2-Methylquinolin-8-ol 8-羟基-2-甲基喹啉

CAS 826-81-3 MFCD00006765

化学结构图

826-81-3
SMILES: Cc1ccc2cccc(O)c2n1

化学属性

Mol. FormulaC10H9NO
Mol. Weight159.18
Density1.21
Boiling Point267°C at 760 mmHg
Melting Point71-73°C
TSCAYes
Flash Point139°C
Solubility不溶
Appearance 白色棱状结晶体。熔点74℃，沸点266-270℃。溶于热醇、乙醚和苯，不溶于水。能随水蒸气挥发，在100℃升华。带有苯酚气味。

别名和识别编码

Chemical Name2-Methylquinolin-8-ol
CAS Number826-81-3
Alfabeta NameMETHYLQUINOLINOL 28---
MDL NumberMFCD00006765
Synonym 2-Methylquinolin-8-ol {LY} 2-Methylquinolin-8-ol {} {LY} 2-Methylquinolin-8-ol {} {} {LY} 2-Methylquinolin-8-ol {} {} {} {LY} 2-Methylquinolin-8-ol {} {} {} {} {LY} 2-Methylquinolin-8-ol {} {} {} {} {} {LY} 2-Methylquinolin-8-ol {} {} {} {} {} {} {LY} 2-Methylquinolin-8-ol {} {} {} {} {} {} {} {LY} 2-Methylquinolin-8-ol {} {} {} {} {} {} {} {} {LY} 2-Methylquinolin-8-ol {} {} {} {} {} {} {} {} {} {LY} 2-Methylquinolin-8-ol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Methylquinolin-8-ol {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Methylquinolin-8-ol {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Methylquinolin-8-ol {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Methylquinolin-8-ol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Methylquinolin-8-ol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Methylquinolin-8-ol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
EC Number212-562-6
Beilstein Registry Number21,106
PubChem Substance ID13224
Chemical Name Translation8-羟基-2-甲基喹啉
Reaxys-RN119194
Wiswesser Line NotationT66 BNJ C1 JQ
LabNetwork Molecule IDLN00005116
InChIInChI=1S/C10H9NO/c1-7-5-6-8-3-2-4-9(12)10(8)11-7/h2-6,12H,1H3
Canonical SMILESCC(C=C1)=NC2=C1C=CC=C2O
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分类

  • {uni_hamburg} no charge; nitrogen heterocycle; carbocycle; aromatic; large ring; fused rings; 6ring; 10ring; alcohol; 1fragment
  • {SNA} Building Blocks, Chemical Synthesis, Heterocyclic Building Blocks, Quinaldines

相关文献及参考

  • Short: II/3 Title: Luminescence of Organic Substances Author: Schmillen, A.; Legler, R. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: II/3 Year: 1967 ISBN: 3-540-03895-7 ISBN: 978-3-540-03895-5 Internet Resource: DOI:10.1007/b86158 RefComment: 270 figs., VIII, 416 pages. Hardcover Abstract: For more than 1000 luminescent organic substances the most important data are represented as wave numbers of absorption and emission bands, decay times and quantum efficiencies. Additional tables contain further information for restricted groups of substances (figures on typical spectra, wave numbers of sharp single bands, influence of surrounding molecules, etc.).
  • Short: IV/20B Title: Vapor Pressure and Antoine Coefficients for Oxygen Containing Organic Compounds Author: Dykyj, J.; Svoboda, J.; Wilhoit, R.C.; Frenkel, M.; Hall, K.R. Editor: Hall, K.R. Source: Landolt-Börnstein, New Series Volume: IV/20B Year: 2000 Keyword: organic compounds; vapor pressure ISBN: 3-540-64968-9 ISBN: 978-3-540-64968-7 Internet Resource: DOI:10.1007/b71424 RefComment: VII, 320 pages.
  • Short: IV/20C Title: Vapor Pressure and Antoine Coefficients for Nitrogen Containing Organic Compounds Author: Dykyj, J.; Svoboda, J.; Wilhoit, R.C.; Frenkel, M.; Hall, K.R. Editor: Hall, K.R. Source: Landolt-Börnstein, New Series Volume: IV/20C Year: 2001 Keyword: organic compounds; vapor pressure ISBN: 3-540-41060-0 ISBN: 978-3-540-41060-7 Internet Resource: DOI:10.1007/b88812 RefComment: VII, 197 pages
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15

