg/L REFERENCE : MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 259,111,1991
TYPE OF TEST : Sister chromatid exchange TEST SYSTEM : Rodent - hamster Lung DOSE/DURATION : 20 mg/L REFERENCE : EMMUEG Environmental and Molecular Mutagenesis. (Alan R. Liss, Inc., 41 E. 11th St., New York, NY 10003) V.10-
其他信息
- 海关编码:29042000
- MSDS 信息:1-硝基萘(86-57-7).msds
- TCI Shanghai:1-硝基萘 1-Nitronaphthalene,>;98.0%(GC)(86-57-7)
- 下游产品:1-萘胺 --> 新铜铁灵 --> 4-硝基1-萘胺
- Alfa Aesar:1-硝基萘,99% 1-Nitronaphthalene, 99%(86-57-7)
- Sigma Aldrich:86-57-7(sigmaaldrich)
- Acros Organics:1-硝基萘 1-Nitronaphthalene, 99%(86-57-7)
- 外观性质:黄色针状结晶。
- 上游原料:萘 --> 搪玻璃反应锅
- 无气味。易溶于氯仿、乙醚和二硫化碳,溶于乙醇,不溶于水。遇浓硫酸溶液呈暗红色。还原时生成1-萘胺。易燃。有毒。有刺激性。
- 方法一:由萘经硝化而得。在实际工业生产中,反应所需的混酸,一部分可重复套用。将上批硝化所得的废酸600kg加入搪玻璃反应锅中,冷却下再加入300kg98%硫酸和793kg100%硝酸,将其进行搅拌配制成混酸待用。在反应锅中加入800kg上次硝化的废酸,投入1550kg精萘和上述配制的混酸,精萘和混酸分三次交叉加入,温度控制在50-55℃。加毕,升温至65℃,保温3h。取样检查终点,凝固点≥51℃时,分出硝化废酸。用热水将反应物洗至中性,即得1-硝基萘。
- MOL 文件:86-57-7.mol
- 用途一:用于制取染料、农药和橡胶防老剂等
- 1-硝基萘价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/06/21 147045000 1-硝基萘 1-Nitronaphthalene 99% 500 GR 443元 2010/06/21 147040050 1-硝基萘 1-Nitronaphthalene 99% 5 GR 164元 2010/05/25 L15725 1-硝基萘, 99% 1-Nitronaphthalene, 99% 25g 154元
- 用途三:气相色谱固定液(最高使用温度100℃,溶剂为无水乙醇),分离芳烃。合成硫化染料和1-萘胺。掩蔽矿物油中荧光。
- Hazard Note:Flammable/Toxic
- 用途二:该品为染料、农药、橡胶助剂等有机合成的中间体。
- 图谱信息:1-硝基萘(86-57-7)核磁图( 13 CNMR) 1-硝基萘(86-57-7)质谱(MS) 1-硝基萘(86-57-7)核磁图( 1 HNMR) 1-硝基萘(86-57-7)红外图谱(IR1) 1-硝基萘(86-57-7)红外图谱(IR2)