(1E,3Z)-1-Methoxy-2-methyl-3-(trimethylsilyloxy)-1,3-pentadiene (1E,3Z)-1-甲氧基-2-甲基-3-(三甲基硅氧基)-1,3-戊二烯

CAS 72486-93-2 MFCD10567404

化学结构图

72486-93-2
SMILES: C/C(=C\OC)/C(=C/C)/O[Si](C)(C)C

化学属性

Mol. FormulaC10H20O2Si
Mol. Weight200.35
Density0.899 g/mL at 25 °C(lit.)
Boiling Point65 °C/6 mmHg(lit.)
Refractive indexn20/D 1.4650(lit.)

别名和识别编码

Chemical Name(1E,3Z)-1-Methoxy-2-methyl-3-(trimethylsilyloxy)-1,3-pentadiene
Synonym (1E,3Z)-1-甲氧基-2-甲基-3-(三甲基硅氧基)-1,3-戊二烯 (1E,3Z)-1-甲氧基-2-甲基-3-[(三甲基硅烷基)氧]-戊-1,3-二烯 [(1-(2-甲氧基-1-甲基乙烯基)烯丙氧基]三甲基硅烷 (1E,3Z)-1-甲氧基-2-甲基-3-[(三甲基硅烷基)氧]-戊-1,3-二烯 [(1-(2-甲氧基-1-甲基乙烯基)烯丙氧基]三甲基硅烷
MDL NumberMFCD10567404
PubChem Substance ID24882659
CAS Number72486-93-2
Chemical Name Translation(1E,3Z)-1-甲氧基-2-甲基-3-(三甲基硅氧基)-1,3-戊二烯
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分类

  • {SNA} Building Blocks, Chemical Synthesis, Enol Ethers, Organic Building Blocks, Oxygen Compounds

相关文献及参考

  • 1. Yu, Z.; et al., An N,N'-dioxide/In(OTf)3 catalyst for the asymmetric hetero-Diels-Alder reaction between Danishefsky's dienes and aldehydes: application in the total synthesis of triketide Angew. Chem. Int. Ed. Engl. 47 , 1308-1311, (2008)
  • 2. Oskarsson, T.; et al., Diverted Total Synthesis Leads to the Generation of Promising Cell-Migration Inhibitors for Treatment of Tumor Metastasis: In vivo and Mechanistic Studies on the Migrastatin Core Ether Analog J. Am. Chem. Soc. 132 , 3224-3228, (2010)
  • 3. Massa, A.; et al., A new approach to di- and tetrasubstituted 2,3-dihydropyridin-4(1H)-ones through aza-Diels-Alder reaction promoted by silicon tetrachloride Synthesis , 643-649, (2009)
  • 4. Andreassen, T.; et al., The use of two optically active N-sulfinyl α-imino esters in the stereoselective aza-Diels-Alder reaction Tetrahedron 65 , 2806-2817, (2009)

安全信息

WGK Germany3
Signal word Warning
Hazard statements
  • H302 Harmful if swallowed 吞食有害
Hazard Codes Xn
GHS Symbol
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Risk Statements
  • R22 Harmful if swallowed 吞咽有害

系列性分类


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