2-Methyl-1,3-cyclopentanedione 2-甲基-1,3-环戊二酮

CAS 765-69-5 MFCD00001406

化学结构图

765-69-5
SMILES: CC1C(=O)CCC1=O

化学属性

Mol. FormulaC6H8O2
Mol. Weight112.13
Melting Point212-215°C
TSCANo
Appearance 白色结晶体。
Boiling Point218°C at 760 mmHg

别名和识别编码

Chemical Name2-Methylcyclopentane-1,3-dione
CAS Number765-69-5
Alfabeta NameMETHYLCYCLOPENTANEDIONE 213---,
MDL NumberMFCD00001406
EC Number212-153-2
Beilstein Registry Number1237255
PubChem Substance ID13005
Synonym 2-Methylcyclopentane-1,3-dione {LY} 2-Methylcyclopentane-1,3-dione {} {LY} 2-Methylcyclopentane-1,3-dione {} {} {LY} 2-Methylcyclopentane-1,3-dione {} {} {} {LY} 2-Methylcyclopentane-1,3-dione {} {} {} {} {LY} 2-Methylcyclopentane-1,3-dione {} {} {} {} {} {LY} 2-Methylcyclopentane-1,3-dione {} {} {} {} {} {} {LY} 2-Methylcyclopentane-1,3-dione {} {} {} {} {} {} {} {LY} 2-Methylcyclopentane-1,3-dione {} {} {} {} {} {} {} {} {LY} 2-Methylcyclopentane-1,3-dione {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Methylcyclopentane-1,3-dione {} {} {} {} {} {} {} {} {} {} {LY} 2-Methylcyclopentane-1,3-dione {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Methylcyclopentane-1,3-dione {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Methylcyclopentane-1,3-dione {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Methylcyclopentane-1,3-dione {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Methylcyclopentane-
Chemical Name Translation2-甲基-1,3-环戊二酮
Reaxys-RN1237255
InChIKeyHXZILEQYFQYQCE-UHFFFAOYSA-N
LabNetwork Molecule IDLN00222075
InChIInChI=1S/C6H8O2/c1-4-5(7)2-3-6(4)8/h4H,2-3H2,1H3
Canonical SMILESCC1C(CCC1=O)=O
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分类

  • {SNA} Bioactive Small Molecules, Building Blocks, C3 to C6, Carbonyl Compounds, Cell Biology, Chemical Synthesis, Ketones, M, Organic Building Blocks
  • {SNA} Building Blocks, C3 to C6, Carbonyl Compounds, Chemical Synthesis, Ketones, Organic Building Blocks
  • {SNA} Bioactive Small Molecules, Building Blocks, C3 to C6, Carbonyl Compounds, Chemical Synthesis, Ketones, M, Organic Building Blocks, 细胞生物学

相关文献及参考

  • Valuable intermediate for steroid synthesis. For a review, see: Synthesis, 477 (1989). Condensation with methyl vinyl ketone and proline-catalyzed asymmetric aldol cyclization of the product gives a diketone useful in steroid and prostaglandin synthesis: Org. Synth. Coll., 7, 363 (1990):

安全信息

Warnings IRRITANT
WGK Germany3
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Hazard Codes Xi
Safety Statements
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触;
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛,皮肤或衣服。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312
  • P301+P317
  • P302+P352
  • P304+P312
  • P304+P340
  • P305+P351+P338
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P317
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P362+P364
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H320 Causes eye irritation 刺激眼睛
  • H332 Harmful if inhaled 吸入有害
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H402 Harmfultoaquaticlife 对水生生物有害。
  • H412 Harmfutoaquaticlifewithlonglastingeffects 对水生生物有害并具有长期影响。
Storage condition 2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

  • 海关编码:29142900
  • 用途一:用作医药中间体
  • Alfa Aesar:2-甲基环戊烷-1,3-二酮,98% 2-Methylcyclopentane-1,3-dione, 98%(765-69-5)
  • 图谱信息:2-甲基-1,3-环戊二酮(765-69-5)红外图谱(IR2) 2-甲基-1,3-环戊二酮(765-69-5)质谱(MS) 2-甲基-1,3-环戊二酮(765-69-5)核磁图( 13 CNMR) 2-甲基-1,3-环戊二酮(765-69-5)Raman光谱 2-甲基-1,3-环戊二酮(765-69-5)核磁图( 1 HNMR) 2-甲基-1,3-环戊二酮(765-69-5)红外图谱(IR1)
  • Acros Organics:2-甲基-1,3-环戊二酮 2-Methyl-1,3-cyclopentanedione, 98%(765-69-5)
  • 2-甲基-1,3-环戊二酮价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 M0901 2-甲基-1,3-环戊二酮 2-Methyl-1,3-cyclopentanedione 5G 467元 2014/06/02 M0901 2-甲基-1,3-环戊二酮 2-Methyl-1,3-cyclopentanedione 25G 1260元 2010/06/21 152320250 2-甲基-1,3-环戊二酮 2-Methyl-1,3-cyclopentanedione 98% 25 GR 1472元
  • Hazard Note:Irritant
  • MOL 文件:765-69-5.mol
  • Sigma Aldrich:765-69-5(sigmaaldrich)
  • TCI Shanghai:2-甲基-1,3-环戊二酮 2-Methyl-1,3-cyclopentanedione,>;97.0%(GC)(765-69-5)
  • MSDS 信息:2-Methylcyclopentane-1,3-dione(765-69-5).msds

系列性分类


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