CAS 7722-84-1 MFCD00011333-Hydrogen peroxide 双氧水(易制爆)(易涉毒) TAO{mole}

Hydrogen peroxide 双氧水(易制爆)(易涉毒)

CAS 7722-84-1 MFCD00011333

化学结构图

SMILES: OO

化学属性

Mol. Formula	H2O2
Mol. Weight	34.01
Density	1.000 g/cm3
Refractive index	n20/D 1.335
Melting Point	0.0 °C
TSCA	Yes
Boiling Point	107°
Solubility	Soluble in water, alcohol and ether. Insoluble in petroleum
Vapor Pressure	23.3 mmHg ( 30 °C)
Vapor Density	1.1 (vs air)
Flash Point	107°C

别名和识别编码

Chemical Name	Hydrogen peroxide
CAS Number	7722-84-1
PubChem Substance ID	784
Beilstein Registry Number	3587191
MDL Number	MFCD00011333
EC Number	231-765-0
Merck Number	14,4798
Synonym	ALBO Perhydrol hydrogen peroxide 8 - 35% Wasserstoffperoxid 5 - 8% Wasserstoffperoxid 50 - 70% Wasserstoffsuperoxid 60%solution hydrogen peroxide 5 - 8% 过氧化氢; 二氧化氢; 二氧化二氢; 双氧水 Hydrogen peroxide 30% Bactident® Katalase Reagenz {Chemica Wasserstoffsuperoxid 3% T-Stuff 双氧水(30%) HYDROGEN PEROXIDE Albone 70 Albone DS 过氧化氢 Waterstofperoxyde 过氧化氢, 35% W/W 水溶液, 稳定 {uni_hambu Wasserstoffperoxid 50% H PERDROGEN PERHYDROL H₂O₂ (hydrogen peroxide) Hydrogen peroxide 过氧化氢30% HYDROGEN PEROX {uni_ham Dihydrogen Dioxide Oxyfull H2O2 Hioxy 氢过氧化物 SUPEROXOL Hybrite hyd {uni Oxydol HYDROGEN PEROXIDE SOLUTION Wasserstoffperoxid 3% 过氧化氢, Select Bleach hydr Albone 35 {uni_ha Hydrogen peroxide 35% PERHYDROL(R) {un BETZ 0241 过氧化氢( 二氧化氢 HYDROGEN PEROXIDE 30% HYDROGEN PEROXIDE 500ML Wasserstof {Che 二氧化氢(30%) Perone Hydrogen peroxide 27% PERONE Dihydrogen dioxide 二氧化二氢双氧水 Peroxide HYDROGENII PEROXIDUM Oxysept I Wasserstoffperoxid < 5% Wasserstoffsuperoxid < 5% Perossido di idrogeno Odosat D CATALASE TEST {Ch
Chemical Name Translation	双氧水(易制爆)(易涉毒)
Wiswesser Line Notation	H2 O2 90%
InChI	InChI=1S/H2O2/c1-2/h1-2H

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产品应用

氧化剂，漂白剂，点滴分析测定钙、钴、铜、锰、钛、钒、铵及铬酸银，有机合成。

安全信息

GHS Symbol

WGK Germany1

Hazard Codes Xn Xn,C,O

Hazard statements

H331 Toxic if inhaled 吸入中毒
H318 Causes serious eye damage 严重伤害眼睛
H302 Harmful if swallowed 吞食有害

Personal Protective Equipment Faceshields, Gloves, Goggles Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter

Precautionary statements

P220 Keep/Store away from clothing/…/combustible materials. 保持远离/贮存远离服装/....../可燃材料。
P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P305+P351+P338
P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P305+P351+P338+P310

Signal word Danger

RTECSMX0900000

UN Number 3149 UN 2014 5.1/PG 2 UN2014

Risk Statements

R8 Contact with combustible material may cause fire 遇到易燃物会导致起火
R22 Harmful if swallowed 吞咽有害
R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
R37/38 Irritating to respiratory system and skin 对呼吸系统和皮肤有刺激性
R20/22 Harmful by inhalation and if swallowed 吸入和不慎吞咽有害
R34 Causes burns 会导致灼伤

Safety Statements

S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S39 Wear eye/face protection 戴眼睛/面孔保护装置；
S17 Keep away from combustible material 远离可燃物料；
S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
S1/2 None 上锁保管并避免儿童触及；

