2,2',2'',2'''-(1,2-PHENYLENEBIS[(1S,3S)-TETRAHYDRO-5,8-DIOXO-1H-[1,2,4]DIAZAPHOSPHOLO[1,2-A]PYRIDAZINE-2,1,3(3H)-TRIYL])TETRAKIS(N-[(1S)-1-PHENYLETHYL])BENZAMIDE 2,2′,2″,2′′′-(1,2-亚苯基双[(1S,3S)-四氢-5,8-二氧代-1H-[1,2,4]二氮杂磷杂环戊基[1,2-a]哒嗪-2,1,3(3H)-三基])四(N-[(1S)-1-苯乙基])苯甲酰胺
CAS 851770-14-4 MFCD10566996
化学结构图
SMILES: C[C@H](NC(=O)C1=CC=CC=C1[C@H]1N2C(=O)CCC(=O)N2[C@H](C2=CC=CC=C2C(=O)N[C@@H](C)C2C=CC=CC=2)P1C1=CC=CC=C1P1[C@@H](C2=CC=CC=C2C(=O)N[C@@H](C)C2C=CC=CC=2)N2C(=O)CCC(=O)N2[C@@H]1C1=CC=CC=C1C(=O)N[C@@H](C)C1C=CC=CC=1)C1C=CC=CC=1
化学属性
| Mol. Formula | C78H72N8O8P2 |
|---|---|
| Mol. Weight | 1311.40 |
| Melting Point | 289-299 °C |
别名和识别编码
| Chemical Name | Bis[(S,S,S)-DiazaPhos-SPE] |
|---|---|
| Synonym | Bis[(S,S,S)-DiazaPhos-SPE] 2,2′,2″,2′′′-(1,2-亚苯基双[(1S,3S)-四氢-5,8-二氧代-1H-[1,2,4]二氮杂磷杂环戊基[1,2-a]哒嗪-2,1,3(3H)-三基])四(N-[(1S)-1-苯乙基])苯甲酰胺 |
| MDL Number | MFCD10566996 |
| CAS Number | 851770-14-4 |
| Chemical Name Translation | 2,2′,2″,2′′′-(1,2-亚苯基双[(1S,3S)-四氢-5,8-二氧代-1H-[1,2,4]二氮杂磷杂环戊基[1,2-a]哒嗪-2,1,3(3H)-三基])四(N-[(1S)-1-苯乙基])苯甲酰胺 |
| PubChem Substance ID | 329760956 |
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分类
- {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Hydroformylation, Landis Ligands, Privileged Ligands and Complexes
- Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Hydroformylation, Landis Ligands, Privileged Ligands and Complexes
相关文献及参考
- 1. Watkins, A. L.; Landis, C. R. , Regioselective rhodium-catalyzed hydroformylation of 1,3-dienes to highly enantioenriched β,γ-unsaturated aldehydes with diazaphospholane ligands Org. Lett. 13 , 164-167, (2011)
- 2. McDonald, R. I.; et al., Enantioselective Hydroformylation of N-Vinyl Carboxamides, Allyl Carbamates, and Allyl Ethers Using Chiral Diazaphospholane Ligands J. Am. Chem. Soc. 132 , 14027-14029, (2010)
- 3. Watkins, A. L.; Landis, C. R., Origin of Pressure Effects on Regioselectivity and Enantioselectivity in the Rhodium-Catalyzed Hydroformylation of Styrene with (S,S,S)-BisDiazaphos J. Am. Chem. Soc. 132 , 10306-10317, (2010)
- 4. Noonan, G. M.; et al., Regioselective and Enantioselective Hydroformylation of Dialkylacrylamides Adv. Synth. Catal. 352 , 1047-1054, (2010)
- 5. Watkins, A. L.; et al., Highly Enantioselective Hydroformylation of Aryl Alkenes with Diazaphospholane Ligands Org. Lett. 10 , 4553-4556, (2008)
- 6. Owens, S. B., Jr.; Gray, G. M., Study of the Effects of Alkali Metal Salts on Styrene Hydroformylation Reactions Catalyzed by Rhodium(I) Complexes of Bis(phosphite) Ligands Organometallics 27 , 4282-4287, (2008)
- 7. Axtell, A.T. et al. Angew. Chem. Int. Ed. Engl. 44 , 5834, (2005) 摘要
- 8. Clark, T.P. et al. J. Am. Chem. Soc. 127 , 5040, (2005) 摘要
