Alpha-Pinene α-蒎烯

CAS 80-56-8 MFCD00001339

化学结构图

80-56-8
SMILES: CC1=CCC2CC1C2(C)C

化学属性

Mol. FormulaC₁₀H₁₆
Mol. Weight136.23
Density0.858
Boiling Point-
Refractive indexn20/D 1.465(lit.)
Autoignition Point491 °F
Melting Point-55
Flash Point-
Solubility微溶于水,溶于乙醇、乙醚、氯仿等多数有机溶剂。

别名和识别编码

Chemical NameAlpha-Pinene
Synonym (±)-2-Pinene 2,6,6-Trimethylbicyclo[3.1.1]hept-2-ene alpha-Pinene (+)-Β-蒎烯 (±)-2-Pinene; 2,6,6-​Trimethylbicyclo[3.1.1]​hept-​2-​ene; alpha-Pinene (±)-2-pinene 2,6,6-Trimethylbicyclo(3.1.1)-2-hept-2-ene 2,6,6-Trimethylbicyclo[3.1.1]-2-heptene 2,6,6-Trimethylbicyclo[3.1.1]hept-2-ene <undefined optical isomer> 2,6,6-三甲 2,6,6-三甲基双环[3.1.1]庚-2-烯 2-Pinene {Chemicalbook} A-PINENE Acintene A Alpha-Pinen Bicyclo[3.1.1]hept-2-ene,2 C10
MDL Number-
CAS Number80-56-8
EC Number201-291-9
Beilstein Registry Number3194807
PubChem Substance ID24848559
Chemical Name Translationα-蒎烯
InChIKeyGRWFGVWFFZKLTI-UHFFFAOYSA-N
Wiswesser Line NotationL46 A EUTJ A1 A1 E1
LabNetwork Molecule IDLN00225136
Canonical SMILES-
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分类

  • {uni_hamburg} no charge; carbocycle; fus
  • Alphabetical, Analytical Standards, Analytical/Chromatography, Artemisia, Boswellia, Cannabis, Chromatography, Cinnamomum, Echinacea, Eucalyptus, Foeniculum, Isoprenoids, Life Sciences Standards, Myristica, N - R, Phytopharma Primary Standards, Phytopharma Standards, Rosmarinus, Salvia, Standards by Plant Genus, Substance Classification, Syzygium, Tanacetum, Thymus, Valeriana, Vitex
  • {SNA} Alkenes,
  • {SNA} Alkenes,

产品应用

  • α-Pinene was used as standard in headspace solid-phase microextraction-gas chromatographic analysis of volatile compounds in virgin olive oils. It was used in the synthesis of cesium-doped heteropolyacid having potential application in biodiesel synthesis

相关文献及参考

  • Merck 14 ,7445
  • Short: II/25D Title: Structure Data of Free Polyatomic Molecules: Molecules Containing Five or More Carbon Atoms Author: Graner, G.; Hirota, E.; Iijima, T.; Kuchitsu, K.; Ramsay, D.A.; Vogt, J.; Vogt, N. Editor: Kuchitsu, K. Source: Landolt-Börnstein, New Series Volume: II/25D Year: 2003 Keyword: Free Polyatomic Molecules; Carbon Atoms; Molecules ISBN: 3-540-42860-7 ISBN: 978-3-540-42860-2 Internet Resource: DOI:10.1007/b75952 RefComment: VIII, 569 pages. Hardcover RefComment: Written for scientists and researchers in the fields of chemistry and physics Abstract: This fourth subvolume presents data on the geometric parameters (internuclear distances, bond angles, dihedral angles of internal rotation etc) of free polyatomic molecules including free radicals and molecular ions. The survey on structure data consists of four subvolumes, each containing the geometric parameters determined in the gas phase either by an analysis of the rotational constants (and sometimes the vibrational constants) obtained from microwave, infrared, Raman, electronic and photoelectron spectroscopy or by an analysis of electron diffraction intensities. Most of the structures listed in the tables are for molecules in the electronic ground state, but structures for electronically excited states have also been included as far as they are available. In this fourth subvolume, the structure of molecules containing five to sixty carbon atoms is listed.
  • Short: II/27B Title: Diamagnetic Susceptibility of Organic Compounds, Oils, Paraffins and Polyethylenes Author: Kumar, M.; Gupta, R. Editor: Gupta, Radha Raman Source: Landolt-Börnstein, New Series Volume: II/27B Year: 2008 Keyword: diamagnetic susceptibility; organic compounds ISBN: 978-3-540-44359-9 (print) ISBN: 978-3-540-45860-9 (online) Internet Resource: doi:10.1007/978-3-540-45860-9 RefComment: VIII, 503 p. With CD-ROM., Hardcover RefComment: Written for: Scientists and researche

