CAS 84-11-7 MFCD00001163-9,10-Phenanthraquinone 9,10-菲醌 TAO{mole}

9,10-Phenanthraquinone 9,10-菲醌

CAS 84-11-7 MFCD00001163

化学结构图

SMILES: O=C1C(=O)c2ccccc2-c2ccccc21

化学属性

Mol. Formula	C14H8O2
Mol. Weight	208
Density	1.308
Melting Point	207.0 to 211.0 deg-C
Flash Point	245°(473°F)
TSCA	Yes
Boiling Point	360°C
Appearance	菲醌为橙红色针状结晶，熔点为207℃，沸点为360℃，可溶于乙醇、冰醋酸、苯和硫酸，不溶于水；菲醌能与亚硫酸氢钠生成可溶于水的加成物，可以利用这一性质进行菲醌的提纯。

别名和识别编码

Chemical Name	9,10-Phenanthraquinone
Synonym	9,10-phenanthrenequinone[qr] 9,10-菲蒽菲醌 9,10-PHENANTHRAQUINONE 9,10-PHENANTHRENEQUINONE Phenanthrene chinone 95% 9,10-PHENANTHRENEQUINONE, FOR FLUOR-ESCE NCE PHENANTHRAQUINONE 9,10-菲二酮 9,10-Phenanthraquinone 9 9,10-Phenanthrenedione 9,10-Phenanthraquinone85-99% 9,10-Phenanthrenchinon
CAS Number	84-11-7
EC Number	201-515-5
Beilstein Registry Number	7(4)2565
MDL Number	MFCD00001163
Merck Number	7213
PubChem Substance ID	87575241
Reaxys-RN	608838
Chemical Name Translation	9,10-菲醌
Wiswesser Line Notation	L B666 HVVJ
LabNetwork Molecule ID	LN00010500

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产品应用

菲醌用于有机合成，可用来生产苯绕蒽酮。菲醌具有抑菌能力，用于拌种可防止谷物黑穗病、棉花苗期病，还可作为纸浆防腐剂。经氢氧化钠处理后可制得多效能的植物生长调节剂整形素。

安全信息

Signal word

GHS Symbol

WGK Germany3

Safety Statements

S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S57 Use appropriate containment to avoid environmental contamination 使用适当容器避免环境污染；
S36 Wear suitable protective clothing 穿戴适当的防护服；
S22 Do not breathe dust 不要吸入粉尘；
S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；

Risk Statements

R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

Precautionary statements

P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P501 Dispose of contents/container to..… 处理内容物/容器.....
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P305+P351+P338
P332+P313
P273 Avoid release to the environment. 避免释放到环境中。
P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
P305+P351+P338+P337+P313
P302+P352+P332+P313+P362+P364

Hazard statements

H315 Causes skin irritation 会刺激皮肤
H319 Causes serious eye irritation 严重刺激眼睛
H335 May cause respiratory irritation 可能导致呼吸道刺激

Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves

RTECSSF7875000

Packing GroupIII

UN Number UN3077 3077

Hazard Codes Xi

Hazard Class9

Storage condition 2-8°C

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 800 mg/kg/29W-C
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Skin and Appendages - tumors
   Tumorigenic - tumors at site of application
REFERENCE :
   PIATA8 Proceedings of the Imperial Academy of Tokyo.  (Tokyo, Japan) V.1-21,
   1912-45.  For publisher information, see PJACAW. Volume(issue)/page/year:
   16,309,1940

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 165 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   HBTXAC "Handbook of Toxicology," 4 vols., Philadelphia, W.B. Saunders Co.,
   1956-59  Volume(issue)/page/year: 5,110,1959

TYPE OF TEST            : DNA repair
TEST SYSTEM             : Bacteria - Bacillus subtilis
DOSE/DURATION           : 400 ug/plate
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 66,337,1979

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 30 umol/L
REFERENCE :
   PNASA6 Proceedings of the National Academy of Sciences of the United States
   of America.  (National Academy of Sciences, Printing & Pub. Office, 2101
   Constitution Ave., Washington, DC 20418) V.1-    1915-
   Volume(issue)/page/year: 81,1696,1984

其他信息

急性毒性:腹腔- 大鼠 LDL0: 165 毫克/ 公斤
储运特性:库房通风低温干燥; 与食品原料分开储运
用途一:菲醌本身是农药，可以用作杀菌剂、拌种剂、电子照相，可用作光导材料、光敏阻焊剂和纸张防腐剂。
Sigma Aldrich:84-11-7(sigmaaldrich)
类别:农药
升华。实际上不溶于水，微溶于乙醇、苯、醋酸乙酯，溶于乙醚、热醇和热醋酸，在浓硫酸中溶解并呈现暗绿色。升华得橙红色片状体。与亚硫酸钠作用生成不稳定的亚硫酸氢盐。经进一步氧化，可得联苯二甲酸。还原成菲氢醌。
菲醌价格(试剂级):更新日期产品编号产品名称包装价格 2014/06/02 P1136 9,10-菲醌 9,10-Phenanthrenequinone 25G 619元 2014/06/02 P1136 9,10-菲醌 9,10-Phenanthrenequinone 250G 3730元 2014/06/02 P0080 9,10-菲醌 9,10-Phenanthrenequinone 25G 1080元
方法一:由菲氧化制成，有化学法及电解法。1.化学法用重铬酸钠（或钾）与菲在硫酸水溶液中氧化。2.电解氧化法电解液含三氧化铬120g/L、硫酸450g/L，含菲35g/L。阴极电流密度3.75A/cm2，电解液温度60-65℃，经电解8h后，过滤，得产品。
Acros Organics:菲醌 Phenanthrenequinone, tech., 80%(84-11-7)
图谱信息:菲醌(84-11-7)核磁图( 13 CNMR) 菲醌(84-11-7)红外图谱(IR2) 菲醌(84-11-7)质谱(MS) 菲醌(84-11-7)红外图谱(IR1)
MOL 文件:84-11-7.mol
检测方法:HPLC
下游产品:9-羟基-9-芴甲酸
TCI Shanghai:9,10-菲醌 9,10-Phenanthrenequinone,>;99.0%(GC)(84-11-7)
MSDS 信息:9,10-Phenanthrenedione(84-11-7).msds
灭火剂:干粉、泡沫、砂土
用途二:菲醌用于有机合成，可用来生产苯绕蒽酮。菲醌具有抑菌能力，用于拌种可防止谷物黑穗病、棉花苗期病，还可作为纸浆防腐剂。经氢氧化钠处理后可制得多效能的植物生长调节剂整形素。
上游原料:三氧化铬 --> 重铬酸钠 --> 菲
海关编码:29146990
毒性分级:高毒
Alfa Aesar:9,10-菲蒽,99% 9,10-Phenanthrenequinone, 95%(84-11-7)