N-Boc-L-Prolinal N-Boc-L-脯氨醛

CAS 69610-41-9 MFCD00274186

化学结构图

69610-41-9
SMILES: CC(C)(C)OC(=O)N1CCC[C@@H]1C=O

化学属性

Mol. FormulaC10H17NO3
Mol. Weight199
Refractive indexn20/D 1.462(lit.)
Boiling Point211
Density1.063
Flash Point>110°(230°F)
TSCANo
Stability对空气敏感

别名和识别编码

Chemical NameN-Boc-L-Prolinal
CAS Number69610-41-9
Alfabeta NameBUTYLFORMYLPYRROLIDINECARBOXYLATE TERTS21()-----
MDL NumberMFCD00274186
Synonym (S)-2-甲醛基吡咯烷-1-甲酸叔丁酯 N-(tert-Butoxycarbonyl)-L-prolinal (S)-BOC-PYRROLIDINE-2-CARBOXALDEHYDE (S)-N-Boc-吡咯烷-2-甲醛 N-(叔丁氧羰基)-L-脯氨醛 (S)-N-Boc-pyrrolidine-2-carboxaldehyde, N-(tert-Butoxycarbonyl)-L-prolinal (S)-tert-Butyl 2-formylpyrrolidine-1-carboxylate N-BOC-L-PROLINAL (S)-N-Boc-吡咯烷-2-甲醛 N-(叔丁氧羰基)-L-脯氨醛 N-BOC-L-脯氨醛 BOC-L-PROLINAL BOC-L-脯氨醛,97% (S)-2-FORMYL-PYRROLIDINE-1-CARBOXYLIC ACID TERT-BUTYL ESTER N-Boc-L-脯氨醛 2-Formylpyrrolidine-1-carboxylic acid tert-butyl ester (S)-(-)-1-BOC-2-PYRROLIDINECARBALDEHYDE N-(TERT-BUTOXYCARBONYL)-L-PROLINAL (S)-N-BOC-PYRROLIDINE-2-CARBOXALDEHYDE (S)-N-Boc-pyrrolidine-2-carboxal
PubChem Substance ID24871916
EC Number250-023-7
Beilstein Registry Number2384789
Chemical Name TranslationN-Boc-L-脯氨醛
LabNetwork Molecule IDLN00010188
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分类

  • {SNA} Aldehydes, Amino Acid Derivatives, Amino Aldehydes, Building Blocks, C10-C12, Carbonyl Compounds, Chemical Biology, Chemical Synthesis, Organic Building Blocks, Peptide Chemistry
  • {SNA} Aldehydes, Amino Acids & Derivatives, Amino Aldehydes, Building Blocks, C10-C12, Carbonyl Compounds, Chemical Biology, Chemical Synthesis, Organic Building Blocks, Peptide Chemistry
  • Aldehydes, Amino Acid Derivatives, Amino Aldehydes, Building Blocks, C10-C12, Carbonyl Compounds,

产品应用

  • 用于降一叶萩碱型生物碱和依靛蓝双酮碳骨架的重要结构单元。

相关文献及参考

  • 1. Org. Lett. 6 , 1813, (2004) 摘要
  • 2. Tetrahedron Lett. 45 , 2985, (2004)

安全信息

Warnings IRRITANT, AIR SENSITIVE
GHS Symbol
WGK Germany3
Hazard Codes Xi
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
Signal word
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S37 Wear suitable gloves 戴适当手套;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition Store at 0-5°C Air Sensitive -20°C保存

其他信息

  • N-BOC-L-脯氨醛价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/06/21 368290010 N-BOC-L-脯氨醛 (S)-N-BOC-Prolinal 97% 1 GR 1837元 2010/06/21 368290050 N-BOC-L-脯氨醛 (S)-N-BOC-Prolinal 97% 5 GR 7255元 2010/05/25 H26495 Boc-L-脯氨醛,97% N-Boc-L-prolinal, 97% 5g 4900元
  • MOL 文件:69610-41-9.mol
  • Alfa Aesar:Boc-L-脯氨醛,97% N-Boc-L-prolinal, 97%(69610-41-9)
  • 比旋光度:-101 ° (c=0.66 in chloroform)
  • 上游原料:二氯甲烷 --> 乙酸 --> 氯铬酸吡啶盐 --> N-BOC-L-脯氨醇 --> 分子筛

系列性分类


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