CAS 696-62-8 MFCD00001056-4-Iodoanisole 4-碘苯甲醚 TAO{mole}

4-Iodoanisole 4-碘苯甲醚

CAS 696-62-8 MFCD00001056

化学结构图

SMILES: COc1ccc(I)cc1

化学属性

Mol. Formula	C7H7IO
Mol. Weight	234.03
Density	1.727
Boiling Point	239°C at 760 mmHg
Melting Point	50-53°C
Flash Point	95.1°C
TSCA	Yes
Stability	对光敏感
Appearance	白色针状结晶。熔点51-52℃，沸点237℃（96.8kPa）。溶于醇、醚等有机溶剂，不溶于水。见光易分解析出碘。

别名和识别编码

Chemical Name	4-Iodoanisole
Synonym	4-Iodoanisole {LY} 4-Iodoanisole {} {LY} 4-Iodoanisole {} {} {LY} 4-Iodoanisole {} {} {} {LY} 4-Iodoanisole {} {} {} {} {LY} 4-Iodoanisole {} {} {} {} {} {LY} 4-Iodoanisole {} {} {} {} {} {} {LY} 4-Iodoanisole {} {} {} {} {} {} {} {LY} 4-Iodoanisole {} {} {} {} {} {} {} {} {LY} 4-Iodoanisole {} {} {} {} {} {} {} {} {} {LY} 4-Iodoanisole {} {} {} {} {} {} {} {} {} {} {LY} 4-Iodoanisole {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Iodoanisole {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Iodoanisole {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Iodoanisole {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Iodoanisole {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Iodoanisole {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Iodoanisole {} {} {} {} {} {}
CAS Number	696-62-8
EC Number	211-789-7
Beilstein Registry Number	1906692
MDL Number	MFCD00001056
PubChem Substance ID	87571731
Reaxys-RN	1906692
Chemical Name Translation	4-碘苯甲醚
InChIKey	SYSZENVIJHPFNL-UHFFFAOYSA-N
LabNetwork Molecule ID	LN00008914
Canonical SMILES	COC1=CC=C(I)C=C1

信息真实价格透明资金保障专业采购外包团队在线服务

品牌质保精细包装现货库存一流品牌服务

产品应用

用于有机合成。

安全信息

Signal word Warning

GHS Symbol

WGK Germany3

Safety Statements

S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S36 Wear suitable protective clothing 穿戴适当的防护服；
S37 Wear suitable gloves 戴适当手套；

Risk Statements

R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

Precautionary statements

P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P302+P352+P332+P313+P362+P364
P305+P351+P338
P305+P351+P338+P337+P313
P332+P313
P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用

Hazard statements

H315 Causes skin irritation 会刺激皮肤
H319 Causes serious eye irritation 严重刺激眼睛
H335 May cause respiratory irritation 可能导致呼吸道刺激

Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves

Storage condition -20°C, protect from light {LY} -20°C, protect from light Light Sensitive {} {LY} -20°C, protect from light {} {} {LY} -20°C, protect from light {} {} {} {LY} -20°C, protect from light {} {} {} {} {LY} -20°C, protect from light {} {} {} {} {} {LY} -20°C, protect from light {} {} {} {} {} {} {LY} -20°C, protect from light {} {} {} {} {} {} {} {LY} -20°C, protect from light {} {} {} {} {} {} {} {} {LY} -20°C, protect from light {} {} {} {} {} {} {} {} {} {LY} -20°C, protect from light {} {} {} {} {} {} {} {} {} {} {LY} -20°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, protect fro

