2-Phenoxyacetyl chloride 苯氧乙酰氯
CAS 701-99-5 MFCD00000726
化学结构图
SMILES: O=C(Cl)COc1ccccc1
化学属性
| Mol. Formula | C8H7ClO2 |
|---|---|
| Mol. Weight | 171 |
| Density | 1.235 |
| Refractive index | 1.5320 to 1.5390 |
| Flash Point | 108°C(lit.) |
| TSCA | Yes |
| Boiling Point | 225-226 |
别名和识别编码
| Chemical Name | 2-Phenoxyacetyl chloride |
|---|---|
| CAS Number | 701-99-5 |
| EC Number | 211-862-4 |
| Beilstein Registry Number | 607585 |
| MDL Number | MFCD00000726 |
| PubChem Substance ID | 87574369 |
| Synonym | Acetylchloride,phenoxy- 苯氧基乙酰氯 苯氧乙酰氯 PHENOXYACETYL CHLORIDE Acyl chloride kind Phenyloxyacetyl chloride phenoxy-acetylchlorid LABOTEST-BB LT00643586 AKOS BBS-00003927 Phenoxyacetic acid chloride |
| Reaxys-RN | 607585 |
| Chemical Name Translation | 苯氧乙酰氯 |
| InChIKey | PKUPAJQAJXVUEK-UHFFFAOYSA-N |
| LabNetwork Molecule ID | LN00192054 |
| InChI | InChI=1S/C8H7ClO2/c9-8(10)6-11-7-4-2-1-3-5-7/h1-5H,6H2 |
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分类
- {SNA} Acid Halides, Building Blocks, Carbonyl Compounds, Chemical Synthesis, Organic Building Blocks
相关文献及参考
- Can be used to protect OH groups. The phenoxyacetate group is 50x more labile to aqueous ammonia than acetate: Tetrahedron Lett., 4273 (1968). It can also be cleaved with methanolic t-BuNH 2 : Chem. Lett., 965 (1982).
安全信息
GHS Symbol
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- S8 Keep container dry 保持容器干燥；
- R14 Reacts violently with water 遇水会猛烈反应
- R34 Causes burns 会导致灼伤
- R36/37 Irritating to eyes and respiratory system 对眼睛和呼吸系统有刺激性
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- P234 Keep only in original container. 只保留在原来的容器中。
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P301+P330+P331
- P301+P330+P331+P310
- P303+P361+P353+P310+P363
- P304+P340+P310
- P305+P351+P338
- P305+P351+P338+P310
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- P390 Absorb spillage to prevent material damage. 吸收溢出物，防止重大损害。
- P405 Store locked up. 上锁保管。
- P406 Store in corrosive resistant/… container with a resistant inner liner. 存放在耐腐蚀/具有耐性的内衬容器。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- H290 May be corrosive to metals 可能腐蚀金属。
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
- H335 May cause respiratory irritation 可能导致呼吸道刺激
其他信息
- Sigma Aldrich:701-99-5(sigmaaldrich)
- 图谱信息:苯氧乙酰氯(701-99-5)质谱(MS) 苯氧乙酰氯(701-99-5)核磁图( 13 CNMR) 苯氧乙酰氯(701-99-5)核磁图( 1 HNMR) 苯氧乙酰氯(701-99-5)红外图谱(IR1)
- 海关编码:29189090
- TCI Shanghai:苯氧基乙酰氯 Phenoxyacetyl Chloride,>;98.0%(GC)(T)(701-99-5)
- Alfa Aesar:苯氧乙酰氯,98% Phenoxyacetyl chloride, 98%(701-99-5)
- F:10-19
- MOL 文件:701-99-5.mol
- Acros Organics:苯氧基乙酰氯 Phenoxyacetyl chloride, 98%(701-99-5)
- 苯氧乙酰氯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 P0113 苯氧基乙酰氯 Phenoxyacetyl Chloride 25G 248元 2014/06/02 P0113 苯氧基乙酰氯 Phenoxyacetyl Chloride 500G 2020元 2010/06/21 169940500 苯氧乙酰氯 Phenoxyacetyl chloride 98% 50 GR 648元
- MSDS 信息:Phenoxyacetyl chloride(701-99-5).msds
- 敏感性:Moisture Sensitive
