CAS 759-94-4 MFCD00053780-S-Ethyl dipropylthiocarbamate 苯基硫代氨基甲酸乙酯/丙草丹 TAO{mole}

S-Ethyl dipropylthiocarbamate 苯基硫代氨基甲酸乙酯/丙草丹

CAS 759-94-4 MFCD00053780

化学结构图

SMILES: CCCN(CCC)C(=O)SCC

化学属性

Mol. Formula	C9H19NOS
Mol. Weight	189.32
Boiling Point	127 °C at 20 mmHg
Density	0.7915
Solubility	0.375 G/100 ML
Flash Point	116°C
Melting Point	25 °C

别名和识别编码

Chemical Name	EPTC
Synonym	S-Ethyl dipropylthiocarbamate {LY} S-Ethyl dipropylthiocarbamate S-ethyl dipropylthiocarbamate {} {LY} S-Ethyl dipropylthiocarbamate {} {} {LY} S-Ethyl dipropylthiocarbamate {} {} {} {LY} S-Ethyl dipropylthiocarbamate {} {} {} {} {LY} S-Ethyl dipropylthiocarbamate {} {} {} {} {} {LY} S-Ethyl dipropylthiocarbamate {} {} {} {} {} {} {LY} S-Ethyl dipropylthiocarbamate {} {} {} {} {} {} {} {LY} S-Ethyl dipropylthiocarbamate {} {} {} {} {} {} {} {} {LY} S-Ethyl dipropylthiocarbamate {} {} {} {} {} {} {} {} {} {LY} S-Ethyl dipropylthiocarbamate {} {} {} {} {} {} {} {} {} {} {LY} S-Ethyl dipropylthiocarbamate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} S-Ethyl dipropylthiocarbamate {} {} {} {} {} {} {} {} {} {} {} {} {LY} S-Ethyl dipropylthiocarbamate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} S-Ethyl dipropylthiocarbamate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} S-Ethyl dipropylthiocar
MDL Number	MFCD00053780
PubChem Substance ID	12968
Beilstein Registry Number	1762751
CAS Number	759-94-4
EC Number	212-073-8
Chemical Name Translation	苯基硫代氨基甲酸乙酯/丙草丹
Merck Number	13,3669
Wiswesser Line Notation	3N3&VS2
InChI	InChI=1S/C9H19NOS/c1-4-7-10(8-5-2)9(11)12-6-3/h4-8H2,1-3H3
Canonical SMILES	CCSC(N(CCC)CCC)=O

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安全信息

RTECSFA4550000

GHS Symbol

WGK Germany1

Hazard statements

H302 Harmful if swallowed 吞食有害

Hazard Codes Xn

Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter

Signal word Warning

Safety Statements

S2 Keep out of the reach of children 避免儿童触及；
S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；

Risk Statements

R22 Harmful if swallowed 吞咽有害

Storage condition 0-6°C 室温储存

UN Number 2902

TYPE OF TEST            : TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Human
DOSE/DURATION           : 135 mg/m3/90M
TOXIC EFFECTS :
   Behavioral - headache
   Behavioral - withdrawal
   Gastrointestinal - nausea or vomiting
REFERENCE :
   HYSAAV Hygiene and Sanitation (USSR).  English translation of GISAAA.
   (Springfield, VA)  1964-71. Discontinued.  Volume(issue)/page/year:
   36(1-3),196,1971

TYPE OF TEST            : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 200 mg/m3/4H
TOXIC EFFECTS :
   Sense Organs and Special Senses (Eye) - lacrimation
   Behavioral - somnolence (general depressed activity)
   Gastrointestinal - changes in structure or function of salivary glands
REFERENCE :
   HYSAAV Hygiene and Sanitation (USSR).  English translation of GISAAA.
   (Springfield, VA)  1964-71. Discontinued.  Volume(issue)/page/year:
   36(1-3),196,1971

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 320 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems
   Laboratory, NIOSH Exchange Chemicals.  (Aberdeen Proving Ground, MD 21010)
   Volume(issue)/page/year: NX#03907

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 58 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JAFCAU Journal of Agricultural and Food Chemistry.  (American Chemical Soc.,
   Distribution Office Dept. 223, POB 57136, West End

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Escherichia coli
DOSE/DURATION           : 5 mg/L
REFERENCE :
   GNKAA5 Genetika (Moscow).  For English translation, see SOGEBZ.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  No.1-    1965-
   Volume(issue)/page/year: 22,2416,1986

Precautionary statements

P201 Obtain special instructions before use. 使用前获取专门指示。
P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
P203
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P281 Use personal protective equipment as required. 使用所需的个人防护装备。
P301+P312
P301+P317
P308+P313
P318
P330 Rinse mouth. 漱口
P405 Store locked up. 上锁保管。
P501 Dispose of contents/container to..… 处理内容物/容器.....

其他信息

稳定性:Stable. Incompatible with strong oxidizing agents.
生产方法:光气与二丙胺作用生成二丙基氨基甲酰氯，再与乙硫醇反应生成茵草敌。也可在NaOH存在下，采用二丙胺与乙硫基甲酰氯反应制得茵草敌，或采用二丙胺与硫酸二乙酯和COS作用制得。
用途:选择性芽前土壤处理剂。经根或幼茎吸收、传导而起作用。作用机制为抑制核酸代谢和蛋白质合成。主要用于玉米、棉花、苜蓿、菜豆、豌豆、亚麻、马铃薯、甜菜、向日葵、柑橘、菠萝、草莓、葡萄及观赏植物，防除阿拉伯高梁、匐匍冰草、稗、野燕麦、莎草、狗尾草等一年生杂草及马齿苋、藜、繁缕等部分阔叶杂草，推荐用药量10～30g/100m 2 。为防药剂挥发损失，可利用机械将药拌入土内，并进行灌溉。
杀虫剂单一组分标准液
RTECS号:FA4550000
NIST化学物质信息:Carbamothioic acid, dipropyl-, s-ethyl ester(759-94-4)
MOL 文件:759-94-4.mol
EPA化学物质信息:Carbamothioic acid, dipropyl-, S-ethyl ester(759-94-4)
外观性质:透明液体,有香味。
PackingGroup:III
HazardClass:6.1(b)
毒害物质数据:759-94-4(Hazardous Substances Data)