N2-Ethyl-N4-Isopropyl-6-(Methylthio)-1,3,5-Triazine-2,4-Diamine 莠灭净

CAS 834-12-8 MFCD00055398

化学结构图

834-12-8
SMILES: CCNc1nc(NC(C)C)nc(SC)n1

化学属性

Mol. FormulaC9H17N5S
Mol. Weight227.37
Melting Point84-85°C
Flash Point11 °C
Appearance 白色结晶固体。m.p.80～84℃(石油醚中重结晶），密度1.19g/m -4 3 Pa。溶争度为：丙酮500g/L，甲醇450g/L，甲苯400g/L，水18.5mg/L。在微酸或微碱性介质中稳定，在强酸、强碱介质中易水解。不易燃，无腐蚀性。 ，蒸气压1.12×10
Density1.15

别名和识别编码

Chemical NameN2-Ethyl-N4-Isopropyl-6-(Methylthio)-1,3,5-Triazine-2,4-Diamine
Synonym 2-ETHYLAMINO-4-ISOPROPYLAMINO- 2-Methylthio-4-ethylamino-6-isopropylamino-S-triazine AMETRYNE s-triazine, 2-(ethylamino)-4-(isopropylamino)-6-(methylthio)- 2-ETHYLAMINO-4-ISOPROPYLAMINO-6-METHYLTHIO-1,3,5-TRIAZINE Evik EVIK MEBATRYNE N-ethyl-N'-(1-methylethyl)-6-methylthio-1,3,5-triazine-2,4-diamine 1,3,5-Triazine,2-(ethylamino)-4-(isopropylamino)-6-(methylthio) 2-(Ethylamino)-4-(isopropylamino)-6 2-Ethylamino-4-isopropylamino-6-methylmercapto-s-tria N'-ETHYL-6-METHYLSULFANYL-N-PROPAN-2-YL-1,3,5-TRIAZINE-2,4-DIAMINE 2-Methylmercapto-4-ethylamino-6-isopropylamino-s-triazine 莠灭净 2-(Methylthio)-4-(ethylamino)-6-(isopropylamino)-s-triazine G-34162 2-(Ethylamino)-4-(isopropylamino)-6-(methylthio)-1,3,5-triazine 2-ETHYLAMINO-4- N-ethyl-N'-(1-methylethyl)-6-(methylthio)-1,3,5-triazine-2,4-diamine 2-乙胺基-4-异丙 { Primatol Z 80 {uni_ham 2-(Ethylamino)-4-(isopropylamino)-6-(methylmercapto)-s-triazine Ametryne; Bromoxynil; 2-Methylth AMETRE 2-ethylamino-4-isopropylamino-6-methylthio-s-triazine Cemerin N-Ethyl-N'-(1-methylethyl)-6-(methylthio)1,3,5-triazine-2,4-diamine {uni 5-三嗪 N-2-乙氨基-N-4 Ametryn N-ethyl-N'-isopropyl-6-methylsulfanyl-(1,3,5)triazine-2,4-diamine Gesapax 2-(Methylmercapto)-4-(isopropylamino)-6-(ethylamino)-s-triazine G 34162 {un 2-ETHYLAMINO-4-ISOPROPYLAMINO-6-METHYLMERCAPTO-S-TRIAZINE 2-Methylmercapto-4-isopropylamino-6-ethylamino-S-triazine 2-(Methylmercapto)-4-(ethylamino)-6-(isopropylamino)-s-triazine {Chemic
MDL NumberMFCD00055398
PubChem Substance ID13263
Beilstein Registry Number0613099
CAS Number834-12-8
EC Number212-634-7
Chemical Name Translation莠灭净
Merck Number13,391
Wiswesser Line NotationT6N CN ENJ BS1 DMY1&1 FM2
LabNetwork Molecule IDLN01263900
InChIInChI=1S/C9H17N5S/c1-5-10-7-12-8(11-6(2)3)14-9(13-7)15-4/h6H,5H2,1-4H3,(H2,10,11,12,13,14)
信息真实价格透明    资金保障    专业采购外包团队在线服务   
信息真实价格透明    资金保障    专业采购外包团队在线服务   
品牌质保精细包装    现货库存    一流品牌服务   

