CAS 8001-35-2 MFCD00132872-毒杀芬;八氯莰烯;氯化莰烯;氯化莰毒杀芬 TAO{mole}

毒杀芬;八氯莰烯;氯化莰烯;氯化莰毒杀芬

CAS 8001-35-2 MFCD00132872

化学结构图

SMILES: C=C1C(CCl)(CCl)C2(Cl)C(Cl)C(Cl)C1(Cl)C2(Cl)Cl

化学属性

Flash Point	4 °C
Mol. Weight	413.80
Mol. Formula	C10H10Cl8
Solubility	不溶于水，易溶于多数有机溶剂。
Density	0.66
Stability	对光敏感
Melting Point	65-90°C

别名和识别编码

Synonym	CHLORINATED CAMPHENE PENPHENE(R) Toxakil Estonox PHENETOX(R) PCC Phenatox Camphofene huileux POLYCHLOROBICYCLIC TERPENES Latka 3956 Camphoclor TOXAPHEN COMPONENT 50 CAMPHECHLOR Kamfochlor 八氯茨烯 Agricide maggot killer (F) Alltox SYNTHETIC 3956(R) 氯化莰、氯化茨烯、八氯茨烯、氯代莰烯、3956、多氯莰烯 Chlorinated camphene 氯化莰烯 Vertac toxaphene 90 Chlorinated camphene 60% ALLTEX(R) HERCULES 3956(R) Fasco-terpene 氯代莰烯(毒杀芬) Toxyphen Toxaphene ENT 9,735 CAMPHECHLOR-(TOXAPHENE) 毒杀芬多氯莰烯 Attac 8 agricidemaggotkiller(f) RCRA waste number P123 TOXAPHEN COMPONENT 26 TOXAPHENE (TM) GENIPHENE(R) Phenacide Camphechlor Toxafeen Clor Chem T-590 TOXAKIL(R) Strobane T-90 Attac 6-3 氯化茨烯毒杀芬;八氯莰烯;氯化莰烯;氯化莰 TOXAPHEN M 5055 八氯莰烯 Strobane-T Toxaphen TOXAPHENE CALIBRATION MIX Anatox TOXAPHENE Attac 4-4 Melipax 氯代莰烯 Hercules 3956 TOXAPHEN COMPONENT 62 SOLUTION Geniphen 氯化莰 Polychlorocamphene Attac 4-2 Attac 6 Compound 3956 Toxon 63 Camphochlor Cristoxo 90 NCI-C00259 PHENACIDE(R)
CAS Number	8001-35-2
MDL Number	MFCD00132872
EC Number	232-283-3
Chemical Name Translation	毒杀芬
Merck Number	13,9633
Chemical Name	Camphechlor Solution
Wiswesser Line Notation	L55 A CYTJ CU1 D1 D1 XG XG XG
PubChem Substance ID	5284469
InChI	InChI=1S/C10H8Cl8/c1-4-7(2-11,3-12)9(16)6(14)5(13)8(4,15)10(9,17)18/h5-6H,1-3H2

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分类

2000/60/EC, 500 Series Drinking Water Methods, 600 Series Wastewater Methods, 8000 Series Solidwaste Methods, Acaricides, Alpha sort, Alphabetic, Analytical Standards, Analytical/Chromatography, Chromatography, EPA, Environmental Standards, European Community: ISO, DIN and DL 152, Insecticides, Method 1311, Method 505, Method 508, Method 608, Method 625, Method Specific, Oeko-Tex Standard 100, Organochlorines, Pesticides, Pesticides & Metabolites, Q-Z, T,

产品应用

为非内吸的持久性接触和胃毒杀虫剂，也有杀螨作用。主要用于防治棉花铃期害虫，如棉铃象鼻虫、棉红铃虫、棉蚜虫，也可用于玉米、水稻、蔬菜、苎麻、果树、森林等方面的害虫，如水稻螟虫、稻苞虫、稻蓟马、稻尽虱、浮尘子、稻螟、稻铁虫、松毛虫、松毒蛾、柠檬恶性叶虫、柑桔凤蝶，苎麻黄夹蝶等，此外，还可杀灭牲畜、家禽体外寄生虫，拌种可防治地下害虫。
校准仪器和装置；评价方法；工作标准；质量保证/质量控制；其他。

安全信息

Hazard statements

H370 Causes damage to organs 导致器官损伤
H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
H301+H311+H331
H315 Causes skin irritation 会刺激皮肤
H301 Toxic if swallowed 吞食有毒
H312 Harmful in contact with skin 皮肤接触有害
H335 May cause respiratory irritation 可能导致呼吸道刺激
H351 Suspected of causing cancer 怀疑致癌

