(R)-(–)-3,3'-Bis(triphenylsilyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate (R)-(-)-3,3'-二(三苯基硅烷基)-1,1'-联萘基-2,2'-二基氢磷酸酯

CAS 791616-55-2 MFCD91616552

化学结构图

791616-55-2
SMILES: OP1(=O)OC2=C(C3=C(O1)C(=CC1C=CC=CC=13)[Si](C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1)C1C=CC=CC=1C=C2[Si](C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1

化学属性

Mol. Weight865.07
Mol. FormulaC56H41O4PSi2
Melting Point329-335
Appearance white to light-yellow pwdr.

别名和识别编码

Synonym (11bR)-4-羟基-2,6-双(三苯甲硅烷基)二萘并-[2,1-d:1′,2′f]-1,3,2-二恶磷环庚烷-4-氧化物 Carreira SALDIPAC Ligand MacMillan TiPSY 催化剂 MacMillan TiPSY 催化剂 Carreira SALDIPAC Ligand (R)-(–)-3,3′-双(三苯甲硅烷基)-1,1′-联萘-2,2′-二酚磷酸酯
Chemical Name(R)-(–)-3,3'-Bis(triphenylsilyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate
Chemical Name Translation(R)-(-)-3,3'-二(三苯基硅烷基)-1,1'-联萘基-2,2'-二基氢磷酸酯
MDL NumberMFCD09265079
PubChem Substance ID24885235
CAS Number791616-55-2
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分类

  • {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Chiral Phosphoric Acids

安全信息

Hazard Codes Xi
Safety Statements
WGK Germany3
GHS Symbol
Precautionary statements
Signal word
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

系列性分类

  1. Phosphine
  2. Phosphorus
  1. Catalysts
  2. Phosphorus

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