安全信息

RTECSDT7000000
GHS Symbol
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P310
  • P305+P351+P338
  • P331 Do NOT induce vomiting.. 不要催吐。
  • P370+P378
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H304 May be fatal if swallowed and enters airways 吞食和进入呼吸道可能致命
  • H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
WGK Germany3
Signal word Danger
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S29 Do not empty into drains 不要排入下水道;
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护;
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
Risk Statements
  • R10 Flammable 易燃
  • R20 Harmful by inhalation 吸入有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
  • R38 Irritating to skin 刺激皮肤
  • R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
  • R50/53
  • R51/53
  • R65 Harmful: may cause lung damage if swallowed 若吞咽可能伤害肺部器官
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes 3 Xi,N Xn
Packing GroupIII
UN Number 2368
Warnings 危化品目录(2015) 危险化学品
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 3700 mg/kg
TOXIC EFFECTS :
   Brain and Coverings - recordings from specific areas of CNS
   Behavioral - somnolence (general depressed activity)
   Lungs, Thorax, or Respiration - other changes
REFERENCE :
   FCTXAV Food and Cosmetics Toxicology.  (London, UK)  V.1-19, 1963-81.  For
   publisher information, see FCTOD7.  Volume(issue)/page/year: 16,853,1978

TYPE OF TEST            : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 625 ug/m3
TOXIC EFFECTS :
   Brain and Coverings - recordings from specific areas of CNS
   Sense Organs and Special Senses (Eye) - effect, not otherwise specified
   Lungs, Thorax, or Respiration - other changes
REFERENCE :
   FCTXAV Food and Cosmetics Toxicology.  (London, UK)  V.1-19, 1963-81.  For
   publisher information, see FCTOD7.  Volume(issue)/page/year: 16,853,1978

TYPE OF TEST            : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - guinea pig
DOSE/DURATION           : 572 ug/m3
TOXIC EFFECTS :
   Brain and Coverings - recordings from specific areas of CNS
   Sense Organs and Special Senses (Eye) - effect, not otherwise specified
   Lungs, Thorax, or Respiration - other changes
REFERENCE :
   FCTXAV Food and Cosmetics Toxicology.  (London, UK)  V.1-19, 1963-81.  For
   publisher information, see FCTOD7.  Volume(issue)/page/year: 16,853,1978

TYPE OF TEST            : LD - Lethal dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : >500 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CBCCT* "Summar

Storage condition 4°C

其他信息

  • MSDS 信息:2437-95-8.msds
  • 下游产品:芳樟醇 --> 香茅醇 --> 双戊烯 --> 松脂醇 --> alpha-松油醇 --> 毒杀芬 --> 莰烯 --> 乙酸异龙脑酯 --> 月桂烯 --> 萜烯树脂,合成品 --> beta-蒎烯
  • α-Pinene is a chemical constituent of essential oil extracted from the stem of Canarium tramdenanum.
  • 外观性质:无色透明液体,有松节油的气味。
  • 食品添加剂最大允许使用量最大允许残留量标准:添加剂中文名称 允许使用该种添加剂的食品中文名称 添加剂功能 最大允许使用量(g/kg) 最大允许残留量(g/kg) β-蒎烯 食品 食品用香料 用于配制香精的各香料成分不得超过在GB 2760中的最大允许使用量和最大允许残留量
  • MOL 文件:2437-95-8.mol

系列性分类


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