Hazard Codes T,N,Xn,F,Xi T

GHS Symbol

Precautionary statements

P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P301+P310
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
P273 Avoid release to the environment. 避免释放到环境中。
P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
P501 Dispose of contents/container to..… 处理内容物/容器.....
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。

WGK Germany3

Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges

Signal word Danger

RTECSXW5250000

Storage condition 避光、冷藏保存。室温储存 2-8°C

UN Number 2761

Safety Statements

S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
S33 Take precautionary measures against static discharges 对静电采取预防措施；
S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
S36 Wear suitable protective clothing 穿戴适当的防护服；
S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label where possible 吞食后不要催吐：立即求医并出示该容器或标签；

Risk Statements

R11 Highly flammable 非常易燃
R25 Toxic if swallowed 吞咽有毒
R38 Irritating to skin 刺激皮肤
R21 Harmful in contact with skin 与皮肤接触有害
R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有毒
R37/38 Irritating to respiratory system and skin 对呼吸系统和皮肤有刺激性
R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
R50/53
R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
R65 Harmful: may cause lung damage if swallowed 若吞咽可能伤害肺部器官
R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥
R39/23/24/25 Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed 毒性：吸入，皮肤接触和吞食都会产生十分严重的不可逆危险

Restrict 剧毒化学品

Warnings 危化品目录(2015) 危险化学品

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 30 gm/kg/80W-C
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Blood - lymphoma, including Hodgkin's disease
REFERENCE :
   NCITR* National Cancer Institute Carcinogenesis Technical Report Series.
   (Bethesda, MD)  No.0-205. For publisher information, see NTPTR*.
   Volume(issue)/page/year: NCI-TR-137,1979

TYPE OF TEST            : TD - Toxic dose (other than lowest)
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 13 gm/kg/80W-C
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Liver - tumors
REFERENCE :
   NCITR* National Cancer Institute Carcinogenesis Technical Report Series.
   (Bethesda, MD)  No.0-205. For publisher information, see NTPTR*.
   Volume(issue)/page/year: NCI-TR-137,1979

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 6600 mg/kg/80W-C
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Liver - tumors
REFERENCE :
   NCITR* National Cancer Institute Carcinogenesis Technical Report Series.
   (Bethesda, MD)  No.0-205. For publisher information, see NTPTR*.
   Volume(issue)/page/year: NCI-TR-137,1979

TYPE OF TEST            : TDLo - Low

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Unreported
SPECIES OBSERVED        : Human - man
DOSE/DURATION           : 44 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85DCAI "Poisoning; Toxicology, Symptoms, Treatments," 2nd ed., Arena, J.M.,
   Springfield, IL, C.C. Thomas, 1970  Volume(issue)/page/year: 2,73,1970

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 50 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   ARZNAD Arzneimittel-Forschung. Drug Research.  (Editio Cantor Verlag,
   Postfach 1255, W-7960 Aulendorf, Fed. Rep. Ger.)  V.1-    1951-
   Volume(issue)/page/year: 17,614,1967

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - guinea pig
DOSE/DURATION           : 250 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85DPAN "Wirksubstanzen der Pflanzenschutz und Schadlingsbekampfungsmittel,"
   Perkow, W., Berlin, Verlag Paul Parey, 1971-1976  Volume(issue)/page/year:
   -,-,1971/1976

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Mammal - dog
DOSE/DURATION           : 15 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   SPEADM Special Publication of the Entomological Society of America.  (4603
   Calvert Rd., College Park, MD 20740)  Volume(issue)/page/year: 78-1,13,1978

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Unreported
SPECIES

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 100 ug/plate
REFERENCE :
   ENMUDM Environmental Mutagenesis.  (New York, NY)  V.1-9, 1979-87.  For
   publisher information, see EMMUEG.  Volume(issue)/page/year: 8(Suppl
   7),1,1986

TYPE OF TEST            : Cytogenetic analysis
ROUTE OF EXPOSURE       : Multiple routes
TEST SYSTEM             : Fish - not otherwise specified
DOSE/DURATION           : 1500 ug/kg/10D (Continuous)
REFERENCE :
   BIZNAT Biologisches Zentralblatt.  (VEB Georg Thieme, Postfach 946, Leipzig
   DDR-7010,

TYPE OF TEST            : Sister chromatid exchange
TEST SYSTEM             : Human Lymphocyte
DOSE/DURATION           : 10 umol/L
REFERENCE :
   ARTODN Archives of Toxicology.  (Springer-Verlag, Heidelberger Pl. 3, D-1000
   Berlin 33, Fed. Rep. Ger.)  V.32-    1974-  Volume(issue)/page/year:
   52,221,1983

