CAS 781-43-1 MFCD00001262-9,10-Dimethylanthracene 9,10-二甲基蒽 TAO{mole}

9,10-Dimethylanthracene 9,10-二甲基蒽

CAS 781-43-1 MFCD00001262

化学结构图

SMILES: Cc1c2ccccc2c(C)c2ccccc12

化学属性

Mol. Formula	C16H14
Mol. Weight	206.28
Melting Point	182-184 °C
TSCA	No
Boiling Point	375.14 °C at 760 mmHg
Density	1.084
Appearance	淡黄色针状或片状结晶。熔点180-181℃，沸点140-142℃（66.7-133Pa）。溶于苯、甲苯、乙醇，不溶于水。

别名和识别编码

Chemical Name	9,10-Dimethylanthracene
MDL Number	MFCD00001262
PubChem Substance ID	13076
Beilstein Registry Number	5(3)2166
CAS Number	781-43-1
EC Number	212-308-4
Reaxys-RN	1909028
Synonym	9,10-Dimethylanthracene {LY} 9,10-Dimethylanthracene {} {LY} 9,10-Dimethylanthracene {} {} {LY} 9,10-Dimethylanthracene {} {} {} {LY} 9,10-Dimethylanthracene {} {} {} {} {LY} 9,10-Dimethylanthracene {} {} {} {} {} {LY} 9,10-Dimethylanthracene {} {} {} {} {} {} {LY} 9,10-Dimethylanthracene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 9,10-Dimethylanthracene {} {} {} {} {} {} {} {} {LY} 9,10-Dimethylanthracene {} {} {} {} {} {} {} {} {} {LY} 9,10-Dimethylanthracene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 9,10-Dimethylanthracene {} {} {} {} {} {} {} {} {} {} {} {LY} 9,10-Dimethylanthracene {} {} {} {} {} {} {} {} {} {} {} {} {LY} 9,10-Dimethylanthracene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 9,10-Dimethylanthracene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 9,10-Dimethylanthracene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 9,10-Dimethylanthracene {} {} {} {} {} {} {} {} {} {} {} {}
Chemical Name Translation	9,10-二甲基蒽
Wiswesser Line Notation	L C666J B1 I1
LabNetwork Molecule ID	LN01109232
InChI	InChI=1S/C16H14/c1-11-13-7-3-5-9-15(13)12(2)16-10-6-4-8-14(11)16/h3-10H,1-2H3
Canonical SMILES	CC(C1=CC=CC=C21)=C3C=CC=CC3=C2C

信息真实价格透明资金保障专业采购外包团队在线服务

品牌质保精细包装现货库存一流品牌服务

产品应用

用于有机合成。

安全信息

RTECSCA9685000

GHS Symbol

Precautionary statements

P201 Obtain special instructions before use. 使用前获取专门指示。
P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P281 Use personal protective equipment as required. 使用所需的个人防护装备。
P284 Wear respiratory protection.? 佩戴呼吸保护装置。
P285 In case of inadequate ventilation wear respiratory protection. 在通风不足的情况下，戴呼吸防护。
P302+P352
P304+P312
P304+P340
P304+P341
P308+P313
P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医，如果你觉得不舒服
P320 Specific treatment is urgent (see … on this label). 紧急具体治疗（见本标签上的）。
P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
P322 Specific measures (see …on this label). 具体治疗（见本标签上的）。
P333+P313
P342+P311
P361 Remove/Take off immediately all contaminated clothing. 立即去除/脱掉所有被污染的衣服。
P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
P403+P233
P405 Store locked up. 上锁保管。
P501 Dispose of contents/container to..… 处理内容物/容器.....

Hazard statements

H311 Toxic in contact with skin 皮肤接触中毒
H312 Harmful in contact with skin 皮肤接触有害
H317 May cause an allergic skin reaction 可能导致皮肤过敏
H330 Fatal if inhaled 吸入致命
H332 Harmful if inhaled 吸入有害
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled 吸入可能导致过敏或哮喘症状或呼吸困难
H351 Suspected of causing cancer 怀疑致癌
H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官

Hazard Codes Xn

WGK Germany3

Personal Protective Equipment dust mask type N95 (US), Eyeshields, Faceshields, Gloves

Signal word Danger {} {} {} {TCI}

Safety Statements

S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
S36/39 Wear suitable protective clothing and eye/face protection 穿戴适当的防护服和眼睛/面保护；

