(+)-9-(1S, 2S-Pseudoephedrinyl)-(10R)-(trimethylsilyl)-9-borabicyclo[3.3.2]decane (+)-9-(1S, 2S-伪麻黄碱基)-(10R)-(三甲基硅基)-9-硼杂双环[3.3.2]癸烷

CAS 848618-13-3 MFCD09265094

化学结构图

848618-13-3
SMILES: C[C@H](NC)[C@@H](OB1[C@H]([C@@H]2CCC[C@H]1CCC2)[Si](C)(C)C)C1C=CC=CC=1

化学属性

Mol. FormulaC22H38BNOSi
Mol. Weight371.44
Melting Point130-134 °C

别名和识别编码

Chemical Name(+)-9-(1S, 2S-Pseudoephedrinyl)-(10R)-(trimethylsilyl)-9-borabicyclo[3.3.2]decane
Synonym (+)-9-(1S, 2S-伪麻黄碱基)-(10R)-(三甲基硅基)-9-硼杂双环[3.3.2]癸烷 N,α-二甲基-β-[[(10R)-10-(三甲基硅基)-9-硼杂双环[3.3.2]癸-9-基]氧]-(αS,βS)-苯乙胺
MDL NumberMFCD09265094
PubChem Substance ID24885323
Chemical Name Translation(+)-9-(1S, 2S-伪麻黄碱基)-(10R)-(三甲基硅基)-9-硼杂双环[3.3.2]癸烷
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分类

  • {SNA} Allylation, Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Signal word Warning
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
Hazard Codes Xi
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

系列性分类

  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Allylation - Chiral Catalysts, Ligands, and Reagents

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