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 500 ug/plate
REFERENCE :
   SCIEAS Science.  (American Assoc. for the Advancement of Science,

TYPE OF TEST

TYPE OF TEST            : Phage inhibition capacity
TEST SYSTEM             : Bacteria - Escherichia coli
DOSE/DURATION           : 100 umol/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 182,193,1987

TYPE OF TEST            : Cytogenetic analysis
ROUTE OF EXPOSURE       : Multiple routes
TEST SYSTEM             : Fish - not otherwise specified
DOSE/DURATION           : 1500 ug/kg/10D (Continuous)
REFERENCE :
   BIZNAT Biologisches Zentralblatt.  (VEB Georg Thieme, Postfach 946, Leipzig
   DDR-7010, Ger. Dem. Rep.) V.1-    1881-  Volume(issue)/page/year:
   94,441,1975

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 900 ug/kg
SEX/DURATION            : female 5-22 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Effects on Newborn - behavioral
REFERENCE :
   AECTCV Archives of Environmental Contamination and Toxicology.
   (Springer-Verlag New York, Inc., Service Center, 44 Hartz Way, Secaucus, NJ
   070944)  V.1-    1973-  Volume(issue)/page/year: 9,247,1980

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE                    : 100 mg/kg
SEX/DURATION            : female 8 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Specific Developmental Abnormalities - musculoskeletal system
REFERENCE :
   TCMUD8 Teratogenesis, Carcinogenesis, and Mutagenesis.  (Alan R. Liss, Inc.,
   41 E. 11th St., New York, NY 10003)  V.1-    1980- Volume(issue)/page/year:
   5,3,1985

TYPE OF TEST            :

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 280 mg/kg
SEX/DURATION            : male 10 week(s) pre-mating
TOXIC EFFECTS :
   Reproductive - Paternal Effects - spermatogen

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 150 mg/kg
SEX/DURATION            : female 7-16 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Specific Developmental Abnormalities - musculoskeletal system
REFERENCE :
   BECTA6 Bulletin of Environmental Contamination and Toxicology.
   (Springer-Verlag New York, Inc., Service Center, 44 Hartz Way, Secaucus, NJ
   07094)  V.1-    1966-  Volume(issue)/page/year: 15,660,1976

TYP

其他信息

生产方法:由莰烯与氯反应而得。松节油经减压蒸馏提取α-蒎烯，在水合氧化钛存在下进行异构化，异构液经减压蒸馏得到纯度在90%以上的莰稀。将莰烯溶于2.5倍的四氯化碳中，通氯反应。氯化过程可采用间歇法或连续法，先使莰烯四氯化碳溶液与氯化反应尾气中的氯气反应，然后将此莰烯四化碳溶液与新鲜的氯气反应。氯化反应在光照下进行，反应温度在40-60℃之间，氯气经串联反应后，尾气含少量余氯和大量氯化氢，尾气压力为10.7kPa左右，可用液碱吸收综合利用。氯化液的含氯量达到66.5-68.5%后，光照后，放料至水蒸气蒸馏锅，在110℃蒸馏得毒杀芬。工业品为莰烯氯化异构反应的混合物。含氯量为66.5-68.5%的毒杀芬原粉，每吨消耗松节油700kPa左右，氯气1350kPa。商品有40%或50%的乳油。
MOL 文件:8001-35-2.mol
杀虫剂单一组分标准液
稳定性:Stable. Incompatible with alkali, strong oxidizers. Heat and light sensitive.
用途:为非内吸的持久性接触和胃毒杀虫剂，也有杀螨作用。主要用于防治棉花铃期害虫，如棉铃象鼻虫、棉红铃虫、棉蚜虫，也可用于玉米、水稻、蔬菜、苎麻、果树、森林等方面的害虫，如水稻螟虫、稻苞虫、稻蓟马、稻尽虱、浮尘子、稻螟、稻铁虫、松毛虫、松毒蛾、柠檬恶性叶虫、柑桔凤蝶，苎麻黄夹蝶等，此外，还可杀灭牲畜、家禽体外寄生虫，拌种可防治地下害虫。
RTECS号:XW5250000
不溶于水，溶于四氯化碳、苯及其他芳烃有机溶剂。带萜类气味，不易挥发，不可燃，温度高于155℃时逐步分解。
外观性质:乳白色或琥珀色蜡样固体。
PackingGroup:III
HazardClass:6.1(b)