Hazard Codes Xi Xi,Xn

其他信息

图谱信息:4-碘苯甲醚(696-62-8)红外图谱(IR1) 4-碘苯甲醚(696-62-8)核磁图( 13 CNMR) 4-碘苯甲醚(696-62-8)红外图谱(IR2) 4-碘苯甲醚(696-62-8)核磁图( 1
用途一:用于有机合成
MOL 文件:696-62-8.mol
Alfa Aesar:4-碘苯甲醚,98+% 4-Iodoanisole, 98+%(696-62-8)
3-氟-4-碘苯甲醚的合成:以间氨基苯甲醚为原料,在浓HCl、NaNO2作用下,反应温度5℃以下,加入40%的氟硼酸,加热,经Schiemann反应生成间氟苯甲醚,产率36.6%。然后在60℃水浴中缓慢滴加65%~68%的发烟硝酸、冰乙酸和醋酐的混合液(间氟苯甲醚与浓硝酸的摩尔比为0.0624∶0.0721、冰乙酸与醋酐的体积比为10.6∶7.6),苯环上4-位硝化1 h后得3-氟-4-硝基苯甲醚,产率48
4-碘苯甲醚价格(试剂级):更新日期产品编号产品名称包装价格 2014/06/02 I0378 4-碘苯甲醚 4-Iodoanisole 500G 2980元 2014/06/02 I0378 4-碘苯甲醚 4-Iodoanisole 25G 352元 2010/06/21 122321000 4-碘苯甲醚 4-Iodoanisole 98% 100 GR 765元
TCI Shanghai:4-碘苯甲醚 4-Iodoanisole,>;96.0%(GC)(696-62-8)
F:8
Sigma Aldrich:696-62-8(sigmaaldrich)
Acros Organics:4-碘代茴香醚/对碘代苯甲醚 4-Iodoanisole, 98%(696-62-8)
用途二:液晶单体合成原料
溶于醇、醚等有机溶剂，不溶于水。见光易分解析出碘。
方法一:由苯甲醚与氯化碘反应而得。将苯甲醚加入冰醋酸中，搅拌并缓缓加入氯碘。加毕升温回流3.5h。冷却，倒入冰水中，析出对碘苯甲醚。将其分出后用5%亚硫酸钠洗去游离碘，然后水洗，减压蒸馏，收集沸点140-160℃（5.33kPa）馏分，冷至0℃过滤。用甲醇洗涤、重结晶，即得成品。
上游原料:亚硫酸钠 --> 二甲醚 --> 一氯化碘
MSDS 信息:4-Iodoanisole(696-62-8).msds
海关编码:29093090
2,3-二氟-4-碘苯甲醚的合成:以2,3-二氨基苯甲醚为原料,在浓HCl和NaNO2作用下,反应温度在5 ℃以下,加入w(HBF4)=40%的氟硼酸,加热,经Schiemann反应生成2,3-二氟苯甲醚,产率40.7%.然后在50～60 ℃水浴中缓慢滴加w(HNO3)=65%～68%的发烟硝酸、冰醋酸和醋酐的混合液,苯环上4-位硝化后得2,3-二氟-4-硝基苯甲醚,产率51.9%,熔点124 ℃.在SnCl2和浓HCl作用下反应12 h,再还原成2,3-二氟-4-氨基苯甲醚,产率84.6%,熔点81～82 ℃.加入NaNO2、浓H2SO4和KI,在5 ℃重氮化,经Sandmeyer反应碘
图谱信息:4-碘苯甲醚(696-62-8)红外图谱(IR1) 4-碘苯甲醚(696-62-8)核磁图( 13 CNMR) 4-碘苯甲醚(696-62-8)红外图谱(IR2) 4-碘苯甲醚(696-62-8)核磁图( 1 HNMR) 4-碘苯甲醚(696-62-8)Raman光谱 4-碘苯甲醚(696-62-8)质谱(MS)
3-氟-4-碘苯甲醚的合成:以间氨基苯甲醚为原料,在浓HCl、NaNO2作用下,反应温度5℃以下,加入40%的氟硼酸,加热,经Schiemann反应生成间氟苯甲醚,产率36.6%。然后在60℃水浴中缓慢滴加65%~68%的发烟硝酸、冰乙酸和醋酐的混合液(间氟苯甲醚与浓硝酸的摩尔比为0.0624∶0.0721、冰乙酸与醋酐的体积比为10.6∶7.6),苯环上4-位硝化1 h后得3-氟-4-硝基苯甲醚,产率48.7%,沸点151.2℃。在ZnCl2和浓HCl作用下反应12 h,再还