安全信息

Warnings IRRITANT
Signal word
GHS Symbol
WGK Germany2
Safety Statements
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S22 Do not breathe dust 不要吸入粉尘；
  • S57 Use appropriate containment to avoid environmental contamination 使用适当容器避免环境污染；
Risk Statements
  • R50/53
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P350
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P332+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
Personal Protective Equipment Eyeshields, Gloves
RTECSVC7920000
Packing GroupIII
UN Number UN3077 UN 3077 9/PG 3 3077
Hazard Codes
Hazard Class9 
TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 500 nmol/plate
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 42,335,1977

Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

  • Sigma Aldrich:1127-45-3(sigmaaldrich)
  • Acros Organics:8-羟基喹啉-N-氧化物 8-Hydroxyquinoline-N-oxide, 99%(1127-45-3)
  • 8-羟基喹哪啶价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 30103880 8-羟基喹哪啶 25g 132元 2011/08/23 30103823 8-羟基喹哪啶 10g 35元 2011/04/16 M0420 8-羟基喹哪啶 8-Hydroxyquinaldine 500G 1810元
  • Sigma Aldrich:826-81-3(sigmaaldrich)
  • 下游产品:8-羟基喹啉-2-甲醛
  • 图谱信息:8-羟基喹哪啶(826-81-3)核磁图( 1 HNMR) 8-羟基喹哪啶(826-81-3)核磁图( 13 CNMR) 8-羟基喹哪啶(826-81-3)红外图谱(IR2) 8-羟基喹哪啶(826-81-3)质谱(MS) 8-羟基喹哪啶(826-81-3)红外图谱(IR1)
  • TCI Shanghai:2-甲基-8-羟基喹啉 8-Hydroxyquinaldine,>;98.0%(GC)(T)(826-81-3)
  • 8-羟基喹啉-N-氧化物价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 H1272 8-羟基喹啉N-氧化物 8-Hydroxyquinoline N-Oxide 5G 1410元 2014/06/02 H1272 8-羟基喹啉N-氧化物 8-Hydroxyquinoline N-Oxide 25G 4780元 2010/06/21 153440050 8-羟基喹啉-N-氧化物 8-Hydroxyquinoline-N-oxide 99% 5 GR 1203元
  • MOL 文件:1127-45-3.mol
  • Hazard Note:Irritant
  • Acros Organics:8-羟基-2-甲基喹啉 8-Hydroxyquinaldine, 98%(826-81-3)
  • MSDS 信息:8-Hydroxyquinoline-N-oxide(1127-45-3).msds
  • MOL 文件:826-81-3.mol
  • 海关编码:29334990
  • 上游原料:2-氨基苯酚 --> 2-硝基苯酚 --> 巴豆醛
  • Alfa Aesar:8-羟基-2-甲基喹啉,98% 8-Hydroxy-2-methylquinoline, 98%(826-81-3)
  • 用途一:用作分析试剂。
  • F:3-10
  • 方法一:由邻氨基苯酚与巴豆醛反应而得。将邻氨基苯酚和邻硝基苯酚均匀混合，加入盐酸。在搅拌下加入巴豆醛。加热6h，放置过夜。用水蒸气蒸馏将示反应的邻硝基苯酚蒸出，在蒸余液中加入氢氧化钠溶液使呈弱碱性。再加粉末状的碳酰内进行饱和，用水蒸气蒸馏出8-羟基喹哪啶，将此粗品再经减压蒸馏，用乙醇重结晶，得纯品。
  • MSDS 信息:8-Hydroxyquinaldine(826-81-3).msds

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Isoquinolines 异喹啉
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Pyrrolines 吡咯啉
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Quinaldines 奎纳丁
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Quinolines 喹啉
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Quinolines 喹啉

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