分类

  • {SNA} A, A-B, AM to AQ, All alphabetically sorted, Alphabetical Index of Analytical Standards, Analytical Standards, Analytical/Chromatography, Chromatography, Environmental Standards, Herbicides, Pesticides & Metabolites, Triazines
  • {Chemicalbook} 农药: 除草剂:
  • {SNA} A, A-B, AM to AQ, Alpha sort, Alphabetic, Analytical Standards, Analytical/Chromatography, Chromatography, Environmental Standards, Herbicides, Pesticides & Metabolites, Triazines
  • {Chemicalbook} 农药: 除草剂: 有机杂环类除草剂
  • A, AM to AQ,
  • {uni_hamburg} no charge; nitrogen heterocycle; aro

产品应用

  • 选择性除草剂，苗前苗后使用,防除香蕉、柑桔、咖啡、可可、玉米、油棕、凤梨、甘蔗、茶、马铃薯和非耕地中阔叶和禾本科杂草。

相关文献及参考

  • Short: IV/20C
  • Merck: 14,393
  • Short: IV/20A
  • Short: EINECS

安全信息

RTECSXY9100000
GHS Symbol
Precautionary statements
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P301+P312+P330
Hazard statements
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
  • H302 Harmful if swallowed 吞食有害
Hazard Codes Xn;N Xn;N,N,Xn,T,F Xn,N
WGK Germany3
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Signal word Warning
Safety Statements
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S2 Keep out of the reach of children 避免儿童触及；
  • S7 Keep container tightly closed 保存在严格密闭容器中；
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
Risk Statements
  • R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有毒
  • R11 Highly flammable 非常易燃
  • R22 Harmful if swallowed 吞咽有害
  • R50/53
  • R39/23/24/25 Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed 毒性：吸入，皮肤接触和吞食都会产生十分严重的不可逆危险
Storage condition CA 4°C 室温储存
UN Number UN 1230 3/PG 2 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 965 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   PCOC** Pesticide Chemicals Official Compendium, Association of the American
   Pesticide Control Officials, Inc., 1966.  (Topeka, KS)
   Volume(issue)/page/year: -,29,1966

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 508 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   FAATDF Fundamental and Applied Toxicology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1981-  Volume(issue)/page/year:
   7,299,1986

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 8160 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85DPAN "Wirksubstanzen der Pflanzenschutz und Schadlingsbekampfungsmittel,"
   Perkow, W., Berlin, Verlag Paul Parey, 1971-1976  Volume(issue)/page/year:
   -,-,1971/1976

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : >2200 mg/m3/4H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   FMCHA2 Farm Chemicals Handbook.  (Meister Pub., 37841 Euclid Ave.,
   Willoughy, OH 44094)  Volume(issue)/page/year: -,C19,1991

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rabbit
DOSE                    : 780 mg/kg
SEX/DURATION            : female 7-19 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Maternal Effects - other effects
REFERENCE :
   NNGADV Nippon Noyaku Gakkaishi.  Journal of the Pesticide Science Society of
   Japan.  (Nippon Noyaku Gakkai, 1-43-11, Komagome, Toshima-ku, Tokyo 170,
   Japan)  V.1-    1976-  Volume(issue)/page/year: 18,S213,1993

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 2500 mg/kg
SEX/DURATION            : female 6-15 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Maternal Effects - other effects
   Reproductive - Effects on Embryo or Fetus - other effects to embryo
REFERENCE :
   NNGADV Nippon Noyaku Gakkaishi.  Journal of the Pesticide Science Society of
   Japan.  (Nippon Noyaku Gakkai, 1-43-11, Komagome, Toshima-ku, Tokyo 170,
   Japan)  V.1-    1976-  Volume(issue)/page/year: 18,S213,1993

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 336600 ug/kg
SEX/DURATION            : female 5-15 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Fertility - post-implantation mortality (e.g. dead and/or
   resorbed implants per total number of implants)
   Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death,
   e.g., stunted fetus)
   Reproductive - Effects on Embryo or Fetus

