N-Bromoacetamide N-溴代乙酰胺
CAS 79-15-2 MFCD00037097
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信息真实价格透明
资金保障
专业采购外包团队在线服务
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现货库存
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分类
- Analytical Standards, Analytical/Chromatography, Biochemicals and Reagents, Chromatography, D to K, Environmental Standards, Enzyme Inhibitors,
- {SNA} Analytical Standards, Analytical/Chromatography, Biochemicals and Reagents, Chromatography, D to K, Environmen
- {SN
相关文献及参考
- Merck 14 ,1398
- Source of positive bromine, useful for the conversion of alkenes to bromohydrins under mild conditions: Helv. Chim. Acta, 26, 562, 746, 1799 (1943); Tetrahedron Lett., 765 (1973). It is also a useful reagent for mild oxidation of secondary alcohols to ketones: J. Biol. Chem., 184, 393 (1950); J. Am. Chem. Soc., 76, 3682 (1954); 85, 1409 (1963).
- In combination with AgOAc and AcOH, has been used to convert alkenes stereoselectively to cis-1,2-diols: Tetrahedron Lett., 1581 (1976).
安全信息
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
- P305+P351+P338+P310
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P301+P330+P331+P310
- P303+P361+P353
- P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
GHS Symbol
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- H302+H312+H332
- S36 Wear suitable protective clothing 穿戴适当的防护服;
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
- S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
- S37 Wear suitable gloves 戴适当手套;
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- R34 Causes burns 会导致灼伤
其他信息
- 用途一:用于有机合成。作溴化剂,氧化剂,催化剂。
- TCI Shanghai:N-溴代乙酰胺 N-Bromoacetamide,>;97.0%(T)(79-15-2)
- F:8
- Alfa Aesar:N-溴乙酰胺,95% N-Bromoacetamide, 95%(79-15-2)
- MOL 文件:79-15-2.mol
- 图谱信息:N-溴代乙酰胺(79-15-2)红外图谱(IR3) N-溴代乙酰胺(79-15-2)核磁图( 13 CNMR) N-溴代乙酰胺(79-15-2)红外图谱(IR1) N-溴代乙酰胺(79-15-2)质谱(MS) N-溴代乙酰胺(79-15-2)红外图谱(IR2)
- color:white to yellow
- Sigma Aldrich:79-15-2(sigmaaldrich)
- N-溴代乙酰胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 B0530 N-溴代乙酰胺 N-Bromoacetamide 5G 350元 2014/06/02 B0530 N-溴代乙酰胺 N-Bromoacetamide 25G 750元 2010/05/25 L02953 N-溴乙酰胺, 95% N-Bromoacetamide, 95% 5g 818元
- 方法一:由乙酰胺与溴反应而得。将乙酰胺溶于摩尔的液溴中,在冷却至4-5℃后,搅拌下加入预冷的氢氧化钾溶液。生成半固体物在0-5℃放置2-3h。在反应混合物中加氯化钠、氯仿,搅拌加热后,将氯仿溶液从固体物质中倾出,用氯仿再萃取两次。将萃取液加无水硫酸钠干燥,过滤。加入乙烷使结晶析出,冷却,过滤,用己烷洗涤,干燥即得N-溴乙酰胺。产率约50%。
- 上游原料:氢氧化钾溶液 --> 液溴