6-Nitropiperonal 6-硝基胡椒醛

CAS 712-97-0 MFCD00005829

化学结构图

712-97-0
SMILES: O=Cc1cc2c(cc1[N+](=O)[O-])OCO2

化学属性

Mol. FormulaC8H5NO5
Mol. Weight195
Melting Point93-94
TSCANo
Appearance 黄色针状结晶。熔点98.5℃。

别名和识别编码

Chemical Name6-Nitropiperonal
CAS Number712-97-0
Synonym 6-Nitro-1,3-benzodioxole-5-carboxaldehyde {uni_hamburg} 3,4-(Methylendioxy)-6-nitrobenzaldehyd 3,4-(Methylenedioxy)-6-nitrobenzaldehyde Piperonal, 6-nitro- 6-Nitropiperonal 6-nitro-piperona 6-硝基胡椒醛 6-硝基-3,4-亚甲基二氧基苯甲醛 4,5-METHYLENEDIOXY-2-NITROBENZALDEHYDE 6-nitropiperonal 6-nitro-benzo(1,3)dioxole-5-carbaldehyde 4,5-(Methylenedioxy)-2-nitrobenzaldehyde AKOS BBS-00006440 4,5-Methylenedioxy-2-nitrobenzaldehyde~6-Nitro-1,3-benzodioxole-5-carboxaldehyde 6-Nitropiperonal, 98+% 2-NITRO-4,5-METHYLENEDIOXYBENZALDEHYDE 1,3-Benzodioxole, 5-formyl-6-nitro- 1,3-Benzodioxole-5-carboxaldehyde, 6-nitro- 6-Nitropiper
MDL NumberMFCD00005829
PubChem Substance ID87573860
EC Number211-926-1
Reaxys-RN384010
Beilstein Registry Number384010
Alfabeta NameNITROBENZODIOXOLECARBALDEHYDE 6135-----,
Chemical Name Translation6-硝基胡椒醛
InChIKeyNRZWECORTTWSEF-UHFFFAOYSA-N
Wiswesser Line NotationT56 BO DO CHJ GVH HNW
LabNetwork Molecule IDLN00181598
信息真实价格透明    资金保障    专业采购外包团队在线服务   
信息真实价格透明    资金保障    专业采购外包团队在线服务   
品牌质保精细包装    现货库存    一流品牌服务   

分类

  • Aldehydes, Building Blocks, C8, Carbonyl Compounds, Chemical Synthesis, Organic Building Blocks
  • {uni_hamburg} no charge; oxygen heterocycle; carbocycle; aromatic; alicycle; large ring; fused rings; 5ring; 6ring; 9ring; aldehyde; 1fragment
  • {SNA} Aldehydes, Building Blocks, C8, Carbonyl Compounds, Chemical Synthesis, Organic Building Blocks

相关文献及参考

  • Kajihara, Y., et al.: Carb. Res., 331, 455 (2001)
  • Beil. 19 ,125
  • FT-IR 2 (2), 2557:B / FT-IR 1 (2), 128:D / FT-NMR 1 (2), 969:B / IR-Spectra (2), 809:H / IR-Spectra (3), 924:F / NMR-Reference 2 (2), 127:A / RegBook 1 (2), 1731:M / Structure Index 1 , 276:A:3
  • Short: III/35D2 Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts for Carbon-13, Part 2: Aromatic Compounds Author: Mikhova, B. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35D2 Year: 2005 Keyword: aromatic compounds; carbon-13; chemical shift; coupling constant; molecular structure ISBN: 978-3-540-20189-2 ISBN: 3-540-20189-0 Internet Resource: DOI:10.1007/b83345 RefComment: VIII, 291 p., Hardcover RefComment: Written for Science and engineers in the fields of physics, chemistry and physical chemistry who inted to use NMR to study the structure and the binding of molecules Abstract: Nuclear Magnetic Resonance (NMR) is based on the fact that certain nuclei exhibit a magnetic moment, orient by a magnetic field, and absorb characteristic frequencies in the radiofrequency part of the spectrum. The spectral lines of the nuclei are highly influenced by the chemical environment i.e. the structure and interaction of the molecules. NMR is now the leading technique and a powerful tool for the investigation of the structure and interaction of molecules. The present Landolt-Börnstein volume III/35 Nuclear Magnetic Resonance (NMR) Data is therefore of major interest to all scientists and engineers who intend to use NMR to study the structure and the binding of molecules. Volume III/35 "NMR-Data" is divided into several subvolumes and parts. Subvolume III/35A contains the nuclei 11B and 31P, subvolume III/35B contains the nuclei 19F and 15N, subvolume III/35C contains the nucleus 1H, subvolume III/35D contains the nucleus 13C, subvolume III/35E contains the nucleus 17O, and subvolum

安全信息

WGK Germany3
RTECSDF4912750
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S37 Wear suitable gloves 戴适当手套;
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition Air & Light Sensitive
Warnings IRRITANT
Hazard Codes Xi
Signal word
GHS Symbol
Precautionary statements
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 56 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems
   Laboratory, NIOSH Exchange Chemicals.  (Aberdeen Proving Ground, MD 21010)
   Volume(issue)/page/year: NX#04490

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 100 ug/plate
REFERENCE :
   JAFCAU Journal of Agricultural and Food Chemistry.  (American Chemical Soc.,
   Distribution Office Dept. 223, POB 57136, West End Stn., Washington, DC
   20037)  V.1-    1953-  Volume(issue)/page/year: 40,2211,1992

其他信息

  • Acros Organics:6-硝基胡椒醛 6-Nitropiperonal, 98+%(712-97-0)
  • 方法一:在冷却下将60ml发烟硝酸和40ml冰乙酸配成混酸,在5℃以下将25g胡椒醛分次加入混酸中,搅拌反应6h。反应液倾入水中析出沉淀。过滤,洗涤,干燥,用乙醇重结晶,得24g6-硝基胡椒醛,收率74%。
  • 上游原料:乙酸 --> 硝酸 --> 胡椒醛
  • 用途一:有机合成中间体。
  • 敏感性:Air & Light Sensitive
  • MOL 文件:712-97-0.mol
  • Sigma Aldrich:712-97-0(sigmaaldrich)
  • TCI Shanghai:6-硝基胡椒醛 6-Nitropiperonal,>;97.0%(GC)(712-97-0)
  • 图谱信息:6-硝基胡椒醛(712-97-0)核磁图( 13 CNMR) 6-硝基胡椒醛(712-97-0)红外图谱(IR2) 6-硝基胡椒醛(712-97-0)核磁图( 1 HNMR) 6-硝基胡椒醛(712-97-0)红外图谱(IR1) 6-硝基胡椒醛(712-97-0)质谱(MS)
  • 6-硝基胡椒醛价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 N0537 6-硝基胡椒醛 6-Nitropiperonal 25G 873元 2010/06/21 160075000 6-硝基胡椒醛 6-Nitropiperonal 98+% 500 GR 12917元 2010/06/21 160070050 6-硝基胡椒醛 6-Nitropiperonal 98+% 5 GR 365元
  • Alfa Aesar:6-硝基-3,4-亚甲基二氧苯甲醛,98+% 6-Nitropiperonal, 98+%(712-97-0)

系列性分类


相关产品推荐