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE                    : 4040 mg/kg
SEX/DURATION            : female 6-15 day(s) after conception
TOXIC EFFECTS :
   Reprodu

其他信息

  • 刺激数据:眼睛- 兔子 76 毫克 轻度
  • 用途三:选择性除草剂，苗前苗后使用,防除香蕉、柑桔、咖啡、可可、玉米、油棕、凤梨、甘蔗、茶、马铃薯和非耕地中阔叶和禾本科杂草。
  • 储运特性:库房通风低温干燥; 与食品原料分开储运
  • MSDS 信息:Ametryn(834-12-8).msds
  • 中毒症状:对眼、皮肤和呼吸道有中度刺激作用。
  • 灭火剂:干粉、泡沫、砂土
  • MOL 文件:834-12-8.mol
  • 图谱信息:莠灭净(834-12-8)质谱(MS) 莠灭净(834-12-8)核磁图( 1 HNMR) 莠灭净(834-12-8)红外图谱(IR1) 莠灭净(834-12-8)红外图谱(IR2) 莠灭净(834-12-8)核磁图( 13 CNMR)
  • 毒性:原药对大鼠急性经口 LD 50 673mg/kg，兔急性经皮 LD 50 》2000mg/kg，大鼠急性吸入 LC 50 >4.65mg/L (4h)。对兔眼睛和皮肤有轻微的刺激作用。虹鳟鱼 LC 50 3.2mg/L (96h)，金鱼 LC 50 14.0mg/L，鹌鹑 LD 50 30000mg/kg。对蜜蜂安全。
  • 毒性分级:中毒
  • 用途一:用于防除香蕉、柑橘、咖啡、甘蔗、茶和非耕地中阔叶和禾本科杂草
  • 职业标准:TLV-TWA 5 毫克/ 立方米
  • 易溶于有机溶剂，在弱酸弱碱中稳定，无腐蚀性。
  • 可燃性危险特性:燃烧产生有毒氮氧化物和硫氧化物气体
  • 类别:农药
  • 注意事项:勿与强酸或强碱性物质混用
  • Sigma Aldrich:834-12-8(sigmaaldrich)
  • 急性毒性:口服- 大鼠 LD50: 508 毫克/ 公斤; 口服- 小鼠 LD50: 965 毫克/ 公斤
  • 上游原料:硫化钠 --> 三聚氯氰 --> 异丙胺 --> 甲硫醇,压力包装,约为22克。 --> 甲硫醇钠 --> 2-氨基-4-甲基-6-甲氧基-1,3,5-三嗪 --> 甲酯
  • 用途二:选择性内吸传导型除草剂。属典型光合作用抑制剂。用于甘蔗、柑橘、玉米、大豆、马铃薯、豌豆、胡萝卜田除防一年生杂草。高剂量可防除某些多年生杂草，亦可防除水生杂草。用于春蔗田，用80%可湿性粉剂1.95～3kg/hm 2 (有效成分1.56～2.4kg)，对水600～750kg做茎叶喷雾处理。用于秋蔗田，用80%可湿性粉剂1.05～1.95kg/hm 2 (有效成分0.84～1.56kg)，对水600～750kg在杂草3叶期喷雾。其他作物可用作播后苗前土壤处理或苗后茎叶处理。莠灭净在低浓度时能促进植物生长，刺激幼芽和根的生长，促进叶面积增大、茎加粗等。但在高浓度时又会在植物产生强烈抑制作用。
  • 杀虫剂单一组分标准液
  • 方法一:由莠去津与甲硫醇反应制得，或2-巯基-4-乙氨基-6-异丙氨基-1，3，5-均三嗪与硫酸二甲酯作用制得。
  • 急救治疗:对症治疗。眼、皮肤充分冲洗干净。

系列性分类

  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Chromatography - Analytical Standards
  4. Environmental Standards - Chromatography
  5. Pesticides & Metabolites - Environmental Standards
  6. Herbicides for Use in Environmental Chromatography Standards
  7. Triazines - Herbicides
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Alphabetic - Analytical Standards
  4. A - Alphabetic
  5. AM to AQ - A

相关产品推荐