Packing GroupII

Storage condition 用瓶口有微孔的塑料瓶装阴凉保存,久贮会分解为水和氧。储存温度2-8℃ 2-8°C

Hazard Class5.1

Restrict {} {} {} 易制爆危险化学品易制爆

Warnings 危化品目录(2015) 危险化学品

TYPE OF TEST            : TD - Toxic dose (other than lowest)
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 155 gm/kg/2Y-C
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Gastrointestinal - tumors
REFERENCE :
   HIUN** Department of Cancer Research, Research Institute for Nuclear
   Medicine and Biology, Hiroshima University.  (Kasumi 1-2-3, Hiroshima 734,
   Japan)

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 622 gm/kg/2Y-C
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Gastrointestinal - tumors
REFERENCE :
   HIUN** Department of Cancer Research, Research Institute for Nuclear
   Medicine and Biology, Hiroshima University.  (Kasumi 1-2-3, Hiroshima 734,
   Japan)

TYPE OF TEST            : TD - Toxic dose (other than lowest)
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 168 gm/kg/30W-C
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Gastrointestinal - tumors
REFERENCE :
   GANNA2 Gann.  Japanese Journal of Cancer Research.  (Tokyo, Japan)  V.1-75,
   1907-84.  For publisher information, see JJCREP.  Volume(issue)/page/year:
   75,17,1984

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 144 gm/kg/26W-C
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Gastrointestinal - tumors
REFERENCE :
   GANNA2 Gann.  Japanese Journal of Cancer Research.  (Tokyo, Japan)  V.1-75,
   1907-84.  For publisher information, see JJCREP.  Volume(issue)/page/year:
   75,17,1984

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 4060 mg/kg
TOXIC EFFECTS :
   Lungs, Thorax, or Respiration - pulmonary emboli
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1072 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 48(6),28,1983

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Human - child
DOSE/DURATION           : 12 mL/kg
TOXIC EFFECTS :
   Behavioral - sleep
   Lungs, Thorax, or Respiration - acute pulmonary edema
   Gastrointestinal - other changes
REFERENCE :
   AJFPD2 American Journal of Forensic Medicine and Pathology.  (Raven Press
   1185 Ave. of the Americas, New York, NY 10036) V.1-    1980-
   Volume(issue)/page/year: 15,44,1994

TYPE OF TEST            : LD50 - Lethal dose, 50 percen

TYPE OF TEST            : LC

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 880 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(iss

TYPE OF TEST            : Sister chromatid

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Escherichia coli
DOSE/DURATION           : 5 pph
REFERENCE :
   AGACBH Agents and Actions, A Swiss Journal of Pharmacology.  (Birkhaeuser
   Verlag, POB 133, CH-4010 Basel, Switzerland)  V.1-    1969/70-
   Volume(issue)/page/year: 4,286,1974

TYPE OF TEST            : Cytogenetic analysis
TEST SYSTEM             : Human Embryo
DOSE/DURATION           : 20 umol/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 172,245,1986

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Mold - Neurospora crassa
DOSE/DURATION           : 500 nnmol/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 374,169,1997

TYPE OF TEST            : Phage inhibition capacity
TEST SYSTEM             : Bacteria - Escherichia coli
DOSE/DURATION           : 500 ng/well
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 260,349,1991

TYPE OF TEST            : Mutation test systems - not otherwise specified
TEST SYSTEM             : Human Embryo
DOSE/DURATION           : 50 umol/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 172,245,1986

TYPE OF TEST            : DNA damage
TEST SYSTEM             : Rodent - hamster Lung
DOSE/DURATION           : 353 umol/L
REFERENCE :
   NATUAS Nature.  (Nature Subscription Dept., POB 1018, Manasguan, NJ 08736)
   V.1-    1869-  Volume(issue)/page/year: 282,318,1979

