(+)-Chloroformyloxy-p-Menthane (+)-氯甲酸薄荷酯

CAS 7635-54-3 MFCD00134483

化学结构图

7635-54-3
SMILES: CC(C)[C@H]1CC[C@H](C)C[C@@H]1OC(=O)Cl

化学属性

Mol. FormulaC11H19ClO2
Mol. Weight218.72 g/mol
Refractive index1.4580 to 1.4600
Boiling Point108-109 °C/11 mmHg(lit.)
Density1.031 g/mL at 25 °C(lit.)
Flash Point70°C(lit.)
Stability对湿度敏感

别名和识别编码

Chemical Name(+)-Chloroformyloxy-p-Menthane
CAS Number7635-54-3
PubChem Substance ID87573180
Beilstein Registry Number2414685
MDL NumberMFCD00134483
Reaxys-RN2414685
Synonym (+)-(1S)-MENTHYL CHLOROFORMATE (+)-CHLOROFORMYLOXY-P-MENTHANE (+)-MENTHYL CHLOROFORMATE (+)-MENTHYL CHLOROFORMATE (97% EE/GLC) (+)-MENTHYL CHLOROFORMATE 97% (+)-Menthyl Chloroformate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
Chemical Name Translation(+)-氯甲酸薄荷酯
LabNetwork Molecule IDLN01743139
InChIInChI=1S/C11H19ClO2/c1-7(2)9-5-4-8(3)6-10(9)14-11(12)13/h7-10H,4-6H2,1-3H3/t8-,9+,10-/m0/s1
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分类

  • {SNA} Acid Halides, Analytical Reagents, Analytical/Chromatography, Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Chiral Resolution Reagents, Chiral Resolving Reagents, Derivatization Reagents, Derivatization Reagents HPLC, Organic Building Blocks, UV-VIS
  • {SNA} Acid Halides, Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Chiral Resolution Reagents, Chiral Resolving Reagents, Derivatization Reagents, Derivatization Reagents HPLC, Organic Building Blocks, UV-VIS, 分析/色谱, 分析试剂
  • Acid Halides, Analytical Rea

相关文献及参考

  • 1. Tetrahedron Lett. 26 , 5433, (1985)
  • FT-NMR 1 (1), 1207:A / RegBook 1 (1), 863:E / Structure Index 1 , 132:B:8

安全信息

GHS Symbol
WGK Germany3
Hazard Codes T,C T
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H331 Toxic if inhaled 吸入中毒
  • H227 Combustible liquid 可燃液体
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P304+P340+P310
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P303+
  • P234 Keep only in original container. 只保留在原来的容器中。
  • P403+P233
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P301+P330+P331+P310
  • P303+P361+P353
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
  • P370+P378
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P305+P351+P338
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P390 Absorb spillage to prevent material damage. 吸收溢出物,防止重大损害。
  • P361 Remove/Take off immediately all contaminated clothing. 立即去除/脱掉所有被污染的衣服。
Signal word Danger {} {} {} {} {} {} {TCI}
UN Number 3277 UN 3277 6.1/PG 2
Risk Statements
  • R34 Causes burns 会导致灼伤
  • R23 Toxic by inhalation 吸入有毒
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
Safety Statements
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S25 Avoid contact with eyes 避免眼睛接触;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
Packing GroupII
Hazard Class6.1/8
Storage condition 储存温度 2-8°C 2-8°C

其他信息

  • MOL 文件:7635-54-3.mol
  • TCI Shanghai:(+)-氯甲酸薄荷酯 (+)-Menthyl Chloroformate,>;97.0%(T)(7635-54-3)
  • Sigma Aldrich:7635-54-3(sigmaaldrich)
  • 氯甲酸薄荷酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 M1221 氯甲酸(+)-薄荷酯 (+)-Menthyl Chloroformate 5ML 615元 2014/06/02 M1221 氯甲酸(+)-薄荷酯 (+)-Menthyl Chloroformate 25ML 1950元 2010/06/21 314510250 氯甲酸薄荷酯 (+)-Menthyl chloroformate 97% 25 ML 2106元
  • F:10-19-21
  • 下游产品:异丙威 --> 禾草敌 --> 头孢替安 --> 碳酸丙烯酯 --> 仲丁威 --> 灭除威 --> 1-乙氧羰基吡咯烷-3-酮
  • Acros Organics:氯甲酸薄荷酯 (+)-Menthyl chloroformate, 97%(7635-54-3)

系列性分类


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