四乙基溴化铵 四乙基溴化铵
CAS 71-91-0 MFCD00011825
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分类
- Acidic Ion Pair Reagents (Anionic), Analytical Reagents, Analytical/Chromatography, Buffers & Reagents, Chromatography Reagents & Solvents, HPLC, Ion Pair Reagents, Ion Pair Reagents - Anionic
- {SNA} Ammonium Salts, Chemical Synthesis, Phase Transfer Catalysts, Synthetic Reagents
- {uni_hamburg} no charge; 2fragments; ionic
- {SNA} Acidic Ion Pair Reagents (Anionic), Buffers & Reagents, Chromatography Reagents & Solvents, HPLC, Ion Pair Reagents, Ion Pair Reagents - Anionic, 分析/色谱, 分析试剂
- {SNA} Ammonium Salts, Analytical Reagents, Analytical/Chromatography, Chemical Synthesis, Electrochemistry,
产品应用
- 离子对色谱用。检验金、铱、钯、铑和钌。极谱分析。
相关文献及参考
- Merck: 14,9199 Beilstein:4,104
- Merck: 14,9199
- Short: III/31a
- Short: II/27B
- Phase-transfer catalyst; see Appendix 2.
- For use in combination with anhydrous HBr as a reagent for selective monohydrobromination of an alkyne, see: Org. Synth., 76, 263 (1998).
安全信息
GHS Symbol
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- H302+H312+H332
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P302+P352+P312+P362+P364
- P304+P340+P312
- P305+P351+P338
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
- S36 Wear suitable protective clothing 穿戴适当的防护服;
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
- S37 Wear suitable gloves 戴适当手套;
- S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : >2 gm/kg TOXIC EFFECTS : Lungs, Thorax, or Respiration - other changes REFERENCE : JPETAB Journal of Pharmacology and Experimental Therapeutics. (Williams & Wilkins Co., 428 E. Preston St., Baltimore, MD 21202) V.1- 1909/10- Volume(issue)/page/year: 97,48,1949
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intravenous SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 63 mg/kg TOXIC EFFECTS : Lungs, Thorax, or Respiration - other changes REFERENCE : JPETAB Journal of Pharmacology and Experimental Therapeutics. (Williams & Wilkins Co., 428 E. Preston St., Baltimore, MD 21202) V.1- 1909/10- Volume(issue)/page/year: 97,48,1949
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Subcutaneous SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 200 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : PSEBAA Proceedings of the Society for Experimental Biology and Medicine. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1903/04- Volume(issue)/page/year: 78,708,1951
TYPE OF TEST : LD50 - Lethal dose, 5
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intravenous SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 14200 ug/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : JOPHAN Journal de Physiologie (Paris). (SPPIF, B.P.22, F-41353 Vineuil, France) V.39- 1946- Volume(issue)/page/year: 49,220,1957
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUT
其他信息
- Alfa Aesar:四乙基溴化铵,98% Tetraethylammonium bromide, 98%(71-91-0)
- TCI Shanghai:四乙基溴化铵 Tetraethylammonium Bromide,>;98.0%(T)(71-91-0)
- MOL 文件:71-91-0.mol
- 用途一:用作极谱分析试剂和农药中间体
- F:3
- 海关编码:29239000
- 检测方法:T,NMR
- 图谱信息:四乙基溴化铵(71-91-0)质谱(MS) 四乙基溴化铵(71-91-0)红外图谱(IR2) 四乙基溴化铵(71-91-0)Raman光谱 四乙基溴化铵(71-91-0)红外图谱(IR1)
- 用途二:离子对色谱用。检验金、铱、钯、铑和钌。极谱分析。
- 上游原料:三乙胺 --> 溶剂
- 易吸湿。易溶于水、乙醇、氯仿和丙酮,微溶于苯,水中溶解度:2795 g/L (25°C)。10%水溶液的pH为6.5,热至95℃达28小时而pH不变。有刺激性。
- 敏感性:Hygroscopic
- Acros Organics:四乙基溴化铵 Tetraethylammonium bromide, 99+%(71-91-0)
- 四乙基溴化铵价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 30175014 四乙基溴化铵;溴化四乙铵 25g 26元 2011/04/16 T0094 四乙基溴化铵 Tetraethylammonium Bromide 25G 134元 2011/04/16 T0094 四乙基溴化铵 Tetraethylammonium Bromide 500G 831元
- 下游产品:四乙基四氟硼酸铵
- Sigma Aldrich:71-91-0(sigmaaldrich)
- 外观性质:白色结晶。易吸湿。易溶于水、乙醇、氯仿和丙酮,微溶于苯,水中溶解度:2795 g/L (25°C)。10%水溶液的pH为6.5,热至95℃达28小时而pH不变。有刺激性。密度:1.397熔点:285°C
- MSDS 信息:Tetraethylammonium bromide(71-91-0).msds