Pyridine N-Oxide 吡啶-N-氧化物
CAS 694-59-7 MFCD00006194
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信息真实价格透明
资金保障
专业采购外包团队在线服务
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分类
- {SNA} Building Blocks, C5, Chemical Synthesis, Heterocyclic Building Blocks, Pyridines
- {uni_hamburg} no charge; nitrogen heterocycle; 6RingOnly; 6ring; 1fragment
相关文献及参考
- Short: II/19c
- Short: II/19b
- Short: II/14a
- Mild oxidant for conversion of unactivated alkyl halides to aldehydes or ketones: J. Org. Chem., 22, 1135 (1957); 35, 244 (1970); Tetrahedron, 33, 1845 (1977). Substituted acetic acids and their anhydrides: J. Org. Chem., 38, 3737 (1973), as well as ɑ-bromo and ɑ-chloro acids: J. Org. Chem., 31, 3058 (1966); J. Am. Chem. Soc., 89, 4968 (1967), can undergo oxidative decarboxylation to aldehydes and ketones.
安全信息
GHS Symbol
- S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护;
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
- S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触;
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- R22 Harmful if swallowed 吞咽有害
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P264+P265
- P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P301+P312
- P301+P317
- P302+P350
- P302+P352
- P302+P352+P332+P313+P362+P364
- P304+P340
- P305+P351+P338
- P305+P351+P338+P337+P313
- P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
- P319
- P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
- P330 Rinse mouth. 漱口
- P332+P313
- P332+P317
- P337+P313
- P337+P317
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
- P362+P364
- P403+P233
- P405 Store locked up. 上锁保管。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- H302 Harmful if swallowed 吞食有害
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Bird - quail DOSE/DURATION : 1 gm/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : JRPFA4 Journal of Reproduction and Fertility. (Biochemical Soc. Book Depot, POB 32, Commerce Way, Colchester, Essex CO2 8HP, UK) V.1- 1960- Volume(issue)/page/year: 48,371,1976
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Bird - wild bird species DOSE/DURATION : 1 gm/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : AECTCV Archives of Environmental Contamination and Toxicology. (Springer-Verlag New York, Inc., Service Center, 44 Hartz Way, Secaucus, NJ 070944) V.1- 1973- Volume(issue)/page/year: 12,355,1983
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intravenous SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 180 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#04070
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intraperitoneal SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 1425 mg/kg TOXIC EFFECTS : Nutritional and Gross Metabolic - weight loss or decreased weight gain Nutritional and Gross Metabolic - body temperature decrease REFERENCE : JPPMAB Journal of Pharmacy and Pharmacology. (Pharmaceutical Soc. of Great Britain, 1 Lambeth High St., London SEI 7JN, UK) V.1- 1949- Volu
其他信息
- F:21
- Sigma Aldrich:694-59-7(sigmaaldrich)
- 下游产品:4-氨基吡啶 --> 4-氯-2-氰基吡啶 --> 4-苄氧基-2(1H)-吡啶酮
- 存储注意事项:湿度敏感
- TCI Shanghai:吡啶-N-氧化物 Pyridine N-Oxide,>;95.0%(T)(694-59-7)
- Alfa Aesar:N-氧化吡啶,95% Pyridine N-oxide, 95%(694-59-7)
- 吡啶-N-氧化物价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 P0557 吡啶N-氧化物 Pyridine N-Oxide 25G 267元 2014/06/02 P0557 吡啶N-氧化物 Pyridine N-Oxide 500G 1920元 2010/06/21 157691000 吡啶-N-氧化物 Pyridine-N-oxide 98% 100 GR 636元
- MSDS 信息:Pyridine-N-oxide(694-59-7).msds
- 敏感性:Hygroscopic
- 海关编码:29333999
- 图谱信息:吡啶-N-氧化物(694-59-7)质谱(MS) 吡啶-N-氧化物(694-59-7)核磁图( 13 CNMR) 吡啶-N-氧化物(694-59-7)红外图谱(IR2) 吡啶-N-氧化物(694-59-7)核磁图( 1 HNMR) 吡啶-N-氧化物(694-59-7)红外图谱(IR3) 吡啶-N-氧化物(694-59-7)红外图谱(IR1)
- Acros Organics:N-氧化吡啶 Pyridine-N-oxide, 98%(694-59-7)
- MOL 文件:694-59-7.mol