其他信息

类别:氧化剂
用途四:用于工业水处理作杀菌灭藻剂。亦可作漂白剂用于织物、纸浆的漂白。
含量分析:取试样1g(准确至0.1mg)，用水稀释至250.0ml。取此溶液25ml，加10ml稀硫酸试液(TS-241)后用0.1mol/L
可燃性危险特性:遇有机物、受热分解放出氧气; 遇铬酸、高锰酸钾、金属粉末反应剧烈
刺激数据:眼睛-兔 1 毫克重度
防护措施:经常接触多患皮炎及支气管和肺脏疾病。经口中毒时会出现腹痛、胸口痛、呼吸困难、呕吐、体温升高、结膜和皮肤出血，个别可能出现视力障碍、痉挛、轻瘫。美国通常规定最高容许浓度为1.4mg/m3。工作接
蒸气压:23.3 mm Hg ( 30 °C)
灭火剂:水
所属类别二:无机化工产品: 无机盐: Cr过氧化物
使用限量:GB 2760-86：生牛乳保鲜与硫氰酸钠配合使用，限量为0.03%过氧化氢2.0ml/L加硫氰酸钠15.0ml/L。限黑龙江、内蒙地区使用，扩大使用地区时须由所在省级卫生部门报请卫生部批准并按农业部有关实施规范执行。袋装豆腐干．0.86g/L(残留量不得检出)。 FDA，§184．1.366(2000)：制干酪用牛乳，0.05%；电解法乳清制造0.05%；淀粉防腐用0.15%；玉米糖浆还原S02用，0.15%；染色的干酪乳清还原用，0.05%；脂肪酸酯类乳化剂漂白用，1.25%。用后均应除去，不得残留。
下游产品:6-羟基吡啶-2-羧酸 --> 过硼酸钠 --> 2-羟基吡啶-N-氧化物 --> 硫酸镉 --> 乙酸镉 --> 聚合磷硫酸铁 --> 过氧化乙酸叔丁酯 --> 赤藓糖醇 --> 过氧化钙 --> 过氧化环己酮 --> 2,6-二氨基-3-溴吡啶 --> 过氧化二碳酸二(2-乙基己基)酯 --> 三油酸山梨酯 --> 2-溴-3-羟基-6-甲基吡啶 --> 三甲胺N-氧化物 --> D-阿拉伯糖 --> 二乙基羟胺 --> 乳化剂EL-90 --> 乳化剂 DPE-30,匀染剂 DPE --> 3-异丙基苯酚 --> 异喹啉-N-氧化物 --> 焦锑酸钠 --> 2,3-二甲基吡啶-N-氧化物 --> 2,6-二氨基-3-溴吡啶 --> 3,5-二溴对氨基苯磺酰胺 --
方法一:电解法(过硫酸铵法) 硫酸铵溶液经电解生成过硫酸铵，由阳极室流出，含量约为180～240g/L，经贮槽供水解用。在减压下，过硫酸铵溶液进入水解蒸馏器进行水解蒸馏。过氧化氢随蒸汽及酸雾蒸出，经分离器除去酸雾，再于蒸馏塔中精馏，从塔底得到过氧化氢(控制浓度27.5%)。 (NH4)2S2O8+2H2O→2NH4HSO4+H2O2 蒽醌法以氢化萜松醇和苯(体积比1：1)为溶剂的工作液，含有2-乙基蒽醌100~110g/L和四氢2-乙基蒽醌70~80g/L，由定量泵送入装有镍催化剂的反应釜。在压力0.2～0.3kPa和温度50~60℃下连续通氢气氢化控制氢化度50%。氢化液经过滤，于顶部进入氧化塔，在40～50℃下与氧气进行逆流氧化。氧化液用水进行逆流萃取，得浓度为27.5%～30%的过氧化氢水溶液，再用苯萃取净化的成品。
Acros Organics:过氧化氢/双氧水 Hydrogen peroxide, 50 wt% solution in water, stabilized, pure(7722-84-1)
外观性质:无色透明液体，有微弱的特殊气味。
所属类别三:食品添加剂: 防腐剂
用途三:过氧化氢具有氧化和还原作用，可用于袋装豆腐干的保鲜，用量为0.86g/kg，残留量不得检出；也可用于生牛乳保鲜，用量为每升生牛乳加0.3%2mL和硫氰酸钠15mg，仅限于黑龙江、内蒙古地区使用。
急性毒性:吸入-大鼠 LC50:2000 毫克/立方米/4小时;口服-小鼠 LD50:2000毫克/公斤
鉴别试验:溶解性可与水混溶(OT-42)。在10%试样液10ml中，加稀硫酸试液(TS-241)5ml和高锰酸钾试液(TS-193)1ml。应有气泡发生，且高锰酸钾的呈色消失。对石蕊呈酸性。
味苦，能