Risk Statements

R42/43
R20/21 Harmful by inhalation and in contact with skin 吸入及与皮肤接触有害
R68 Possible risk of irreversible effects 可能有不可挽回的作用的危险
R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1100 mg/kg/46W-I
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Lungs, Thorax, or Respiration - tumors
   Skin and Appendages - tumors
REFERENCE :
   CNREA8 Cancer Research. (Public Ledger Building, Suit 816, 6th & Chestnut
   Sts., Philadelphia, PA 19106)  V.1-    1941-  Volume(issue)/page/year:
   2,157,1942

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 40 mg/kg/20D-I
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Skin and Appendages - tumors
REFERENCE :
   CRNGDP Carcinogenesis (London). (Oxford Univ. Press, Pinkhill House,
   Southfield Road, Eynsham, Oxford OX8 1JJ, UK)  V.1-    1980-
   Volume(issue)/page/year: 6,1483,1985

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : >184 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   PMRSDJ Progress in Mutation Research.  (Elsevier Science Pub. Co., Inc., 52
   Vanderbilt Ave., New York, NY 10017)  V.1-    1981- Volume(issue)/page/year:
   1,682,1981

TYPE OF TEST            : Morphological transformation
TEST SYSTEM             : Rodent - hamster Kidney
DOSE/DURATION           : 80 ug/L
REFERENCE :
   BJCAAI British Journal of Cancer.  (Macmillan Press Ltd., Houndmills,
   Basingstoke, Hants. RG21 2XS, UK)  V.1-    1947-  Volume(issue)/page/year:
   37,873,1978

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Escherichia coli
DOSE/DURATION           : 10 ug/plate
REFERENCE :
   PMRSDJ Progress in Mutation Research.  (Elsevier Science Pub. Co., Inc., 52
   Vanderbilt Ave., New York, NY 10017)  V.1-    1981- Volume(

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 100 ug/plate
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB

TYPE OF TEST            : Mutation test systems - not otherwise specified
TEST SYSTEM             : Bacteria - Escherichia coli
DOSE/DURATION           : 30 nmol/tube
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 147,79,1985

TYPE OF TEST            : Sex chromosome loss and n

TYPE OF TEST            : DNA repair
TEST SYSTEM             : Yeast - Saccharomyces cerevisiae
DOSE/DURATION           : 100 mg/L
REFERENCE :
   PMRSDJ Progress in Mutation Research.  (Elsevier Science Pub. Co., Inc., 52
   Vanderbilt Ave., New York, NY 10017)  V.1-    1981- Volume(issue)/page/year:
   1,502,1981

TYPE OF TEST            : Sister chromatid exchange
TEST SYSTEM             : Human Lymphocyte
DOSE/DURATION           : 100 umol/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 211,77,1989

TYPE OF TEST

Storage condition 2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

TCI Shanghai:9,10-二甲基蒽 9,10-Dimethylanthracene,>;98.0%(GC)(781-43-1)
用途一:用于有机合成。
Sigma Aldrich:781-43-1(sigmaaldrich)
9,10-二甲基蒽价格(试剂级):更新日期产品编号产品名称包装价格 2014/06/02 D0252 9,10-二甲基蒽 9,10-Dimethylanthracene 1G 789元 2014/06/02 D0252 9,10-二甲基蒽 9,10-Dimethylanthracene 10G 4030元 2010/06/21 115972500 9,10-二甲基蒽 9,10-Dimethylanthracene 97% 250 MG 461元
Alfa Aesar:9,10-二甲基蒽,99% 9,10-Dimethylanthracene, 99%(781-43-1)
上游原料:碘甲烷 --> 硫脲 --> 锌粉 --> 蒽醌 --> 9,10-二氢蒽
Acros Organics:9,10-二甲基蒽 9,10-Dimethylanthracene, 97%(781-43-1)
溶于苯、甲苯、乙醇，不溶于水。
图谱信息:9,10-二甲基蒽(781-43-1)红外图谱(IR3) 9,10-二甲基蒽(781-43-1)红外图谱(IR1) 9,10-二甲基蒽(781-43-1)红外图谱(IR2) 9,10-二甲基蒽(781-43-1)质谱(MS) 9,10-二甲基蒽(781-43-1)核磁图( 13 CNMR)
MOL 文件:781-43-1.mol
方法一:由蒽醌与甲基碘化镁反应生成9,10-二甲基-9,10-二羟基蒽，再在乙酸、锌粉和硫脲存在下脱羟基即得该品。