(3S,4R)-4-Acetoxy-3-[(R)-1-(tert-butyldimethylsilyloxy)ethyl]azetidin-2-one (3R,4R)-4-乙酰氧基-3-[(R)-叔丁基二甲硅氧基)乙基]-2-氮杂环丁酮

CAS 76855-69-1 MFCD00077636

化学结构图

76855-69-1
SMILES: CC(=O)O[C@H]1NC(=O)[C@H]1[C@@H](C)O[Si](C)(C)C(C)(C)C

化学属性

Mol. FormulaC13H25NO4Si
Mol. Weight287
Melting Point107-109
Density1.422

别名和识别编码

Chemical Name(3S,4R)-4-Acetoxy-3-[(R)-1-(tert-butyldimethylsilyloxy)ethyl]azetidin-2-one
MDL NumberMFCD00077636
PubChem Substance ID87562608
CAS Number76855-69-1
EC Number408-050-9
Reaxys-RN4690202
Beilstein Registry Number2384789
Synonym [3R(1′R,4R)]-(+)-4-乙酰氧基-3-[1-(叔丁基二甲基硅氧基)乙基]-2-氮杂环丁酮
Chemical Name Translation(3R,4R)-4-乙酰氧基-3-[(R)-叔丁基二甲硅氧基)乙基]-2-氮杂环丁酮
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分类

  • Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Lactams, Organic Building Blocks
  • {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Lactams, Organic Building Blocks

相关文献及参考

  • FT-NMR 1 (3), 694:B / RegBook 1 (2), 2989:I / Structure Index 1 , 473:E:6

安全信息

WGK Germany2
GHS Symbol
Precautionary statements
  • P305+P351+P338+P337+P313
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P305+P351+P338
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P302+P352+P333+P313+P362+P364
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P333+P313
  • P302+P350
  • P337+P313
  • P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
Signal word
Hazard statements
  • H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H319 Causes serious eye irritation 严重刺激眼睛
Hazard Codes
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Faceshields, Gloves
UN Number
Safety Statements
Risk Statements
Packing GroupIII
Hazard Class9

系列性分类


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